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1.
Theoretical line ratios involving 2s
2
S - 3p
2
P, 2p
2
P - 3s
2
S, and 2p
2
S - 3d
2
D transitions inCiv between 312 and 420 Å are presented. A comparison of these with solar active region observational data obtained during a rocket flight by the Solar EUV Rocket Telescope and Spectrograph (SERTS) reveals good agreement between theory and experiment, with discrepancies that average only 22%. This provides experimental support for the accuracy of the atomic data adopted in the line ratio calculations, and also resolves discrepancies found previously when the theoretical results were compared with solar data from the S082A instrument on boardSkylab. The potential usefulness of theCIV line ratios as electron temperature diagnostics for the solar transition region is briefly discussed. 相似文献
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Metals in contaminated salt marshes are mainly locked in the anaerobic layer of sediments, where they are tightly bound as sulfides and organic complexes. Vascular plants survive in saturated soils in part by pumping O2 into their root zones, changing their microenvironment to an oxic one. This, along with chelating exudates, mobilizes metals, allowing uptake by the roots. We compared the common reed Phragmites australis and cordgrass Spartina alterniflora in lab and field studies for ways in which they handle trace metals. Both plants store most of their metal burden in their roots, but some is transported to aboveground tissues. Spartina leaves contain approximately 2-3 x more Cr, Pb, and Hg than Phragmites leaves, but equivalent Cu and Zn. Furthermore, Spartina leaves have salt glands, so leaf excretion of all metals is twice that of Phragmites. In-depth studies with Hg indicate that Hg excretion correlates with Na release but not with transpiration, which is 2.2 x higher in Phragmites; and that more Hg accumulates in early-appearing leaves than in upper (i.e. later) leaves in both species. Spartina thus makes more metals available to salt marsh ecosystems than Phragmites by direct excretion and via dead leaves which will enter the food web as detritus. 相似文献
4.
Maria Luce Frezzotti Gianfranco Di Vincenzo Claudio Ghezzo Ernst A. J. Burke 《Contributions to Mineralogy and Petrology》1994,117(2):111-123
Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO2+H2O inclusions + Al2SiO5 ± brines in garnet (type 1); early CO2-rich inclusions (± brines) in quartz (type 2); early CO2+CH4 (up to 4 mol%)±H2O inclusions + graphite + fibrolite in quartz (type 3); late CH4+CO2+N2 inclusions and H2O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO2-rich, possibly with immiscible brines. CO2-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off
O
2 can entering in the graphite stability field; at the same time, the feldspars reacted with CO2-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf
O
2 can explain the progressive variation in the fluid composition from CO2-rich to CH4 and water dominated in a closed system (in situ evolution). The presence of N2 the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility 相似文献
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L. D. Ashwal R. A. Armstrong R. J. Roberts M. D. Schmitz F. Corfu C. J. Hetherington K. Burke M. Gerber 《Contributions to Mineralogy and Petrology》2007,153(4):389-403
Nepheline-bearing gneisses from the 75 km2 Tambani body in the Mozambique Belt of southern Malawi, are miaskitic biotite-nepheline monzodiorites, reflecting an absence
of K-feldspar, alkali amphiboles or pyroxenes, and contain euhedral zircon megacrysts up to 5 cm across. The zircons contain
U = 1–1,860 ppm, Th = 0–2,170 ppm and Y = 400–1,100 ppm, and very low concentrations of all other measured trace elements
except Hf (HfO2 = 0.53–0.92 wt. %). Cathodoluminescence images reveal oscillatory sector growth zoning and no evidence for xenocrystic cores,
indicating that the zircons represent primary magmatic crystallization products that have survived amphibolite grade metamorphism.
U-Pb isotopic analyses (by TIMS) yield an upper intercept age of 730 ± 4 Ma (MSWD = 1.7), which we interpret as the time of
magmatic crystallization of the zircons. This is coincident with 11 SHRIMP spot analyses, which yield a mean age of 729 ±
7 Ma (MSWD = 0.37). Metamorphism, at 522 ± 17 Ma as suggested by monazite, caused partial Pb-loss during local recrystallization
of zircon. Lu-Hf isotopic data for three whole-rock samples of nepheline-bearing gneiss are collinear with those for zircon
megacrysts, and correspond to an age of 584 ± 17 Ma (MSWD = 0.37. We interpret the Lu-Hf array to represent a mixing line
defined by the Hf isotopic signature of primary zircon and that of the rock-forming minerals reset during metamorphic (re-)crystallization;
hence the 584 Ma age is likely geologically meaningless. Given the well-defined association of nepheline syenites (and phonolitic
volcanic equivalents) with continental rifting, we suggest that the Tambani body represents a magmatic product formed at 730 Ma
during the break-up of the Rodinia supercontinent. The 522 Ma age is akin to other Pan-African metamorphic ages that record
collisional suturing events during the final assembly of Gondwana. Zircon-bearing nepheline gneisses thus preserve a record
of intra-continental rifting and of continental collision in southern Malawi. 相似文献
8.
Tom Bradwell Derek Fabel Chris D. Clark Richard C. Chiverrell David Small Rachel K. Smedley Margot H. Saher Steven G. Moreton Dayton Dove S. Louise Callard Geoff A. T. Duller Alicia Medialdea Mark D. Bateman Matthew J. Burke Neil McDonald Sean Gilgannon Sally Morgan David H. Roberts Colm ó Cofaigh 《第四纪科学杂志》2021,36(5):871-933
Predicting the future response of ice sheets to climate warming and rising global sea level is important but difficult. This is especially so when fast-flowing glaciers or ice streams, buffered by ice shelves, are grounded on beds below sea level. What happens when these ice shelves are removed? And how do the ice stream and the surrounding ice sheet respond to the abruptly altered boundary conditions? To address these questions and others we present new geological, geomorphological, geophysical and geochronological data from the ice-stream-dominated NW sector of the last British–Irish Ice Sheet (BIIS). The study area covers around 45 000 km2 of NW Scotland and the surrounding continental shelf. Alongside seabed geomorphological mapping and Quaternary sediment analysis, we use a suite of over 100 new absolute ages (including cosmogenic-nuclide exposure ages, optically stimulated luminescence ages and radiocarbon dates) collected from onshore and offshore, to build a sector-wide ice-sheet reconstruction combining all available evidence with Bayesian chronosequence modelling. Using this information we present a detailed assessment of ice-sheet advance/retreat history, and the glaciological connections between different areas of the NW BIIS sector, at different times during the last glacial cycle. The results show a highly dynamic, partly marine, partly terrestrial, ice-sheet sector undergoing large size variations in response to sub-millennial-scale climatic (Dansgaard–Oeschger) cycles over the last 45 000 years. Superimposed on these trends we identify internally driven instabilities, operating at higher frequency, conditioned by local topographic factors, tidewater dynamics and glaciological feedbacks during deglaciation. Specifically, our new evidence indicates extensive marine-terminating ice-sheet glaciation of the NW BIIS sector during Greenland Stadials 12 to 9 – prior to the main ‘Late Weichselian’ ice-sheet glaciation. After a period of restricted glaciation, in Greenland Interstadials 8 to 6, we find good evidence for rapid renewed ice-sheet build-up in NW Scotland, with the Minch ice-stream terminus reaching the continental shelf edge in Greenland Stadial 5, perhaps only briefly. Deglaciation of the NW sector took place in numerous stages. Several grounding-zone wedges and moraines on the mid- and inner continental shelf attest to significant stabilizations of the ice-sheet grounding line, or ice margin, during overall retreat in Greenland Stadials 3 and 2, and to the development of ice shelves. NW Lewis was the first substantial present-day land area to deglaciate, in the first half of Greenland Stadial 3 at a time of globally reduced sea-level c. 26 kabp , followed by Cape Wrath at c. 24 kabp. The topographic confinement of the Minch straits probably promoted ice-shelf development in early Greenland Stadial 2, providing the ice stream with additional support and buffering it somewhat from external drivers. However, c. 20–19 kabp , as the grounding-line migrated into shoreward deepening water, coinciding with a marked change in marine geology and bed strength, the ice stream became unstable. We find that, once underway, grounding-line retreat proceeded in an uninterrupted fashion with the rapid loss of fronting ice shelves – first in the west, then the east troughs – before eventual glacier stabilization at fjord mouths in NW Scotland by ~17 kabp. Around the same time, ~19–17 kabp , ice-sheet lobes readvanced into the East Minch – possibly a glaciological response to the marine-instability-triggered loss of adjacent ice stream (and/or ice shelf) support in the Minch trough. An independent ice cap on Lewis also experienced margin oscillations during mid-Greenland Stadial 2, with an ice-accumulation centre in West Lewis existing into the latter part of Heinrich Stadial 1. Final ice-sheet deglaciation of NW mainland Scotland was punctuated by at least one other coherent readvance at c. 15.5 kabp , before significant ice-mass losses thereafter. At the glacial termination, c. 14.5 kabp , glaciers fed outwash sediment to now-abandoned coastal deltas in NW mainland Scotland around the time of global Meltwater Pulse 1A. Overall, this work on the BIIS NW sector reconstructs a highly dynamic ice-sheet oscillating in extent and volume for much of the last 45 000 years. Periods of expansive ice-sheet glaciation dominated by ice-streaming were interspersed with periods of much more restricted ice-cap or tidewater/fjordic glaciation. Finally, this work indicates that the role of ice streams in ice-sheet evolution is complex but mechanistically important throughout the lifetime of an ice sheet – with ice streams contributing to the regulation of ice-sheet health but also to the acceleration of ice-sheet demise via marine ice-sheet instabilities. 相似文献
9.
Richard Christopher Chiverrell Geoff Stephen Powell Thomas Matthew Burke Alicia Medialdea Rachel Smedley Mark Bateman Chris Clark Geoffrey A. T. Duller Derek Fabel Geraint Jenkins Xianjiao Ou Helen Marie Roberts James Scourse 《第四纪科学杂志》2021,36(5):752-779
Here we reconstruct the last advance to maximum limits and retreat of the Irish Sea Glacier (ISG), the only land-terminating ice lobe of the western British Irish Ice Sheet. A series of reverse bedrock slopes rendered proglacial lakes endemic, forming time-transgressive moraine- and bedrock-dammed basins that evolved with ice marginal retreat. Combining, for the first time on glacial sediments, optically stimulated luminescence (OSL) bleaching profiles for cobbles with single grain and small aliquot OSL measurements on sands, has produced a coherent chronology from these heterogeneously bleached samples. This chronology constrains what is globally an early build-up of ice during late Marine Isotope Stage 3 and Greenland Stadial (GS) 5, with ice margins reaching south Lancashire by 30 ± 1.2 ka, followed by a 120-km advance at 28.3 ± 1.4 ka reaching its 26.5 ± 1.1 ka maximum extent during GS-3. Early retreat during GS-3 reflects piracy of ice sources shared with the Irish-Sea Ice Stream (ISIS), starving the ISG. With ISG retreat, an opportunistic readvance of Welsh ice during GS-2 rode over the ISG moraines occupying the space vacated, with ice margins oscillating within a substantial glacial over-deepening. Our geomorphological chronosequence shows a glacial system forced by climate but mediated by piracy of ice sources shared with the ISIS, changing flow regimes and fronting environments. 相似文献
10.
The herring roe fishery in Canada's southern Gulf of St. Lawrence is a productive fishery that lies outside the confines of privatized arrangements. Yet, this fishery is compromised by its dependence on the Japanese seafood market. Consideration of the efficiency of this fishery needs to account for the role assumed by this market in setting fishing practices. A more ecologically and economically efficient use of the herring resource requires greater attention to supply chain integration by local harvesters, processors and buyers prior to engaging with distant markets. This is necessary regardless of the property rights regime that is in place. 相似文献