The mechanism of structural and chemical transformations of tantalite,columbite, and zircon surfaces in the process of acid and electrochemical treatment of mineral suspensions

The results of experimental studies and scientific substantiation of an effect of directional change in the chemical and phase composition of the surface and increase in the contrast of physicochemical and electrical properties of tantalite, columbite, and zircon in the course of treatment with anolyte (pH < 5) and a hydrochloric acid solution (HCl, pH 3–3.5) are reported. The mechanism of structural and chemical transformations of the mineral surface in the process of leaching with acid solutions are studied. This mechanism includes the activation of oxidation of iron atoms in the surface layer of tantalite and columbite with the transition from Fe(II) to Fe(III), destruction of the zircon surface with the formation of oxygen–vacancy defects of the SiO ^2-₃ - and SiO ⁰₂ -types, and intense dissolution of iron- and silicate-bearing films from the surface of rare-metal minerals.

     

Large-volume platinum ore deposits in zonal mafic-ultramafic complexes of the Ural-Alaskan type and the outlook for their development

The results of mineralogical-technological studies of PGM mineralization in zonal mafic-ultramafic complexes of the Ural-Alaskan type are given. All studied massifs in the Urals and Kamchatka are characterized by similar evolution of mineral assemblages. The chromite (platinum-chromitite-dunite) and dunite (platinum-pegmatoid dunite) geological-economic types of small platinum deposits and occurrences are separate enriched sites (ore shoots) of large-volume platinum ore deposits. These are rather thick and extended zones of recrystallized dunites with attributes of high-temperature structural deformations and intense fluid reworking. Low Pt grade in ore (<0.5 gpt) is determined by fine and very fine (grain size class — 80 μm) euhedral PGM crystals distributed rather uniformly in ore mass. The high and occasionally anomalous Pt contents (up to 1 kgpt and higher) are related to large xenomorphic segregations of PGM, which concentrate largely in the marginal parts of separate chromite segregations. The significant part of productive Pt-bearing mineralization is hosted in olivine matrix of igneous rocks, so that recovery of platinum cannot be associated only with separation of chromite ore. The direct gravity concentration of platinum ore without preliminary separation of chromite concentrate is recommended as the main technique of platinum recovery. The technological scheme provides for two-stage comminution of ore with between-cycle separation of coarse the PGM fraction into the concentrate as a commodity product. The results obtained allow us to regard the aforementioned mineralization as a new geological and economic type of lode platinum deposits, whose potential is comparable with active platinum reserves in the complex Cu-Ni ores of the Noril’sk district.     

Innovation processes in technologies for the processing of refractory mineral raw materials

Analysis of the grade of mineral resources of Russia and other countries shows that end products that are competitive in terms of both technological and environmental criteria in the world market can only be obtained by the development and implementation of progressive technologies based on the up-to-date achievements of fundamental sciences. The essence of modern innovation processes in technologies developed in Russia for the complex and comprehensive processing of refractory raw materials with a complex composition is ascertained. These processes include (i) radiometric methods of concentration of valuable components, (ii) high-energy methods of disintegration of highly dispersed mineral components, and (iii) electrochemical methods of water conditioning to obtain target products for solving specific technological problems.     

New technologies of comprehensive recovery of valuable components from minerals: Current status and further progress

The main lines of basic research in the field of comprehensive processing of minerals are considered, and the current status of development of new technologies in Russia and abroad is compared. Alternative processes of intergranular disintegration of mineral complexes, as well as highly efficient and environmentally safe technologies of refractory ore processing, are discussed.     

The accuracy of observations of the Galilean satellites of Jupiter taken at the Abastumani Astrophysical Observatory of the Academy of Sciences of Georgia

The sets of photographic observations of the Galilean satellites of Jupiter taken at the Abastumani Astrophysical Observatory of the Academy of Sciences of Georgia are analyzed here. Positional observations of the system of Jupiter were made in the period from 1985 to 1994 with the use of the double Zeiss astrograph in order to determine the exact coordinates of Jupiter and its satellites. The accurate positions of the satellites and Jupiter itself, as well as their stellar (equatorial) coordinates relative to the stars of the currently available catalogs and the relative ??satellite ?? satellite?? coordinates were obtained from the observations. From the comparison of the observation results with the modern theories of motion of satellites, the accuracy in determining the positions of the satellites and Jupiter was analyzed. The results of observations are presented in the Pulkovo database of observations of Solar System bodies that is accessible to users at http://www.puldb.ru.     

Astrometric observations of planetary satellites at the Abastumani Astrophysical Observatory

We present and discuss the results of the astrometry project during which we observed the satellites of Mars, Jupiter, Saturn, Uranus, and Neptune at the Abastumani Astrophysical Observatory (Georgia) between 1983 and 1994. Observations at the Abastumani Observatory were performed with the double Zeiss astrograph (DZA: D/F = 400/3024 mm) and AZT-11 telescope (F = 16 m). We processed a large array of observations and determined exact coordinates of the planets and their satellites in a system of reference stars of modern catalogues as well as relative coordinates of the satellites. The results were compared with modern ephemerides using the MULTI-SAT software. The comparison enabled us to estimate the accuracy of observations (their random and systematic uncertainties) and the accuracy of modern theories of the motion of planets and their satellites. Random uncertainties of observations are estimated to be 0.10??C0.40?? for various objects and observational conditions. Observational results obtained for Uranus, Neptune and the satellites Titania and Oberon were shown to deviate appreciably and systematically from theories of their motion. The results of observations are presented in the Pulkovo database for Solar System bodies that is available at the website http://www.puldb.ru.     

Proper motions,absolute magnitudes and spatial distribution of Zirconium stars

The computational algorithm to determine the the proper motions of Zirconium stars on the basis of catalogues “Carte du Ciel” and on the recent photographic observations carried out with the 70cm Abastumani meniscus telescope is presented. It allowed to determine the proper motions of 288 stars in the region around α Per with a rms error of ± 0,004 arcsec/yr. Applying the method proper motions of 74 Zirconium stars and 146 control stars have been obtained. The error of proper motions obtained for the North Zone (δ > −2°) 109 AGK₃ control stars is ± 0.006 arcsec/yr. On the basis of proper motins absolute magnitudes were separately calculated for the MCLPZS and LASZS. For the MCLPZS the average absolute visual magnitude at maximum, corresponding to the mean period of P = 350 days, equals −3^ϕm.9. For the LASZS the mean absolute visual magnitude, corresponding to the apparent median ones equals −1^ϕm.9. Low luminosity (M_v = −1^ϕmϕ9) Zirconium stars escape rather far (at a distance of up to 2 kpc) to the South from the Galactic plane into the region l ∼ 240 – 260°, where its assumed to be a connection with the Large Magellanic Cloud (LMC) begins to appear. Low luminosity Zirconium stars are weakly correlated with position of the Galaxy spiral arms. The MCLPZS show a somewhat other distribution.     

Physicochemical and Energy Impact on the Process of Leaching of a Eudialyte Concentrate

Doklady Earth Sciences - The results of an experimental study of alkaline decomposition of eudialyte concentrate when exposed to physicochemical and energy impacts prior to the subsequent acid...