Tensile stresses around boreholes due to transient fluid flow

We present solutions for the effective stress induced by gas flow through a porous solid into a borehole resulting from sudden pressure reduction. Tensile effective stress that exceeds the strength of the solid will lead to borehole failure. This has applications to the intentional creation of cavities, relevant to the efficient recovery of coalbed methane, and the avoidance of borehole stability problems in conventional gas production.     

Late Holocene relative sea level rise and the Neoglacial history of the Greenland ice sheet

In West Greenland, early and mid Holocene relative sea level (RSL) fall was replaced by late Holocene RSL rise during the Neoglacial, after 4–3 cal. ka BP (thousand calibrated years before present). Here we present the results of an isolation basin RSL study completed near to the coastal town of Sisimiut, in central West Greenland. RSL fell from 14 m above sea level at 5.7 cal. ka BP to reach a lowstand of ?4.0 m at 2.3–1.2 cal. ka BP, before rising by an equivalent amount to present. Differences in the timing and magnitude of the RSL lowstand between this and other sites in West and South Greenland record the varied interplay of local and non‐Greenland RSL processes, notably the reloading of the Earth's crust caused by a Neoglacial expansion of the Greenland Ice Sheet (GIS) and the subsidence associated with the collapse of the Laurentide Ice Sheet forebulge. This means that the timing of the sea level lowstand cannot be used to infer directly when the GIS advanced during the Neoglacial. The rise in Late Holocene RSL is contrary to recently reported bedrock uplift in the Sisimiut area, based on repeat GPS surveys. This indicates that a belt of peripheral subsidence around the current ice sheet margin was more extensive in the late Holocene, and that there has been a switch from subsidence to uplift at some point in the last thousand years or so. Copyright © 2008 John Wiley & Sons, Ltd.     

Mineralogical sources of the buffer capacity in a granite catchment determined by strontium isotopes

The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The ⁸⁷Sr/⁸⁶Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering.     

The Messinian Sicilian stratigraphy revisited: new insights for the Messinian salinity crisis

Controversies around the Messinian salinity crisis (MSC) are because of the difficulties in establishing genetic and stratigraphic relationships between its deep and shallow‐water record. Actually, the Sicilian foreland basin shows both shallow and deep‐water Messinian records, thus offering the chance to reconstruct comprehensive MSC scenarios. The Lower Gypsum of Sicily comprises primary and resedimented evaporites separated in space and time by the intra‐Messinian unconformity. A composite unit including halite, resedimented gypsum and Calcare di Base accumulated between 5.6 and 5.55 Ma in the main depocentres; it records the acme of the Messinian Salinity Crisis during a tectonic phase coupled with sea‐level falls at glacials TG14‐TG12. These deposits fully post‐date primary gypsum, which precipitated in shallow‐water wedge‐top and foreland ramp basins between 5.96 and 5.6 Ma. This new stratigraphic framework results in a three‐stage MSC scenario characterized by different primary evaporite associations: selenite in the first and third stages, carbonate, halite and potash salt in the second one associated with hybrid resedimented evaporites.     

Observations of a fast burst of the deep western boundary undercurrent and sediment transport in South Wilmington Canyon from DSRVAlvin

On October 3 and 4, 1986, DSRVAlvin dives encountered a strong current at 2,300 m in South Wilmington Canyon. The current, estimated at 1 knot, transported surficial sediment and constructed and modified bedforms. It appears to have been constant in its direction of flow from 30 to 40°. The observed current was probably a burst of fast flow in a region of slow average currents in the Deep Western Boundary Undercurrent. Such episodic events may have a greater influence on the stratigraphic record than the temporally longer more tranquil flow conditions.     

Colonization, succession, and nutrition of macrobenthic assemblages in a restored wetland at Tijuana Estuary, California

Modes of colonization, the successional trajectory, and trophic recovery of a macrofaunal community were analyzed over 19 months in the Friendship marsh, a 20-acre restored wetland in Tijuana Estuary, California. Traditional techniques for quantifying macrofaunal communities were combined with emerging stable isotopic approaches for evaluation of trophic recovery, making comparisons with a nearby natural Spartina foliosa habitat. Life history-based predictions successfully identified major colonization modes, although most taxa employed a variety of tactics for colonizing the restored marsh. The presence of S. foliosa did not seem to affect macrofaunal colonization or succession at the scale of this study. However, soil organic matter content in the restored marsh was positively correlated with insect densities, and high initial salinities may have limited the success of early colonists. Total macrofaunal densities recovered to natural marsh levels after 14 months and diversity, measured as species richness and the Shannon index (H′), was comparable to the natural marsh by 19 months. Some compositional disparities between the natural and created communities persisted after 19 months, including lower percentages of surface-feeding polychaetes (Polydora spp.) and higher percentages of dipteran insects and turbellarians in the Friendship marsh. As surficial structural similarity of infaunal communities between the Friendship and natural habitat was achieved, isotopic analyses revealed a simultaneous trajectory towards recovery of trophic structure. Enriched δ¹³C signatures of benthic microalgae and infauna, observed in the restored marsh shortly after establishment compared to natural Spartina habitat, recovered after 19 months. However, the depletion in δ¹⁵N signatures of macrofauna in the Friendship marsh indicated consumption of microalgae, particularly nitrogen-fixing cyanobacteria, while macroalgae and Spartina made a larger contribution to macrofaunal diets in the natural habitat. Future successional studies must continue to develop and employ novel combinations of techniques for evaluating structural and functional recovery of disturbed and created habitats.     

A Stable Carbon Isotope Study of the Food-web in a Freshwater-deprived South African Estuary, with Particular Emphasis on the Ichthyofauna

The importance of macrophytes as food sources for estuarine nekton is unclear. Previous carbon isotope investigations in the macrophyte-dominated, freshwater-deprived Kariega Estuary showed that the bivalveSolen cylindraceusdid not utilize the dominant estuarine macrophytes found within the estuary as a primary food source. This finding prompted questions as to what the nekton of this estuary utilize as primary energy sources. δ¹³C analyses of the principal autochthonous and allochthonous primary carbon sources, as well as the dominant invertebrate and fish species, indicate that there are two main carbon pathways within the Kariega Estuary. The littoral community, which incorporates the majority of crustaceans, gobies, mullet and a sparid, utilizes δ¹³C enriched primary food sources namelySpartina maritima,Zosteracapensis and epiphytes. The channel fauna, which includes the zooplankton, zooplanktivorous and piscivorous fish, utilizes a primary food source depleted in δ¹³C, which is most likely a mixture of phytoplankton, terrestrial plant debris and C₄macrophyte detritus. The C₃saltmarsh macrophytesSarcocornia perennisandChenolea diffusa, as well as benthic microalgae, appear to be less important as primary food sources to the nekton of the Kariega Estuary.     

Evidence for inherited Sm−Nd isotopes in granitoid zircons

This study presents evidence to show that, in addition to preserving U–Pb isotope systematics, refractory zircons also preserve, at least in part, an inherited Sm–Nd isotope component. The zircons analyzed during this study were taken from the Strontian granitoid (NW Scotland). The inner intrusion of this composite pluton is known from a previous study to contain substantial U–Pb zircon inheritance, whereas the outer part has only minor inheritance. Zircons from the inner intrusion were found to have significantly lower Nd₄₂₅ values than either their host rock, separated apatite or monazite. It is argued that this isotopic disequilibrium is due to the presence of an inherited Sm–Nd isotope component, rather than being due to a post-crystallization disturbance of the zircons. The preservation of inherted Sm–Nd isotopes within refractory zircons implies that they remain closed systems with respect to the diffusion of Sm and Nd (and presumably the other REE) to temperatures in excess of 700°C. The fact that zircons commonly have high Sm/Nd ratios, relative to sialic crustal material, means that the Nd isotopic evolution of inherited zircons will be very different to that of much of the continental crust.