A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

What can ecological science tell us about opportunities for carbon sequestration on arid rangelands in the United States?

Scientific interest in carbon sequestration on rangelands is largely driven by their extent, while the interest of ranchers in the United States centers on opportunities to enhance revenue streams. Rangelands cover approximately 30% of the earth's ice-free land surface and hold an equivalent amount of the world's terrestrial carbon. Rangelands are grasslands, shrublands, and savannas and cover 312 million hectares in the United States. On the arid and semi-arid sites typical of rangelands annual fluxes are small and unpredictable over time and space, varying primarily with precipitation, but also with soils and vegetation. There is broad scientific consensus that non-equilibrium ecological models better explain the dynamics of such rangelands than equilibrium models, yet current and proposed carbon sequestration policies and associated grazing management recommendations in the United States often do not incorporate this developing scientific understanding of rangeland dynamics. Carbon uptake on arid and semi-arid rangelands is most often controlled by abiotic factors not easily changed by management of grazing or vegetation. Additionality may be impossible to achieve consistently through management on rangelands near the more xeric end of a rangeland climatic gradient. This point is illustrated by a preliminary examination of efforts to develop voluntary cap and trade markets for carbon credits in the United States, and options including payment for ecosystem services or avoided conversion, and carbon taxation. A preliminary analysis focusing on cap and trade and payment for avoided conversion or ecosystem services illustrates the misalignment between policies targeting vegetation management for enhanced carbon uptake and non-equilibrium carbon dynamics on arid United States rangelands. It is possible that current proposed carbon policy as exemplified by carbon credit exchange or offsets will result in a net increase in emissions, as well as investment in failed management. Rather than focusing on annual fluxes, policy and management initiatives should seek long-term protection of rangelands and rangeland soils to conserve carbon, and a broader range of environmental and social benefits.     

The study of hydrodynamic behaviour of a complex karst system under low-flow conditions using natural and artificial tracers (the catchment of the Unica River,SW Slovenia)

In this study a multi-tracer test with fluorescent tracers was combined with time series analyses of natural tracers to characterize the dynamics of the solute transport through different recharge pathways and to study hydraulic behaviour of a binary karst system under low-flow conditions. Fluorescent tracer testing included the introduction of uranine, amidorhodamine G, or naphthionate at three injection points. Sampling and monitoring took place at two karst springs (Malenščica, Unica) and at two underground rivers (Pivka, Rak) recharging the Unica River at the Polje of Planina, SW Slovenia. Other monitored parameters included precipitation, spring or underground river discharge, water temperature, and electrical conductivity. Water samples were collected and analyzed for total organic carbon, Mg²⁺, SO₄ ²⁻, and NO₃ ⁻ in the laboratory. In the study area, results of the tracer test suggest that contaminant transport in karst may be retarded for several weeks during low-flow conditions followed by increases in contaminant concentrations after subsequent rainfall events. Based on interpretation of tracer concentration breakthrough curves, low apparent dominant flow velocities (i.e., between 5.8 and 22.8 m/h through the well developed karst conduits, and 3.6 m/h through the prevailing vadose zone with a dominant influence of a diffuse recharge) were obtained. Together with analyses of hydro-chemographs the artificial tracing identified different origins of water recharging the studied aquifer. During prolonged low-water conditions the Malenščica spring is mainly recharged from the karst aquifer and the Unica spring by the sinking Pivka River. After more intensive rainfall events allogenic recharge from Cerknica prevails in the Malenščica spring, while the Unica spring drains mainly the allogenic water from the Pivka Valley. These findings of alternating hydraulic connections and drainage areas due to respective hydrological conditions are important and should be considered when monitoring water quality, implementing groundwater protection measures, and optimizing future water exploitation.     

Methodology for groundwater recharge assessment in carbonate aquifers: application to pilot sites in southern Spain

Aquifer recharge can be determined by conventional methods such as hydrodynamic or hydrologic balance calculations, or numerical, hydrochemical or isotopic models. Such methods are usually developed with respect to detrital aquifers and are then used on carbonate aquifers without taking into consideration their hydrogeological particularities. Moreover, such methods are not always easy to apply, sometimes requiring data that are not available. Neither do they enable determination of the spatial distribution of the recharge. For eight regions in southern Spain, the APLIS method has been used to estimate the mean annual recharge in carbonate aquifers, expressed as a percentage of precipitation, based on the variables altitude, slope, lithology, infiltration landform, and soil type. The aquifers are representative of a broad range of climatic and geologic conditions. Maps of the above variables have been drawn for each aquifer, using a geographic information system; thus they can be superimposed to obtain the mean value and spatial distribution of the recharge. The recharge values for the eight aquifers are similar to those previously calculated by conventional methods and confirmed by discharge values, which corroborates the validity of the method.     

Application of the European water framework directive in a Western Mediterranean basin (Málaga,Spain)

The water framework directive (WFD) is applied within the Guadalhorce river basin, a Western Mediterranean basin in the Málaga province (South Spain). Criteria defining different surface and groundwater bodies are described. The basic hydrographic network is constituted of low-mountain and low-altitude Mediterranean mineralized rivers. Heavily modified surface water bodies correspond (1) to areas where dams regulate the main watercourses, (2) to areas downstream of reservoirs, where river flow is reduced, and (3) to the coastal sector of the river where artificial channelling has caused morphological variations. Groundwater bodies are related to carbonate and porous aquifers and, locally, to aquifers influenced by dissolution of evaporites. The main impacts to water bodies are irrigated lands and livestock farming. There are also point sources of pollution, such as wastewater, landfills, golf courses, industrial zones, quarries and petrol stations. In addition, groundwater is frequently pumped for human supply and irrigation. Qualitative status of groundwater bodies was done by chemical analysis of samples from a monitoring network and the quantitative status by examining variations in piezometric levels. Both revealed the existence of water bodies at risk of not meeting the environmental objectives of the WFD. The main indicators of pollution are nitrates related to agricultural activities, and total organic carbon (TOC), PO₄³⁻ and NH₄⁺ in relation to wastewater.     

Tectonic shortening and gravitational spreading in the Gulf of Cadiz accretionary wedge: Observations from multi-beam bathymetry and seismic profiling

The Gulf of Cadiz lies astride the complex plate boundary between Africa and Eurasia west of the Betic-Rif mountain belt. We report on the results of recent bathymetric swathmapping and multi-channel seismic surveys carried out here. The seafloor is marked by contrasting morphological provinces, spanning the SW Iberian and NW Moroccan continental margins, abyssal plains and an elongate, arcuate, accretionary wedge. A wide variety of tectonic and gravitational processes appear to have shaped these structures. Active compressional deformation of the wedge is suggested by folding and thrusting of the frontal sedimentary layers as well as basal duplexing in deeper internal units. There is evidence for simultaneous gravitational spreading occurring upslope. The very shallow mean surface and basal slopes of the accretionary wedge (1° each) indicate a very weak decollement layer, geometrically similar to the Mediterranean Ridge accretionary complex. Locally steep slopes (up to 10°) indicate strongly focused, active deformation and potential gravitational instabilities. The unusual surface morphology of the upper accretionary wedge includes “raft-tectonics” type fissures and abundant sub-circular depressions. Dissolution and/or diapiric processes are proposed to be involved in the formation of these depressions.     

Contribution of stable isotopes to the understanding of the unsaturated zone of a carbonate aquifer (Nerja Cave, southern Spain)

We analysed the stable isotopes (¹⁸O and ²H) of rainwater and drip water within a cave (Nerja Cave) located in the unsaturated zone of a carbonate aquifer. Rainfall is more abundant and presents lower isotopic content in winter, while the volume of drip water is greater and its isotopic content is lower in summer. The flow analysis of ¹⁸O through the unsaturated zone confirms the seasonal lag between rainfall and the appearance of drip water in the cave and reveals that the unsaturated zone of the aquifer, in the sector of the cave, behaves like an inertial system with a strong capability to modulate the input signal. To cite this article: F. Carrasco et al., C. R. Geoscience 338 (2006).