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1.
Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites
Milton BLANDER Arthur D. PELTON In‐Ho JUNG Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910
Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (pFe) is larger than the partial pressure at equilibrium (pFe(eq)). The supersaturation ratio S = pFe/pFe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H2O ? H2 + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites. 相似文献
2.
Bennett R. Burns J. Nastav F. Lipkin J. Percival C. 《Oceanic Engineering, IEEE Journal of》1985,10(1):17-22
Two single-sensor piezometer probes, 8 mm in diameter, were developed for deep-ocean geotechnical investigations. These probes were tested in a hyperbaric chamber pressurized to 55 MPa (8000 psi). Testing was performed for a period of five weeks under high hydrostatic pressure with the probes inserted in reconstituted illitic marine sediment. Small differential pore-water pressures were generated in response to both mechanically and thermally generated forcing functions. During deep-ocean simulated pressure tests, the sensors exhibited excellent sensitivity and stability. These developments in piezometer-probe technology provide a quantitative means of assessing important geotechnical parameters of fine-grained seabed deposits. 相似文献
3.
Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO2) in marine waters is described. An extractor—stripper removes CO2 that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH? ions for the titration of the acid formed by the reaction of CO2 and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO2 determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO3 into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l?1 was found for 17 samples of Bermuda coastal waters having a mean TCO2 of 2007.2 μmol l?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO2. 相似文献
4.
When viewed from the air, Scottish ‘hummocky moraine’ can be resolved into a series of linear ridges that resemble those found at the margins of actively retreating glaciers today. Recent work has supported the interpretation of these linear ridges as ice-marginal landforms and the authors believe that the majority of ‘hummocky moraine’ deposits can be interpreted in this way. Consequently the pattern of deglaciation can be established fairly precisely from the pattern of linear ridges. This approach is applied to the landforms of the northern part of the Loch Lomond Stadial ice-field in order to reconstruct the regional pattern of deglaciation. This leads to important inferences about the significance of topographic control during deglaciation and more importantly it provides fresh insight into the environment of the British Isles during the Loch Lomond Stadial. 相似文献
5.
O. J. Bennett A. S. Dickinson T. Leininger F. X. Gadéa 《Monthly notices of the Royal Astronomical Society》2003,341(1):361-368
The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations. 相似文献
6.
Lance B. Morrissey Philippe Janvier Simon J. Braddy John P. Bennett Susan B. Marriott Peter R. Tarrant 《Geology Today》2006,22(2):66-67
Armoured jawless fish, or 'ostracoderms', lived 450–360 million years ago, and display unusual morphologies, unlike any modern fish group. Since they left no living descendants, their mode of swimming has, until recently, remained speculative, although this is a crucial question as the first true pectoral fins evolved within the 'ostracoderms'. The discovery of the oldest-known fish trails, from the Early Devonian (400 million year old) 'Lower Old Red Sandstone' of south-east Wales offers new insights into the swimming behaviour of these early fish, notably the osteostracan 'ostracoderms' (or cephalaspids), whose horseshoe-shaped head and paddle-shaped pectoral fins have remained a functional riddle. 相似文献
7.
Arthur Kosowsky 《New Astronomy Reviews》2003,47(11-12):939
The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys. 相似文献
8.
The quest for direct lines of evidence for Paleolithic plant consumption during the African Middle Stone Age has led scientists to study residues and use-wear on flaked stone tools. Past work has established lithic function through multiple lines of evidence and the spatial breakdown of use-wear and microscopic traces on tool surfaces. This paper focuses on the quantitative analysis of starch assemblages and the botanical identification of grains from flake and core tools to learn about human ecology of carbohydrate use around the Niassa woodlands, in the Mozambican Rift. The processing of starchy plant parts is deduced from the occurrence of starch assemblages that presumably got attached to stone tool surfaces by actions associated with extractive or culinary activities. Specifically, we investigate starch grains from stone tools recently excavated in northern Mozambique at the site of Mikuyu; which presumably spans the middle to late Pleistocene and represents similar sites found along the Malawi/Niassa corridor that links East, Southern, and Central Africa. Starch was extracted and processed with a diverse tool kit consisting of scrapers, cores, points, flakes, and other kinds of tools. The microbotanical data suggests consumption of seeds, legumes, caryopses, piths, underground storage organs, nuts, and mesocarps from more than a dozen families. Our data suggest a great antiquity for starch use in Africa as well as an expanded diet and intensification. 相似文献
9.
G. Caro V.C. Bennett B. Bourdon T.M. Harrison A. von Quadt S.J. Mojzsis J.W. Harris 《Chemical Geology》2008,247(1-2):253-265
146Sm–142Nd and 147Sm–143Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe 207Pb/206Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?142Nd = ? 6 ± 12 ppm, ?143Nd = ? 32.5, and 147Sm/144Nd = 0.1150. These results do not confirm previous claims for a 30 ppm 142Nd excess in South African cratonic mantle. The lack of a 142Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?142Nd = 8 ± 10 ppm, ?143Nd = 45 ± 1, and 147Sm/144Nd = 0.5891. Back-calculation of this present-day ?143Nd yields an unrealistic estimate for the initial ?143Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the 147Sm–143Nd system. Examination of 146,147Sm–142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of 146Sm–142Nd systematics in Jack Hills zircons. 相似文献
10.
Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years. 相似文献