Solubility of hydrous ferric oxide and iron speciation in seawater

Iron solubility equilibria were investigated in seawater at 36.22‰ salinity and 25°C using several filtration and dialysis techniques. In simple filtration experiments with 0.05 μm filters and Millipore ultra-filters, ferric chlorides fluorides, sulfates, and FeOH²⁺ species were found to be insignificant relative to Fe(OH)₂⁺ at p[H⁺] = ?log [H⁺] greater than 6.0. Hydrous ferric oxide freshly precipitated from seawater yielded a solubility product of ${}^1\text{K}{}_{\mathrm{<mtext>so</mtext>}}\text{=}\text{[Fe}{}^{\mathrm{3+}}\text{][H}{}^{\mathrm{+}}\text{]}{}^{\mathrm{?3}}\text{= 4.7 · 10}{}^5$. Solubility studies based on the rates of dialysis of various seawater solutions and on the filtration of acidified seawater solutions indicated the existence of the Fe(OH)₃⁰ species. The formation constant for this species can be calculated as ${}^1\text{β}{}_3\text{=}\text{[Fe(OH)}{}_3{}^0\text{] [H}{}^{\mathrm{+}}\text{]}{}^3\text{/[Fe}{}^{\mathrm{3+}}\text{] = 2.4 · 10}{}^{\mathrm{?14}}$. The Fe(OH)₄^? species is present at concentrations which are negligible compared to Fe(OH)₂⁺ and Fe(OH)₃⁰ in the normal pH range of seawater. However, there is at least one other significant ferric complex in seawater above p[H⁺] = 8.0 (possibly with bicarbonate, carbonate, or borate ions) in addition to the Fe(OH)₂⁺ and Fe(OH)₃⁰ species.     

Effect of major ion variations in the marine environment on the specific gravity-conductivity-chlorinity-salinity relationship

Partial equivalent conductances and partial equivalent volumes of the major constituents in seawater were used to evaluate the specific gravity-conductivity-chlorinity-salinity relationships in the marine environment. For example, in the open ocean, the relationships between Cl‰ and both S‰ and specific gravity are valid to within 0.014‰ and 0.014 σ_t, respectively. The relationships between conductivity and S‰ and specific gravity are valid to within 0.006‰ and 0.007 σ_t. In river diluted nearshore areas specific gravity anomalies inferred from Cl‰, can be as great as 0.06 σ_t and 0.04 σ_t when inferred from a conductivity ratio measurement.     

The distribution of total and electrochemically available copper in the northwestern atlantic ocean

Copper in a series of samples from the northwestern Atlantic has been determined by anodic stripping voltammetry (ASV) and atomic absorption spectrometry after preconcentration by cobalt—APDC coprecipitation. Samples from a transect across the continental shelf directly off the New York Bight showed a linear relationship between total copper and salinity (31–34‰) and less than 5% of the total copper was detectable by ASV. A slope water station showed less than 9% of the total copper to be ASV detectable in the upper 780m, below which the ASV detectable copper increased to 70% at 3000 m. The Sargasso Sea profiles showed less than 7% ASV detectable copper in the upper 150 m; the fraction of the total copper detected by ASV increased to about 80% of the total copper at greater depths. The reduced availability of copper to the ASV measurement in coastal waters and open ocean surface waters appears to be related to recent contact with waters where biological productivity occurs.     

A map series of the Southern East Pacific Rise and its flanks, 15° S to 19° S

Four large-scale bathymetric maps of the Southern East Pacific Rise and its flanks between 15° S and 19° S display many of the unique features of this superfast spreading environment including abundant seamounts (the Rano Rahi Field), axial discontinuities, discontinuity migration, and abyssal hill variation. Along with a summary of the regional geology, these maps will provide a valuable reference for other sea-going programs on-and off-axis in this area, including the Mantle ELectromagnetic and Tomography (MELT) experiment.     

Documenting hurricane impacts on coral reefs using two-dimensional video-mosaic technology

Four hurricanes impacted the reefs of Florida in 2005. In this study, we evaluate the combined impacts of hurricanes Dennis, Katrina, Rita, and Wilma on a population of Acropora palmata using a newly developed video‐mosaic methodology that provides a high‐resolution, spatially accurate landscape view of the reef benthos. Storm damage to A. palmata was surprisingly limited; only 2 out of 19 colonies were removed from the study plot at Molasses Reef. The net tissue losses for those colonies that remained were only 10% and mean diameter of colonies decreased slightly from 88.4 to 79.6 cm. In contrast, the damage to the reef framework was more severe, and a large section (6 m in diameter) was dislodged, overturned, and transported to the bottom of the reef spur. The data presented here show that two‐dimensional video‐mosaic technology is well‐suited to assess the impacts of physical disturbance on coral reefs and can be used to complement existing survey methodologies.     

Tectonics at the intersection of the East Pacific Rise with Tamayo Transform fault

During the Fall of 1979, a manned submersible program, utilizing DSRV ALVIN, was carried out at the intersection of the East Pacific Rise (EPR) with the Tamayo Transform boundary. A total of seven dives were completed in the vicinity of the EPR/Tamayo intersection depression and documented the geologic relationships that characterize the juxtaposition of these types of plate boundaries. The young volcanic terrain of the EPR axis can be traced into and across the Tamayo Transform valley but becomes buried by sedimentary talus that is being shed from sediment scarps along the unstable sediment slope that defines the north side of the intersection depression. Within 4 km of the transform boundary, the dominant trend (000°) of the fissures and faults that disrupt the rise-generated volcanics is markedly oblique to the regional direction of sea floor spreading (120°). Since no evidence was found to suggest that these structures accommodate significant amounts of strike-slip displacement, they are taken to reflect a distortion of the EPR extensional tectonic regime by a transform generated shear couple. The floor of the Tamayo Transform valley in this area is inundated by mass-wasted sediment, and the principal transform displacement zone is characterized at the surface by a narrow (<1.5 km) interval of fault scarps in sediment that trends parallel with the transform valley. Extrapolated to the west, this zone links with zones of transform deformation investigated during earlier submersible studies (CYAMEX and Pastouret, 1981). Evidence of low-level hydrothermal discharge was seen at one locality on the EPR axis and at another 8 km west of the axis at the edge of the zone of transform deformation.     

Tectonics of a fast spreading center: A Deep-Tow and sea beam survey on the East Pacific rise at 19°30′ S

Sea Beam and Deep-Tow were used in a tectonic investigation of the fast-spreading (151 mm yr^-1) East Pacific Rise (EPR) at 19°30 S. Detailed surveys were conducted at the EPR axis and at the Brunhes/Matuyama magnetic reversal boundary, while four long traverses (the longest 96 km) surveyed the rise flanks. Faulting accounts for the vast majority of the relief. Both inward and outward facing fault scarps appear in almost equal numbers, and they form the horsts and grabens which compose the abyssal hills. This mechanism for abyssal hill formation differs from that observed at slow and intermediate spreading rates where abyssal hills are formed by back-tilted inward facing normal faults or by volcanic bow-forms. At 19°30 S, systematic back tilting of fault blocks is not observed, and volcanic constructional relief is a short wavelength signal (less than a few hundred meters) superimposed upon the dominant faulted structure (wavelength 2–8 km). Active faulting is confined to within approximately 5–8 km of the rise axis. In terms of frequency, more faulting occurs at fast spreading rates than at slow. The half extension rate due to faulting is 4.1 mm yr^-1 at 19°30 S versus 1.6 mm yr^-1 in the FAMOUS area on the Mid-Atlantic Ridge (MAR). Both spreading and horizontal extension are asymmetric at 19°30 S, and both are greater on the east flank of the rise axis. The fault density observed at 19°30 S is not constant, and zones with very high fault density follow zones with very little faulting. Three mechanisms are proposed which might account for these observations. In the first, faults are buried episodically by massive eruptions which flow more than 5–8 km from the spreading axis, beyond the outer boundary of the active fault zone. This is the least favored mechanism as there is no evidence that lavas which flow that far off axis are sufficiently thick to bury 50–150 m high fault scarps. In the second mechanism, the rate of faulting is reduced during major episodes of volcanism due to changes in the near axis thermal structure associated with swelling of the axial magma chamber. Thus the variation in fault spacing is caused by alternate episodes of faulting and volcanism. In the third mechanism, the rate of faulting may be constant (down to a time scale of decades), but the locus of faulting shifts relative to the axis. A master fault forms near the axis and takes up most of the strain release until the fault or fault set is transported into lithosphere which is sufficiently thick so that the faults become locked. At this point, the locus of faulting shifts to the thinnest, weakest lithosphere near the axis, and the cycle repeats.     

Coastal Habitat Use and Residency of Juvenile Atlantic Sharpnose Sharks (Rhizoprionodon terraenovae)

Coastal habitat use and residency of a coastal bay by juvenile Atlantic sharpnose sharks, Rhizoprionodon terraenovae, were examined by acoustic monitoring, gillnet sampling, and conventional tag–recapture. Acoustic monitoring data were used to define the residency and movement patterns of sharks within Crooked Island Sound, Florida. Over 3 years, sharks were monitored for periods of 1–37 days, with individuals regularly moving in and out of the study site. Individual sharks were continuously present within the study site for periods of 1–35 days. Patterns of movement could not be correlated with time of day. Home range sizes were typically small (average?=?1.29 km²) and did not vary on a yearly basis. Gillnet sampling revealed that juvenile Atlantic sharpnose sharks were present in all habitat types found within Crooked Island Sound, and peaks in abundance varied depending on month within a year. Although telemetry data showed that most individuals remained within the study site for short periods of time before emigrating, conventional tag–recapture data indicates some individuals return to Crooked Island Sound after extended absences (maximum length?=?1,352 days). Although conventional shark nursery theory suggests small sharks remain in shallow coastal waters to avoid predation, juvenile Atlantic sharpnose sharks frequently exited from protected areas and appear to move through deeper waters to adjacent coastal bays and estuaries. Given the high productivity exhibited by this species, the benefit gained through a nursery that reduces predation may be limited for this species.     

Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.