Speciation of volatile arsenic at geothermal features in Yellowstone National Park

Geothermal features in the Yellowstone National Park contain up to several milligram per liter of aqueous arsenic. Part of this arsenic is volatilized and released into the atmosphere. Total volatile arsenic concentrations of 0.5-200 mg/m³ at the surface of the hot springs were found to exceed the previously assumed nanogram per cubic meter range of background concentrations by orders of magnitude. Speciation of the volatile arsenic was performed using solid-phase micro-extraction fibers with analysis by GC-MS. The arsenic species most frequently identified in the samples is (CH₃)₂AsCl, followed by (CH₃)₃As, (CH₃)₂AsSCH₃, and CH₃AsCl₂ in decreasing order of frequency. This report contains the first documented occurrence of chloro- and thioarsines in a natural environment. Toxicity, mobility, and degradation products are unknown.     

Atmospheric nitrogen inputs into the North Sea: effect on productivity

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.     

Investigation into albedo-controlled energy loss during the last glaciation

In recent years, attention has increasingly been paid to the question of the stability of the earth's climate. It has been observed that changes in climate are usually related to changes in the earth's surface. On this question, Liedtke writes ‘A change in climate can lead to considerable landscape changes’ (Liedtke 1990, p. 38). There seems to be some form of interaction between climate and the condition of the earth's surface. If solar radiation is taken to be the primary energy source for the earth's climate, the question arises as to how insolation affects the character of the earth's surface, and vice versa, how does the character of the earth's surface affect the insolation which occurs? Reconstructions of the last great Pleistocene glaciation 18,000 years ago show that the form of the earth's surface at that time was considerably different to its present form. In view of the interaction mentioned above between climate and earth surface, does this suggest a difference between the earth's radiation budget 18,000 years ago and that of today? If, as is widely believed, the area of the earth's surface covered by ice 18,000 years ago was approximately three times the current area (Liedtke 1990, p. 42), this presumably would have had at least some influence on the earth's radiation budget. The ice-covered areas may have modified the radiation budget by means of their high reflexivity. In other words, an albedo-related loss of radiation may have occurred. The results of this investigations show, that the global radiation budget at 18,000 B.P was about 7- -10% less than that of today.     

Current approaches to MRV in South Africa: a scoping study

It is shown that there are MRV-related activities underway in South Africa, particularly focusing on measuring electricity consumption and monitoring GHG emissions. Yet currently many of these activities happen in parallel systems within multi-polar governance structures. A bottom-up perspective of MRV in South Africa, informed by interviews, workshops, desktop research, and stakeholder consultations, is provided and the systems, data, methodologies, and the institutional environment relevant to a South African MRV system are examined. The development of the local monitoring and evaluation system, and its relevance within the international MRV context, is also discussed. Some recommendations are made: most importantly, there is a need for a coherent approach to be developed, one that is coordinated by government and built on existing MRV systems.     

Water quality in the Great Barrier Reef region: responses of mangrove, seagrass and macroalgal communities

Marine plants colonise several interconnected ecosystems in the Great Barrier Reef region including tidal wetlands, seagrass meadows and coral reefs. Water quality in some coastal areas is declining from human activities. Losses of mangrove and other tidal wetland communities are mostly the result of reclamation for coastal development of estuaries, e.g. for residential use, port infrastructure or marina development, and result in river bank destabilisation, deterioration of water clarity and loss of key coastal marine habitat. Coastal seagrass meadows are characterized by small ephemeral species. They are disturbed by increased turbidity after extreme flood events, but generally recover. There is no evidence of an overall seagrass decline or expansion. High nutrient and substrate availability and low grazing pressure on nearshore reefs have lead to changed benthic communities with high macroalgal abundance. Conservation and management of GBR macrophytes and their ecosystems is hampered by scarce ecological knowledge across macrophyte community types.     

Spatial and isotopic analysis of watershed soil loss and reservoir sediment accumulation rates in Lake Anna, Virginia, USA

Soil erosion and associated sedimentation are a threat to the sustainable use of surface water resources through the loss of volume storage capacity and conveyance of pollutants to receiving water bodies. The RUSLE2 empirical model and isotopic sediment core analyses were used to evaluate watershed erosion and reservoir sediment accumulation rates for Lake Anna, in Central Virginia. A sediment flux rate of 66,000 Mg/year was estimated from the upper basin and land use was determined to be the primary factor contributing to soil erosion. Barren lands and agricultural activities were estimated to contribute the most sediment (>20 Mg/ha/year), whereas forested and herbaceous landscapes were less likely to erode (<0.3 Mg/ha/year). Eleven separate ²¹⁰Pb-based estimates of sediment accumulation were used to construct reservoir-scale sedimentation rates. Sedimentation rates in the upper reaches of the reservoir were variable, ranging from 2.3 to 100 Mg/ha/year, with a median rate of 8.4 Mg/ha/year. Historical sedimentation showed an increase in annual accumulation from 1972 to present. Based on these data the reservoir has experienced a 2% loss of volume storage capacity since impoundment in 1972. Results from this study indicate that Lake Anna is not currently experiencing excessive sedimentation and erosion problems. However, the predominance of highly erosive soils (soil erodibility factor >0.30) within the watershed makes this system highly vulnerable to future anthropogenic stressors.     

The UV cameras on the High Energy Transient Experiment (HETE)

The High Energy Transient Experiment (HETE), scheduled for launch this year, is a small satellite dedicated to multiwavelength observations of -ray and X-ray bursts. The HETE spacecraft will be equipped with gamma-ray detectors, X-ray detectors with a coded mask, and ultraviolet-sensitive CCD cameras. The UV cameras on HETE are wide-field imagers which will a) provide UV images of the regions in which -ray or X-ray bursts are detected, before, duringand after the burst, b) detect UV transients, whether associated with a high-energy transient or not, c) monitor the brightnesses of field stars for variability over a wide range of timescales, and d) serve as star trackers for HETE. In this poster, we describe the HETE UV instrumentation, control software, and data products.     

Power,coalitions and institutional change in South African climate policy

This paper examines power relations, coalitions and conflicts that drive and hinder institutional change in South African climate policy. The analysis finds that the most contested climate policies are those that create distributional conflicts where powerful, non-poor actors will potentially experience real losses to their fossil fuel-based operations. This finding opposes the assumption of competing objectives between emissions and poverty reduction. Yet, actors use discourse that relates to potentially competing objectives between emissions reductions, jobs, poverty reduction and economic welfare.

The analysis relates to the broader questions on how to address public policy problems that affect the two objectives of mitigating climate change and simultaneously boosting socio-economic development. South Africa is a middle-income country that represents the challenge of accommodating simultaneous efforts for emissions and poverty reduction.

Institutional change has been constrained especially in the process towards establishing climate budgets and a carbon tax. The opposing coalitions have succeeded in delaying the implementation of these processes, as a result of unequal power relations. Institutional change in South African climate policy can be predominantly characterized as layering with elements of policy innovation. New policies build on existing regulations in all three cases of climate policy examined: the climate change response white paper, the carbon tax and the renewable energy programme. Unbalanced power relations between coalitions of support in government and civil society and opposition mainly from the affected industry result in very fragile institutional change.

Key policy insights

• The South African government has managed to drive institutional change in climate policy significantly over the past 7 years.

• Powerful coalitions of coal-related industries and their lobbies have constrained institutional change and managed to delay the implementation of carbon pricing measures.

• A successfully managed renewable energy programme has started to transform a coal- and nuclear-powered electricity sector towards integrating sustainable energy technologies. The programme is vulnerable to intergovernmental opposition and requires management at the highest political levels.

• Potential conflict with poverty reduction measures is not a major concern that actively hinders institutional change towards climate objectives. Predominantly non-poor actors frequently use poverty-related discourse to elevate their interests to issues of public concern.