The natural high-pressure phase of cubic CdSe in impact glass from Zhamanshin crater

A CdSe high-pressure polymorph of the NaCl structural type of a₀ = 0.549 nm and Fm–3m space group was discovered in nature for the first time. Its composition is within range of CdSe–CdSe_1–х where x = 0.2 apfu. The phase was discovered as abundant nanosize inclusions in irgizite-type condensate glass separated from the sample of impact rock of the Zhamanshin crater (Central Kazakhstan). The treated mineral was presumably formed within a gas–plasma cloud at the moment of impact.     

Geochemical features of the utilization of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant using acid leaching

The decontamination of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant is complicated by the geochemical features of the waste composition: low sulfide and high carbonate content, polyelemental composition, and considerable amounts of technogenic admixtures (kerosene, oils, soda, and soluble glasses). These circumstances result in sufficient complication of the suggested technology of waste treatment, including the sulfuric-acid leaching and separate sorption recovery of hazardous and useful elements from the working solution.     

Cosmogenic Substances in the Zhamanshin Crater

Using high-resolution analytical electron microscopy, heterogeneous fragments of cosmogenic substances, such as nickelphosphide Ni₃P and the unnamed intermetallide ZnAl₂, are detected for the first time for a large meteorite crater, the Zhamanshin circular structure. Due to the impossibility of simultaneous finding these phases in the same meteorite, an assumption is made on the cometary nature of the impactor of the Zhamanshin crater.     

2.8-Ma ash-flow caldera at Chegem River in the northern Caucasus Mountains (Russia), contemporaneous granites, and associated ore deposits

Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ± 0.02 Ma (sanidine and biotite ⁴⁰Ar/³⁹Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical calderas of continental-margin volcanic arcs. Erosional remnants of the outflow Chegem Tuff sheet extend at least 50 km north from the source caldera in the upper Chegem River. These outflow remnants were previously interpreted by others as erupted from several local vents, but petrologic similarities indicate a common origin and correlation with thick intracaldera Chegem Tuff. The 11 × 15 km caldera and associated intrusions are superbly exposed over a vertical range of 2,300 m in deep canyons above treeline (elev. to 3,800 m). Densely welded intracaldera Chegem Tuff, previously described by others as a rhyolite lava plateau, forms a single cooling unit, is > 2 km thick, and contains large slide blocks from the caldera walls. Caldera subsidence was accommodated along several concentric ring fractures. No prevolcanic floor is exposed within the central core of the caldera. The caldera-filling tuff is overlain by andesitic lavas and cut by a 2.84 ± 0.03-Ma porphyritic granodiorite intrusion that has a cooling age analytically indistinguishable from that of the tuffs. The Eldjurta Granite, a pluton exposed low in the next large canyon (Baksan River) 10 km to the northwest of the caldera, yields variable K-feldspar and biotite ages (2.8 to 1.0 Ma) through a 5-km vertical range in surface and drill-hole samples. These variable dates appear to record a prolonged complex cooling history within upper parts of another caldera-related pluton. Major W-Mo ore deposits at the Tirniauz mine are hosted in skarns and hornfels along the roof of the Eldjurta Granite, and associated aplitic phases have textural features of Climax-type molybdenite porphyries in the western USA. Similar ⁴⁰Ar/³⁹Ar ages, mineral chemistry, and bulk-rock compositions indicate that the Chegem Tuff, intracaldera intrusion, and Eldjurta Granite are all parts of a large magmatic system that broadly resembles the middle Tertiary Questa caldera system and associated Mo deposits in northern New Mexico, USA. Because of their young age and superb three-dimensional exposures, rocks of the Chegem-Tirniauz region offer exceptional opportunities for detailed study of caldera structures, compositional gradients in volcanic rocks relative to cogenetic granites, and the thermal and fluid-flow history of a large young upper-crustal magmatic system.     

Geological-petrographic properties of Late Miocene granitoids from the Caucasian Mineral Waters region and their relation with the superplume

Doklady Earth Sciences -     

Geodynamic setting of recent volcanism in North Eurasia

A GIS layout of the map of recent volcanism in North Eurasia is used to estimate the geodynamic setting of this volcanism. The fields of recent volcanic activity surround the Russian and Siberian platforms—the largest ancient tectonic blocks of Eurasia—from the arctic part of North Eurasia to the Russian Northeast and Far East and then via Central Asia to the Caucasus and West Europe. Asymmetry in the spatial distribution of recent volcanics of North Eurasia is emphasized by compositional variations and corresponding geodynamic settings. Recent volcanic rocks in the arctic part of North Eurasia comprise the within-plate alkaline and subalkaline basic rocks on the islands of the Arctic Ocean and tholeiitic basalts of the mid-ocean Gakkel Ridge. The southern, eastern, and western volcanic fields are characterized by a combination of within-plate alkaline and subalkaline basic rocks, including carbonatites in Afghanistan, and island-arc or collision basalt-andesite-rhyolite associations. The spatial distribution of recent volcanism is controlled by the thermal state of the mantle beneath North Eurasia. The enormous mass of the oceanic lithosphere was subducted during the formation of the Pangea supercontinent primarily beneath Eurasia (cold superplume) and cooled its mantle, having retained the North Pangea supercontinent almost unchanged for 200 Ma. Volcanic activity was related to the development of various shallow-seated geodynamic settings and deep-seated within-plate processes. Within-plate volcanism in eastern and southern North Eurasia is controlled, as a rule, by upper mantle plumes, which appeared in zones of convergence of lithospheric plates in connection with ascending hot flows compensating submergence of cold lithospheric slabs. After the breakdown of Pangea, which affected the northern hemisphere of the Earth insignificantly, marine basins with oceanic crust started to form in the Cretaceous and Cenozoic in response to the subsequent breakdown of the supercontinent in the northern hemisphere. In our opinion, the young Arctic Ocean that arose before the growth of the Gakkel Ridge and, probably, the oceanic portion of the Amerasia Basin should be regarded as a typical intracontinental basin within the supercontinent [48]. Most likely, this basin was formed under the effect of mantle plumes in the course of their propagation (expansion, after Yu.M. Pushcharovsky) to the north of the Central Atlantic, including an inferred plume of the North Pole (HALIP).     

Native ytterbium of regolith AS Luna-24

Native ytterbium first identified in a single brownish orange glass fragment collected from the deepest part (184–189 cm) of the bore core delivered from the Mare Crisium of the Moon to the Earth by the Luna-24 Automatic Station is described. As follows from X-ray elemental maps, the ytterbium grain is metallic. Possible mechanisms of its formation and reasons for its elevated corrosion stability are discussed.