Electron optical and X-ray powder diffraction study of synthetic and natural potassic cordierites

The microstructural and X-ray diffraction characteristics of natural K-bearing cordierites in buchites (Blaue Kuppe, Germany), and paralavas (Bokaro, India) are compared to those of three suites of synthetic, K-bearing Mg-cordierite, studied after annealing glasses of the requisite compositions for durations between 5 min and 255 days at 1,290° C and 1 bar. In analogy to pure Mg-cordierite, hexagonal high-cordierite initially crystallizes from the glass and subsequently transforms to orthorhombic low-cordierite. After annealing for 30–60 min, the crystals develop tweed-structure. With prolonged annealing, the pattern coarsens and develops into lamellar twinning. Higher K-contents favour earlier development of tweed-contrast. Distortion indices obtained by X-ray powder diffraction show a sharp initial increase of with annealing time, followed by a levelling off after approximately 10 h. Higher K-contents delay this initial increase, and decrease drastically the maximum distortion index that can be attained. The contrasting observations with respect to increasing K-content are due to the different levels of information yielded by TEM and X-ray diffraction. Analyses of electron diffraction patterns indicate that the metric state of individual crystals in any single sample annealed for more than one hour is highly heterogeneous, while no compositional differences could be detected. Hexagonal and variously distored crystals coexist. Thus intermediate structural states of cordierite in the classical sense are shown to exist, although intermediate distortion indices obtained by routine X-ray powder diffraction are largely due to a summation effect over such structurally heterogeneous populations. Although distinct differences in microstructure between the synthetic and the natural Fe²⁺-bearing cordierites exist, the Bokaro samples most closely resemble the early (1–10 h) tweed-structure of the synthetic products, whereas the Blaue Kuppe samples are comparable to a more mature (1–3 days) stage. It is thus concluded that the cordierite-bearing Bokaro paralavas cooled considerably faster than the Blaue Kuppe buchites.     

The Spaces of Conservation and Development around Lake Nakuru National Park,Kenya

Geographically or sociologically defined resource management units, such as buffer zones or community resource management territories, seek to harmonize local land–use practices with protected–area management objectives. The geographically restricted nature of these models often results in simplistic representations of society–nature relations over time and space. Conservation areas are misrepresented as ecologically and socially homogeneous, as well as politically neutral. This study examines the limits of a spatially defined conservation and development project designed around the physical geographical unit of the watershed at Lake Nakuru National Park, Kenya. It argues that politically motivated violence that has plagued the area since the early 1990s has severely undermined the suitability of such narrowly defined conservation territories. Specifically, the case study points to the permeability of the Lake Nakuru watershed to national and regional political forces that ultimately constrain participation in conservation activities. The spaces of conservation and development must be enlarged to include these extralocal arenas and processes if environmental problems are to be effectively addressed.     

Mesozooplankton biomass and grazing responses to Cyclone Opal, a subtropical mesoscale eddy

As part of E-Flux III cruise studies in March 2005, plankton net collections were made to assess the effects of a cyclonic cold-core eddy (Cyclone Opal) on the biomass and grazing of mesozooplankton. Mesozooplankton biomass in the central region of Cyclone Opal, an area of uplifted nutricline and a subsurface diatom bloom, averaged 0.80±0.24 and 1.51±0.59 g DW m⁻², for day and night tows, respectively. These biomass estimates were about 80% higher than control (OUT) stations, with increases more or less proportionately distributed among size classes from 0.2 to >5 mm. Though elevated relative to surrounding waters south of the Hawaiian Islands (Hawai’i lee), total biomass and size distribution in Cyclone Opal were almost exactly the same as contemporary measurements made at Stn. ALOHA, 100 km north of the islands, by the HOT (Hawaii Ocean Time-series) Program. Mesozooplankton biomass and community composition at the OUT stations were also similar to ALOHA values from 1994 to 1996, preceding a recent decadal increase. These comparisons may therefore provide insight into production characteristics or biomass gradients associated with decadal changes at Stn. ALOHA. Gut fluorescence estimates were higher in Opal than in ambient waters, translating to grazing impacts of 0.11±0.02 d⁻¹ (IN) versus 0.03±0.01 d⁻¹ (OUT). Over the depth-integrated euphotic zone, mesozooplankton accounted for 30% of the combined grazing losses of phytoplankton to micro- and meso-herbivores in Opal, as compared to 13% at control stations. Estimates of active export flux by migrating zooplankton averaged 0.81 mmol C m⁻² d⁻¹ in Cyclone Opal and 0.37 mmol C m⁻² d⁻¹ at OUT stations, 53% and 24%, respectively, of the carbon export measured by passive sediment traps. Migrants also exported 0.18 mmol N m⁻² d⁻¹ (117% of trap N flux) in Cyclone Opal compared to 0.08 mmol N m⁻² d⁻¹ (51% of trap flux) at control stations. Overall, the food-web importance of mesozooplankton increased in Cyclone Opal both in absolute and relative terms. Diel migrants provided evidence for enhanced export flux in the eddy that was missed by sediment trap and ²³⁴Th techniques, and migrant-mediated flux was the major export term in the observed bloom-perturbation response and N mass balance of the eddy.     

Producer Services Research in the United Kingdom

This paper reviews recent research in the United Kingdom on producer services and suggests directions for further research. A recurrent theme in UK-based geographic research into producer services is the role of service activities, establishments, and trade in uneven development of the UK space economy, a role manifested in uneven provision and quality of services in peripheral regions. During the 1980s, overall growth in demand for producer services and the rapid rise in metropolitan London real estate costs reduced London's dominance, but these trends moderated by the end of the decade. In the absence of adequate government statistics, regular and standardized surveys are needed to compile a time series of service change in the United Kingdom. Directions for continued empirical research include the role of producer services in innovation and technology transfer, the implications of information technology for the location of employment in the sector, and the impacts of productivity increases on employment and wages.     

Wisconsinan Late-glacial environmental change in southern New England: A regional synthesis

A synthesis of vegetational and climatic history during the Wisconsinan Late-glacial (13-9 ka BP) is presented for the southern New England region. The interpretations are based on a number of pollen-stratigraphical investigations supported by plant macrofossil data. Chronology is based partly on AMS dates of plant macrofossils. Reference is made briefly to the controversial nature of the evidence for deglaciation in the region. A curve representing mean July temperature changes in the region during the period 13-9 ka BP is provided.     

The secular variation of cometary magnitude

This paper calculates the mean variation in absolute magnitude per perihelion passage, ΔH₁₀, for short-period comets from the data of Vsekhsvyatskii and finds a value of 0.30 ± 0.06. Other mechanisms used for estimating cometary decay are reviewed and it is concluded that a more probable value for ΔH₁₀ is about 0.002. Reasons for the discrepancy between these two values are given.     

Carbon fluxes from eroding peatlands – the carbon benefit of revegetation following wildfire

Peatlands are among the largest long‐term soil carbon stores, but their degradation can lead to significant carbon losses. This study considers the carbon budget of peat‐covered sites after restoration, following degradation by past wildfires. The study measured the carbon budget of eight sites: four restored‐revegetated sites, two unrestored bare soil control sites, and two intact vegetated controls over two years (2006–2008). The study considered the following flux pathways: dissolved organic carbon (DOC); particulate organic carbon (POC); dissolved carbon dioxide (CO₂); primary productivity; net ecosystem respiration, and methane (CH₄). The study shows that unrestored, bare peat sites can have significant carbon losses as high as 522 ± 3 tonnes C/km²/yr. Most sites showed improved carbon budgets (decreased source and/or increased sink of carbon) after restoration; this improvement was mainly in the form of a reduction in the size of the net carbon source, but for one restored site the measured carbon budget after four years of restoration was greater than observed for vegetated controls. The carbon sequestration benefit of peatland restoration would range between 122 and 833 tonnes C/km²/yr. Copyright © 2011 John Wiley & Sons, Ltd.     

Book reviews

APPLIED GEOGRAPHY: Issues, Questions and Concerns (Geo Journal Library Vol. 15) edited by M. S. Kenzer. 16 × 24 cm, x and 210 pages. Kluwer: Dordrecht 1989 (ISBN 0 7923 04381).

WINE AND THE VINE: An Historical Geography of Viticulture and the Wine Trade by T. Unwin. 16 × 24 cm, xvi and 409 pages. Routledge: London 1991 (ISBN 0 415 13120 6) $A155.00 (hard); distributed by The Law Book Co.

WATERFRONT SYDNEY 1860–1920 by G. Aplin and J. Storey. 26 × 18 cm. 144 pages. Allen & Unwin: Sydney 1991 (first published 1984) (ISBN 1 86373 098 2) $A24.95 (soft).

Australian Geographer 23 (2), November 1992

INDUSTRIAL LOCATION: Principles and Policies (Second Edition) by K. Chapman and D. F. Walker. 15 × 23 cm, xiii and 322 pages. Basil Black‐well: Oxford 1991 (ISBN 0 631 16789 7) $A39.95 (soft).

INTERNATIONALISATION OF AUSTRALIA'S SERVICE INDUSTRIES by J. V. Langdale. 17 × 25 cm, iv and 373 pages. Australian Government Publishing Service, for Department of Industry, Technology and Commerce: Canberra 1991 (ISBN 0 644 13841 6).

TOURISM AND GOLD IN KAKADU: The Impact of Current and Potential Natural Resource Use on the Northern Territory Economy by B. Knapman, O. Stanley and J. Lea. 21 × 29 cm, vi and 49 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1179 4).

ABORIGINAL AUSTRALIA AND THE ‘NEW FEDERALISM’ INITIATIVE (Discussion Paper No. 2) by G. J. Crough. 14 × 21 cm, 42 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1325 8).

AUSTRALIAN NATIONHOOD AND OUTBACK INDIGENOUS PEOPLES (Discussion Paper No. 1) by P. Jull. 14 × 21 cm, 38 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1309 6).

MIGRATION AND DEVELOPMENT IN THE SOUTH PACIFIC (Pacific Research Monograph No. 24) edited by J. Connell. 17 × 25 cm, xii and 199 pages. National Centre for Development Studies, Australian National University: Canberra 1990 (ISBN 0 07315 0668 5) $A25.00 (soft).

POPIULESIN BLONG HONIARA: Olketa Popiulesin Map Blong 1986 Sensis. HONIARA: 1986 Census Atlas (Statistics Office Occasional Paper No. 4 / Board of Development Studies Monograph No. 1) by A.C. Walsh. 21 × 29 cm, vii and 95 pages. Department of Statistics: Honiara and Board of Development Studies, Massey University: Palmerston North 1990 (ISSN 0114 8834) $NZ34.00 in New Zealand, $NZ38.00 elsewhere (soft).

DOI MOI: Vietnam's Renovation Policy and Performance (Political and Social Change Monograph No. 14) edited by D. K. Forbes, T. H. Hull, D. G. Marr and B. Brogan. 15 × 22 cm, xiv and 263 pages. Department of Political and Social Change, Australian National University: Canberra 1991 (ISBN 0 7315 1303 7).     

NMR-spectroscopy of synthetic potassium-bearing cordierites

Potassic cordierites with the chemical composition K _x Mg₂Al_4+x Si₅–xO₁₈ (x = 0.00, 0.10, 0.20, and 0.25) were synthesized by annealing glasses at 1290° C for different lengths of time. The procedure resulted in cordierites with different states of Al,Si-order for the tetrahedral sites in the structure. The dependence between the potassium-content and the state of order on one side and between annealing time and the state of order on the other side was then studied using ²⁹Si MAS nuclear magnetic resonance (NMR) spectroscopy. The spectra show that the state of order is a continuous function of annealing time for all compositions considered, but the rate of ordering decreases with increasing K-content. Since the substitution K+Al Si leads to higher Al/Si-ratios; the lower rate of ordering is discussed as a consequence of changed statistics for Al, Si site exchanges. The Al atoms replacing silicon in the structure to balance the charge of potassium cations are not located close to the potassium ion but at a maximum distance from it. This is shown to be a consequence of an improvement in coordination of all oxygen atoms in the cordierite framework.