Recent extreme slope failures in glacial environments: effects of thermal perturbation

This paper describes recent exceptional slope failures in high-mountain, glacial environments: the 2002 Kolka–Karmadon rock–ice avalanche in the Caucasus, a series of ice–rock avalanches on Iliamna Volcano, Alaska, the 2005 Mt. Steller rock–ice avalanche in Alaska, and ice and rock avalanches at Monte Rosa, Italy in 2005 and 2007. Deposit volumes range from 10⁶ to 10⁸ m³ and include rock, ice and snow. Here we focus on thermal aspects of these failures reflecting the involvement of glacier ice and permafrost at all sites, suggesting that thermal perturbations likely contributed to the slope failures. We use surface and troposphere air temperatures, near-surface rock temperatures, satellite thermal data, and recent 2D and 3D thermal modeling studies to document thermal conditions at the landslide sites. We distinguish between thermal perturbations of volcanic-geothermal and climatic origin, and thermal perturbations related to glacier–permafrost interaction. The data and analysis support the view that recent, current and future climatic change increases the likelihood of large slope failures in steep glacierized and permafrost terrain. However, some important aspects of these settings such as the geology and tectonic environment remain poorly understood, making the identification of future sites of large slope instabilities difficult. In view of the potentially large natural disasters that can be caused by such slope failures, improved data and understanding are needed.     

Monitoring selective availability dither frequencies and their effect on GPS data

Summary The signals transmitted by Block II satellites of the Global Positioning System (GPS) can be degraded to limit the highest accuracy of the system (10 m or better point positioning) to authorized users. This mode of degraded operation is called Selective Availability (S/A). S/A involves the degradation in the quality of broadcast orbits and satellite clock dithering. We monitored the dithered satellite oscillator and investigated the effect of this clock dithering on high accuracy relative positioning. The effect was studied over short 3-meter and zero-baselines with two GPS receivers. The equivalent S/A effects for baselines ranging from 0 to >10,000 km can be examined with short test baselines if the receiver clocks are deliberately mis-synchronized by a known and varying amount. Our results show that the maximum effect of satellite clock dithering on GPS double difference phase residuals grows as a function of the clock synchronization error according to: S/A _effect =0.04 cm/msec, and it increases as a function of baseline length like: S/A _effect =0.014 cm/100 km. These are equations for maximum observed values of post-fit residuals due to S/A. The effect on GPS baselines is likely to be smaller than the 0.14 mm for a baseline separation of 100 km. We therefore conclude, for our limited data set, and for the level of S/A during our tests, that S/A clock dithering has negligible effect on all terrestrial GPS baselines if double difference processing techniques are employed and if the GPS receivers remain synchronized to better than 10 msec. S/A may constitute a problem, however, if accurate point processing is required, or if GPS receivers are not synchronized. We suggest and test two different methods to monitor satellite frequency offsets due to S/A. S/A modulates GPS carrier frequencies in the range of-2 Hz to +2 Hz over time periods of several minutes. The methods used in this paper to measure the satellite clock dither could be applied by the civilian GPS community to continuously monitor S/A clock dithering. The monitored frequencies may aid high accuracy point positioning applications in a postprocessing mode (Malys and Ortiz 1989), and differential GPS with poorly synchronized receivers (Feigl et al. 1991).     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

Restructuring of polygalacturonate on alumina upon hydration—Effect on phosphate sorption kinetics

Hydration of organic coatings in soils is expected to affect the sorption of oxyanions onto hydrous Fe and Al oxides. We hypothesized that the hydration of polygalacturonate (PGA) coatings on alumina (Al₂O₃) increases their permeability for phosphate. Pure and PGA-coated alumina were equilibrated in deionized water for 2 and 170 h at pH 5 and 20 °C before studying (i) their porosity with N₂ gas adsorption and ¹H NMR relaxometry, (ii) structural changes of PGA-coatings with differential scanning calorimetry (DSC), and (iii) the kinetics of phosphate sorption and PGA desorption in batch experiments. Scanning electron micrographs revealed that PGA molecules formed three-dimensional networks with pores ranging in size from <10 to several hundred nanometers. Our NMR results showed that the water content of intraparticle alumina pores decreased upon PGA sorption, indicating a displacement of pore water by PGA. The amount of water in interparticle alumina pores increased strongly after PGA addition, however, and was attributed to water in pores of PGA and/or in pores at the PGA-alumina interface. The flexibility of PGA molecules and the fraction of a PGA gel phase increased within one week of hydration, implying restructuring of PGA. Hydration of PGA coatings increased the amount of phosphate defined as instantaneously sorbed by 84%, showing that restructuring of PGA enhanced the accessibility of phosphate to external alumina surfaces. Despite the fact that the efficacy of phosphate to displace PGA was higher after 170 h than after 2 h, a higher phosphate surface loading was required after 170 h to set off PGA desorption. Our findings imply that the number of PGA chain segments directly attached to the alumina surface decreased with time. We conclude that hydration/dehydration of polymeric surface coatings affects the sorption kinetics of oxyanions, and may thus control the sorption and transport of solutes in soils.     

A method to reduce the influence of ice-rafted debris on a grain size record from northern Fram Strait, Arctic Ocean

The granulometric composition of terrigenous deep-sea sediments provides information on current speed if certain frame conditions are fulfilled. These include that current transport is the only transport process. At high latitudes this type of investigation is impaired due to the influence of ice-rafted debris (IRD) which contaminates the current-sorted grain size fractions. This study presents a new method that addresses this problem by setting the ice-rafted sand in relation to the silt of both current- and ice-transported origin. Deviations from the resulting regression function are then used to determine the behaviour of the silt mean grain size as a function of current speed largely independent from IRD bias. The study is based on sediments from the Yermak Plateau, Arctic Ocean, a region influenced by IRD brought with the south-headed Transpolar Drift and by north-directed bottom currents. The IRD correction results in displaying changes of current speed at much higher clarity; climate forcing of the currents becomes more evident. For example, the 8200 year cold event shows up as a major event in the corrected record whereas it is hardly visible in the original record.