Simultaneous five color (UBVRI) polarimetry of EF Eri

We present the first observations of the AM Her type object EF Eri where both the polarization and the photometric data are recorded simultaneously in five color bands (UBVRI). The position angle rotates strongly (30°) vs. wavelength from U to I, probably due to Faraday rotation or due to fact that the polarized radiation seen in the different wavelength bands comes from different parts of the accretion region. The phase dependence of the position angle requires field and accretion geometry more complicated than a simple centered dipole and a second emitting region producing weaker intermediate pulses in the infrared seems to be present. We derive the value of the inclination of the system i=55°±5°, the colatitude of the active pole ₁,= 38° ±5° and the second emitting region = 115° ± 5°, both of which are nearly at the same longitude facing the main accretion stream.Based on observations made at the European Southern Observatory, La Silla, Chile.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.     

Simultaneous five color (UBVRI) polarimetry of VV Puppis

Observations of linear and circular polarization in five colour bands during a highly active state of VV Puppis in January-86 are reported. A strong linear polarization pulse with the maximum in the blue, P_B22 %, is observed at the end of the bright phase when the active pole is at the limb and a weaker secondary pulse, P_B7 %, is seen in the beginning of the bright phase, when the active pole reappears. Strong positive circular polarization is also observed in the blue and the ultraviolet, P_UP_B18 %, P_V10 % during the bright phase. The circular polarization reverses the sign in the B and V bands during the faint phase and a negative polarization hump is seen when the active pole crosses the limb. The circular polarization in the V band reaches the value P_V–10% at the hump, after which it remains near P_V–5% during the faint phase. This is probably due to radiation coming from the second, less active pole and accretion thus takes place onto both poles. The wavelength dependences of the positive and negative parts of the circular polarization curve are different and no polarization reversal is seen in the U band. The position angle of the linear polarization is well determined during a large portion of the cycle, especially in the V band, thanks to the activity from both poles. A best fit to the position angle curve, taking into account also the duration of the positive circular polarization phase interval =0.40 (in the V band), yields the values of orbital inclination i=78°±2° and the colatitude of the active magnetic pole =146°±2°. The relatively good fit to the position angle data indicates that the simple dipole model is nearly correct in the case of VV Puppis. Some wavelength dependence is, however, seen in the position angle curves, especially in the I band where the slope / at the main pulse is considerably smaller than in the other bands. The shape of the position angle curves changes also in the blue and the ultraviolet around the middle of the bright phase. This is probably due to optical thickness effects as the side of the accretion column which is toward the observer changes near this phase.Based on observations made at the European Southern Observatory, La Silla, Chile.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.On leave from University of Helsinki Observatory     

Bald kelp: natural and harvesting-induced frond loss in the South African kelp Ecklonia maxima

Ecklonia maxima dominates kelp beds on the west coast of southern Africa, and is commercially and ecologically valuable. Some plants lose all their secondary blades (fronds), leaving only the gas-filled bulb and short primary blade at the top of the stipe. These ‘bald’ kelps may persist for months or longer, occupying substratum space but contributing little to productivity. We investigated natural causes of balding in five kelp beds in False Bay, South Africa, and the effect of simulated commercial frond-harvesting on loss of fronds. Densities of sporophytes with and without fronds were measured at the water surface during low tides. Generalised linear modelling analysis showed a significant relationship between balding and site (whether sheltered from or exposed to swell/wind), position in the kelp bed (shoreward or seaward) and total E. maxima density. We conclude that balding is caused mainly by drying of meristematic basal regions of fronds during emersion of kelp heads at low tide. After partial harvesting of fronds, kelp heads floated higher out of the water, but after 95 days frond loss was significantly higher only when fronds were cut too close to the primary blade, possibly because of damage to meristematic tissue. Nevertheless, increased emersion that results from frond-harvesting may increase desiccation and blade loss and we suggest caution in setting harvest limits for this kelp.     

桐柏碰撞造山带及其邻区变形特征与构造格局

桐柏碰撞造山带及其邻区可以划分为九个大地构造单元,自北向南分别是:华北克拉通南缘岩石构造单元——宽坪岩群、具弧后盆地性质的二郎坪岩石构造单元、具岛弧性质的秦岭杂岩单元、龟山岩组和南湾岩组构成的俯冲前缘楔构造带、构造混杂岩带、桐柏北部高压岩片单元、桐柏核部杂岩单元、桐柏南部高压岩片单元以及随州构造变形带。根据详细的构造解析以及新的地质年代学资料,本文将中生代以来的构造变形划分为五幕,前两幕变形主要发育在构造混杂岩带以南的各个岩石构造单元中,之后的三幕变形则波及整个研究区。第一幕变形的时间约为255～238Ma,以发育区域上透入性的片理及北西西向的拉伸线理为主,并导致了高压岩片早期自西向东的挤出。第二幕变形的时间约为230～215Ma,以自北向南的逆冲推覆构造为主,使得高压岩片进一步垂向抬升。第三幕变形应早于下侏罗统,以近北西西向的宽缓褶皱为主要特征,该幕变形期间桐柏核部杂岩及其两侧高压岩片单元发生同步的抬升。第四幕变形大致发生在140～130Ma之间,主要表现为桐柏核部杂岩两侧走滑型韧性剪切带的活动,桐柏核部杂岩表现出向东的挤出。第五幕变形发生在120～80Ma,表现为北西向及北东向的脆性断裂活动,并切割以上所有构造形迹。桐柏高压岩片的抬升剥露受多幕变形控制,呈阶段性的抬升。     

Lipid biomarkers of deep-sea hydrothermal vent polychaetes—Alvinella pompejana, A. caudata, Paralvinella grasslei and Hesiolyra bergii

The lipid composition was determined for 5 species of polychaete annelids collected by the Deep Submergence Vehicle ALVIN from high temperature chimneys at the 2500 m depth hydrothermal vent field of the East Pacific Rise. These are the first lipid biomarker analyses reported for these hydrothermal vent polychaetes. Lipid content was low in all samples (1.6–35.9 mg g^–1 wet mass) and was dominated by polar lipid (78–90% of total lipid) with 8–19% sterol (ST), and very low storage lipid (triacylglycerol and wax ester). Total polyunsaturated fatty acids (PUFA) were moderately high (22–31% of total fatty acids (FA)) with extremely low or no docosahexaenoic acid (DHA, 22:6(n-3)). Eicosapentaenoic acid (EPA, 20:5(n-3)) levels were 5–6% in Alvinella pompejana and A. caudata and 10.3–13.7% in an errantiate polychaete (likely Hesionidae) and Hesiolyra bergii. There were greater PUFA and a greater EPA/AA (AA is arachidonic acid, 20:4(n-6)) ratio in the anterior versus the posterior half of A. pompejana, which may correlate to the strong temperature gradient reported in its tube. Total nonmethylene interrupted diunsaturated fatty acids (NMID) were 4–9% of total FA for most polychaete species and included several 20:2 and 22:2 components. The principal monounsaturated fatty acids (MUFA) included 18:1(n-7)c (14–19%), 16:1(n-7)c (2.6–10%) and 20:1(n-11)c (3–7% of total FA). These polychaete species may desaturate and elongate the bacterial-derived 18:1(n-7)c to obtain the essential FA EPA and AA. The major ST in the polychaetes is cholesterol (89–98% of total ST) with less cholesterol in the gut contents of A. pompejana. Other ST included 24-ethylcholesterol (1.5–5% of total ST) with lesser amounts of 24-methylenecholesterol, desmosterol, lathosterol, 24-methylcholesterol, 24-ethylcholesterol, and the stanols dehydrocholestanol and cholestanol. The high ST levels could play a role in thermal adaptation of membranes at the hydrothermal vent environment. Differences in the FA profiles separated the closely related species A. pompejana and A. caudata from Paralvinella grasslei, H. bergii, and the errantiate polychaete (likely Hesionidae).     

陕西省略阳县杨家坝多金属矿区成矿作用地球化学示踪

本文以陕西省略阳县杨家坝多金属矿区为例,通过对该矿区岩(矿)石和各类脉体的岩相学、稀土和微量元素及流体包裹体地球化学示踪发现,多金属中重晶石的形成及硅化、碳酸盐化、滑石化、纤闪石化、绢云母化和绿泥石化和透闪石岩的含氟浅闪石及隐晶硅质玻璃和微晶硅质,这表明与成矿蚀变有关的热液流体是一种不同于一般地壳流体的富硅、钛、铁、碱质和挥发份,并具备熔体性质的成矿流体。各类样品的稀土元素配分模式明显富集LREE,在Ce、Eu、Yb异常的组合上也各具特征。LREE富集是地幔流体作用的显著特征之一;矿石和脉体的负Ce、正Eu和负Yb异常以及流体包裹体中H2O-C6H6成分,是高温还原地幔流体的重要标志;正Ce和负Eu异常的出现,以及Ce、Eu、Yb异常的减弱和消失则是壳幔混染叠加改造的显示。综合研究表明:矿区成矿过程可能统一受制于秦岭地区碰撞造山背景下具高温还原性质的地幔流体作用,且由此引发壳幔强烈混染的叠加改造作用在成矿过程中发挥了重要作用。     

Effect of adsorbed iron on thermoluminescence and electron spin resonance spectra of Ca-Fe-exchanged montmorillonite

The electron spin resonance (ESR) spectra and the natural and gamma-induced thermoluminescence (TL) glow curves of a series of variably cation-exchanged Fe-Ca-clays prepared from SWy-1 montmorillonite were examined. The ESR signal (g = 2) intensity associated with the surface Fe was found to increase linearly with surface Fe content up to a nominal concentration of 50% exchangeable Fe. At > 50% exchangeable Fe, no appreciable increase in the signal was noted. The TL intensity decreased linearly with increasing surface Fe up to 50% nominal exchangeable Fe. At > 50%, the signal was not appreciably further diminished. The natural TL showed only a high-temperature peak, but irradiation produced an additional low-temperature peak. One month after gamma-irradiation, the integrated TL signal was still 10-100 times higher than that from the non-irradiated material. Thus, (1) surface iron clusters may form above a certain critical Fe concentration; (2) the Fe clusters are probably less effective in quenching TL than are single Fe atoms, implying interaction between surface Fe and the stored energy content of the material; and (3) the electronic energy stored in the material as the result of gamma-irradiation is only slowly dissipated.     

Bio-treatment and water reuse as feasible treatment approaches for improving wastewater management during flotation of copper ores

Established and emerging technologies for treatment of flotation wastewaters are compared and discussed in the context of their applicability during the management of wastewaters from Cu–Co ores processing through flotation in the Katanga province of the Democratic Republic of Congo. The effects from water recycling on water quality and flotation performance are briefly presented in parallel. The ore processing schemes and the wastewater management practices at two operational concentrators are illustrated as study cases and their peculiarities outlined. A reference to a copper concentrator in a nearby Zambia is addressed for comparative purpose. Based on analysis of the findings, the clarification, bio-treatment inside the tailing ponds or the use of constructed wetlands as polishing stage prior to water reuse are suggested as feasible treatment approaches in view improving the management practice of flotation wastewaters during the dressing of copper ores in the Katanga province.     

Characterization of dehydration-induced luminescence of kaolinite

Dehydration-induced luminescence (DIL), the emission of light from a clay paste upon dehydration, was characterized experimentally for a colloidal kaolinite. The relationship between total photon count of the emitted light and film thickness is linear up to a thickness of 30 micrometers. The photon emission was obtained over a critical range of water contents (25-60%) of the oven-dry clay, and the kinetics of photon emission was presumed to be closely associated with the kinetics of film dehydration. Whether drying proceeded throughout the bulk or via a moving front was undetermined, but in either mode it was preceded by the formation of a thin dry film at the interface with the atmosphere. Grinding of the kaolinite for several minutes by mortar and pestle before paste preparations resulted in an overall increase of photon emission compared to unground kaolinite and in the formation of more than one emission peak, as well as a prolongation of the light emission. This effect on the kinetics of light emittance was observed for about two months after the application of the mechanical stress and suggests a means of detecting the mechanical stress history of a clay. An estimate was made of the spectral characteristics of the emitted light using optical filters and by incorporating tryptophan and salicylic acid into the kaolinite paste where they acted as fluorescent probes. The latter technique shifted the frequency of the light emitted by the kaolinite from the ultraviolet to the visible range where it was less effectively reabsorbed. The first method showed that the wavelengths of 97% of the emitted light was <460 nm and that 75% of the light had wavelengths < 410 nm. The second method showed that the total intensity of DIL increased in the presence of fluorescence molecules, suggesting that the emittance was in the ultraviolet range.     

Nitrite reduction by Fe(II) associated with kaolinite

Interactions of iron (Fe) with the nitrogen (N) cycle have emerged and contain elements of abiotic and biological reactions. One such abiotic reaction which has received little study is the reactivity of NO₂ ^? and Fe(II) associated with a major clay mineral, kaolinite. The main objective of this study was to evaluate the reactivity of NO₂ ^? with Fe(II) added to kaolinite under anoxic conditions. Stirred batch reactivity experiments were carried out with 10 g L^?1 kaolinite spiked with 25 and 100 µM Fe(II) at pH 6.45 in an anaerobic chamber. Approximately 500 µM NO₂ ^? was added to initiate the reaction with Fe(II)-loaded kaolinite. The rate of nitrite removal from solution was 2.4-fold slower in the high Fe(II) treatment when compared with the low Fe(II) treatment. A large portion of the NO₂ ^? removed from solution was confirmed to be reduced to N₂O_(g) in the Fe(II)-kaolinite slurries. However, NO₂ ^? reduction was also noticed in the presence of kaolinite-alone and to somewhat lesser extent in the presence of dithionite-citrate-bicarbonate (DCB)-treated kaolinite. Chemical extractions coupled with infrared spectroscopy suggest that Fe(III) oxide mineral impurities and structural Fe(III) in kaolinite may participate in NO₂ ^? removal from solution. Furthermore, a magnetite mineral was identified based on X-ray diffraction analysis of untreated kaolinite and DCB-treated kaolinite. Our findings reveal a novel pathway of NO₂ ^? transformation in the environment in the presence of Fe(II) associated (sorbed and impurity) with kaolinite.