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Assessment of groundwater vulnerability to pollution in Dire Dawa,Ethiopia using DRASTIC 总被引:1,自引:0,他引:1
Assessment of groundwater vulnerability to pollution is an effective tool for the delineation of groundwater protection zones.
DRASTIC approach was used to determine vulnerability zones in Dire Dawa groundwater basin, a semiarid region of Ethiopia.
Maps of the seven DRASTIC parameters were prepared. GIS-ArcView was used for mapping and performing weighted-overlay analysis.
The result of the analysis indicated that eastern part of the study area, in which Dire Dawa town is located, is highly vulnerable.
A low aquifer vulnerability class was determined for the western portion of the study area as a result of greater groundwater
depths, higher relative soil-clay content, and relatively low recharge rates for this area. The area between the two zones
is of medium vulnerability. Observed nitrate concentrations in boreholes are in accordance with the vulnerability map. Some
of the boreholes in the Sabian well field (Dire Dawa area) already deliver groundwater with nitrate levels significantly exceeding
health standards set by the World Health Organization, while boreholes in the western part (low vulnerability zone) contain
almost no nitrate. The result of this study is useful for risk assessments and for the development of effective groundwater
management strategies for this region and others like it. 相似文献
4.
Groundwater arsenic (As) concentrations above 10 μg/L (World Health Organization; WHO standard) are frequently found in the Titas Upazila in Bangladesh. This paper evaluates the groundwater chemistry and the mechanisms of As release acting in an underground aquifer in the middle-northeast part of the Titas Upazila in Bangladesh. Previous measurements and analyses of 43 groundwater samples from the region of interest (ROI) are used. Investigation is based on major ions and important trace elements, including total As and Fe in groundwater samples from shallow (8–36 m below ground level: mbgl) and deep (85–295 mbgl) tube wells in the aforementioned ROI. Principal hydrochemical facies are Ca–HCO3, with circumneutral pH. The different redox-sensitive constituents (e.g., As, Fe, Mn, NH4, and SO4) indicate overlapping redox zones, leading to differences regarding the redox equilibrium. Multivariate statistical analysis (factor analysis) was applied to reduce 20 chemical variables to four factors but still explain 81% of the total variance. The component loadings give hints as to the natural processes in the shallow aquifers, in which organic matter is a key reactant. The observed chemistry of As, Fe, and Mn can be explained by simultaneous equilibrium between Fe-oxide and SO4 reduction and an equilibrium of rhodochrosite precipitation/dissolution. A correlation test indicates the likeliness of As release by the reductive dissolution of Fe-oxides driven by the degradation of sediments organic matter. Other mechanisms could play a role in As release, albeit to a lesser extent. Reactive transport modeling using PHREEQC reproduced the observed chemistry evolution using simultaneous equilibrium between Fe-oxide and SO4 reduction and the equilibrium of rhodochrosite dissolution/precipitation alongside organic matter oxidation. 相似文献
5.
Using of a New Field Analysis Method to Investigate the Stability of Arsenic and its Inorganic Species in Aquatic Systems The stability of arsenic species in aquatic systems is limited by the possibilities of chemical and biochemical reactions. Redox reactions and bioalkylation lead to changes of the species ratios. In this work, the stability of As(III) and As(V) was examined at storage of distilled, de-ionized, and drinking water at different conditions (refrigerator/room temperature; daylight/darkness) and additions (sulfuric acid; ascorbic acid). The determination of these species was carried out by a modified spectrophotometric method, suitable for laboratory analysis as well as for field analysis. The results show that chemical oxidation and biochemical reduction can occur. Sulfuric acid is favourable for the stabilization of total arsenic and of the inorganic species. 相似文献
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South-western Greenland constitutes an internationally important wintering area for many seabird species. Several species of management concern have a predominantly near-coastal distribution, though available information about seabird numbers is mostly confined to offshore waters. Here we report on extensive aerial surveys conducted in March 1999, covering the coastal waters (up to 15-20 km from the mainland coast) and fjords of south-west Greenland. The most widespread and numerous species were estimated as 463 000 common eiders ( Somateria mollissima ), 153000 king eiders ( S. spectabilis ), 125000 thick-billed murres ( Uria lomvia ), 94 000 long-tailed ducks ( Clangula hyemails ), and 12 000 black guillemots ( Cepphus grylle ). A total of 19 bird species were recorded. The estimates for common eider and long-tailed duck approximately represent the entire winter population in south-western Greenland while estimates for the other species represent only an unknown proportion since their distribution continues further offshore. Waters around Nuuk and within the Julianehåbsbugten (Julianehåb Bay) area were identified as areas of high seabird density. A large proportion of the common eider population was aggregated in the fjord systems (22%), calling attention to the importance of fjords for this species. In contrast, pelagic seabird species appear to be absent from the fjords. The large winter population of common eider reveals the importance of south-western Greenland as a key wintering area for the eastern Canadian breeding population. The western Greenland breeding population is the only other contributor, probably amounting to no more than 15 000 pairs. 相似文献
7.
Past and future polar amplification of climate change: climate model intercomparisons and ice-core constraints 总被引:1,自引:0,他引:1
V. Masson-Delmotte M. Kageyama P. Braconnot S. Charbit G. Krinner C. Ritz E. Guilyardi J. Jouzel A. Abe-Ouchi M. Crucifix R. M. Gladstone C. D. Hewitt A. Kitoh A. N. LeGrande O. Marti U. Merkel T. Motoi R. Ohgaito B. Otto-Bliesner W. R. Peltier I. Ross P. J. Valdes G. Vettoretti S. L. Weber F. Wolk Y. Yu 《Climate Dynamics》2006,27(4):437-440
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Batch experiments were conducted to study the sorption of uranium on selected clay minerals (KGa-1b and KGa-2 reference kaolinite,
SWy-2 and STx-1b reference montmorillonite, and IBECO natural bentonite) as a function of pH (4–9) and 0.001, 0.01, and 0.025 M
NaCl in equilibrium with the CO2 partial pressure of the atmosphere. Uranium concentrations were kept below 100 μg L−1 to avoid precipitation of amorphous Uranium-hydroxides. Solely PTFE containers and materials were used, because experiments
showed significant sorption at higher pH on glass ware. All batch experiments were performed over a period of 24 h, since
kinetic experiments proved that the common 10 or 15 min are in many cases by far not sufficient to reach equilibrium. Kaolinite
showed much greater uranium sorption than the other clay minerals due to the more aluminol sites available. Sorption on the
poorly crystallized KGa-2 was higher than on the well-crystallized KGa-1b. Uranium sorption on STx-1b and IBECO exhibited
parabolic behavior with a sorption maximum around pH 6.5. Sorption of uranium on montmorillonites showed a distinct dependency
on sodium concentrations because of the effective competition between uranyl and sodium ions, whereas less significant differences
in sorption were found for kaolinite. The presence of anatase as impurity in kaolinite enhanced the binding of uranyl-carbonate
complexes with surface sites. The kinetic of uranium sorption behavior was primarily dependent on the clay minerals and pH.
A multisite surface complexation model without assuming exchange is based on the binding of the most dominant uranium species
to aluminol and silanol edge sites of montmorillonite, respectively to aluminol and titanol surface sites of kaolinite. For
eight surface species, the log_k was determined from the experimental data using the parameter estimation code PEST together
with PHREEQC. 相似文献
10.
Vulnerability of groundwater in Quaternary aquifers to organic contaminants: a case study in Wuhan City,China 总被引:5,自引:0,他引:5
Yanxin Wang Broder J. Merkel Yilian Li Hui Ye Surong Fu Dana Ihm 《Environmental Geology》2007,53(3):479-484
More than 30 organic contaminants were detected in shallow groundwaters at Wuhan, the largest city in central China. Seriously
contaminated groundwaters were from densely populated, industrial and commercial areas. Abnormal concentrations were found
in groundwater from Hankou, downtown Wuhan: trimethylbenzene up to 29 μg/L, tetramethylbenzene up to 866 μg/L, and trichloroethene
up to 9.5 μg/L. Benzene, Toluene, Ethylene and Xylene (BTEX) contamination of groundwater is serious and widespread at Wuhan,
ranging between 0.14 and 25.0 μg/L. Considering the hydrogeological conditions of most Chinese cities, DRAMIC, a modified
version of the widely used DRASTIC model, was proposed by the authors for assessing vulnerability of groundwater to contamination.
The factors D, R, A and I in DRAMIC model are the same as in DRASTIC. The factor topography is ignored. The factor soil media is substituted by a new factor aquifer thickness (M) and the factor hydraulic conductivity of the aquifer by a new factor impact of contaminant (C). The equation for determining the DRAMIC Index is: DRAMIC = 5D
R + 3R
R + 4A
R + 2M
R + 5I
R + 1C
R. The calculated DRAMIC Index can be used to identify areas that are more likely to be susceptible to groundwater contamination
relative to each other. The higher the DRAMIC Index is, the greater the groundwater pollution potential. Applying DRAMIC,
a GIS-based vulnerability map for Wuhan city was prepared. Interestingly, places such as downtown Hankou, where enhanced concentrations
of BTEX have been detected, correspond quite well with those with higher DRAMIC ratings. 相似文献