Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Isotopic studies of leaf water. Part 1: A physically based two-dimensional model for pine needles

Understanding of isotopic variations in leaf water is important for reconstruction of paleoclimate and assessment of global biochemical processes. We report here a study of isotopic distributions within a single needle of two pine species, Pinus resinosa Ait and Pinus strobes L., with the objective of understanding how isotopic compositions of leaf water are controlled by environmental and physiological variables. A 2D model was developed to simulate along-leaf isotopic variations and bulk leaf water isotopic compositions. In addition to variables common to all leaf water isotopic models, this 2D model also takes into account the specific geometry and dimensions of pine needles and the isotopic transport in xylem and mesophyll. The model can successfully simulate oxygen isotopic variations along a single needle and averaged over a leaf (bulk leaf water). The simulations suggest that isotopic composition of the bulk leaf water does not always depend only upon the average transpiration rate, which in turn raises questions about using leaf water isotopic values to estimate transpiration rates. An unsuccessful attempt to simulate along-needle hydrogen isotopic variations suggests that certain unknown biological process(es) may not have been incorporated into our 2D model, and if so, it calls for a reevaluation of all other models for hydrogen isotopic simulations of leaf water since they too lack these processes.Existing leaf water isotopic models are reviewed in this work. In particular, we evaluate the most frequently used model, the stomatal boundary layer model (also referred to as the Craig-Gordon model). We point out that discrepancy between the boundary layer model and the measured bulk leaf water seems to depend upon relative humidity. Using our 2D model, we show that this humidity dependency is a result of an interplay between environmental and physiological conditions: if the transpiration rate of plant leaves decreases with increasing relative humidity, our 2D model can reproduce the pattern of isotopic discrepancy between boundary layer model predictions and observations, enabling us to understand better the reason behind this discrepancy.     

The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.     

Scaling analysis of deposition from turbidity currents

Many oil-bearing sedimentary deposits are formed by the settling of particles from turbidity currents. Modeling sedimentary processes that form these turbidites enables the calculation of properties such as extent, depth, porosity and permeability of hydrocarbon-bearing reservoirs. This paper estimates the extent and thickness of turbidites from the initial conditions of the turbidity flow. This is achieved by the application of scaling analysis of the partial differential equations that govern the dynamics of and deposition from turbidity currents. We apply the results of scaling analysis to five modern submarine fans. The predicted and actual values of the dimensions of the fan deposits match well. We then compare the derived results against tabulated sizes of ancient turbidites. The comparisons are good as long as we correctly identify the flow regimes in which the deposition took place. The good agreements observed in the two cases show that the estimates obtained using scaling analysis can provide useful first-guess values for the dimensions of the deposits.     

Code of Practice For Ocean Mining: An International Effort to Develop a Code For Environmental Management of Marine Mining

A code of practice for ocean mining has been developed by the International Marine Minerals Society. The code provides general guiding Principles for development of marine mineral resources and delineates Operating Guidelines for application, as appropriate, at specific mining sites. In total 11 operating guidelines are provided to serve as benchmarks for industry and targets for regulatory agencies and other stakeholders. They include the following commitments: •To sustainable development, •To environmentally responsible corporate ethics, •To the development of effective community partnership, •To implementation of environmental risk management, •To the integration of environmental management into all phases of development, •To the establishment of corporate environmental performance targets, •To timely environmental improvements and upgrading, •To responsible rehabilitation of operations sites and decommissioning of facilities, and •To accurate and timely, reporting and documentation, archiving, and performance review.     

Morphodynamics of intertidal bars on a megatidal beach, Merlimont, Northern France

The morphology, bedforms and hydrodynamics of Merlimont beach, in northern France, characterised by intertidal bars and a spring tidal range of 8.3 m, were surveyed over a 10-day experiment with variable wave conditions that included a 2-day storm with significant wave heights of up to 2.8 m. The beach exhibited two pronounced bar-trough systems located between the mean sea level and low neap tide level. Waves showed a cross-shore depth modulation, attaining maximum heights at high tide. The mean current was characterised dominantly by strong tide-induced longshore flows significantly reinforced by wind forcing during the storm, and by weaker, dominantly offshore, wave-induced flows. Vertical tidal water-level variations (tidal excursion rates) showed a bimodal distribution with a peak towards the mid-tide position and low rates near low and high water. The two bar-trough systems in the mid-tide zone remained stable in position during the experiment but showed significant local change. The absence of bar migration in spite of the relatively energetic context of this beach reflects high macro-scale bar morphological lag due to a combination of the large vertical tidal excursion rates in the mid-tide zone, the cross-shore wave structure, and the pronounced dual bar-trough system. The profile exhibited a highly variable pattern of local morphological change that showed poor correlation with wave energy levels and tidal excursion rates. Profile change reflected marked local morphodynamic feedback effects due mainly to breaks in slope associated with the bar-trough topography and with trough activity. Change was as important during low wave-energy conditions as during the storm. Strong flows in the entrenched troughs hindered cross-shore bar mobility while inducing longshore migration of medium-sized bedforms that contributed in generating short-term profile change. The large size and location of the two pronounced bars in the mid-tide zone of the beach are tentatively attributed respectively to the relatively high wave-energy levels affecting Merlimont beach, and to the cross-shore increase in wave height hinged on tidal modulation of water depths. These two large quasi-permanent bars probably originated as essentially breakpoint bars and are different from a small bar formed by swash and surf processes in the course of the experiment at the mean high water neap tide level, which is characterised by a certain degree of tidal stationarity and larger high-tide waves.     

Acoustic-gravity waves in the thermosphere of Venus

Properties of acoustic-gravity waves in the upper atmosphere of Venus are studied using a two-fluid model which includes the effects of wave-induced diffusion in a diffusively separated atmosphere. In conjunction with neutral mass spectrometer data from the Pioneer Venus orbiter, the theory should provide information on the distribution of wave sources in the Venus upper atmosphere. Observed wave structure in species density measurements should generally have periods ?30–35 min, small N₂, CO, and O amplitudes, and highly variable phase shifts relative to CO₂. A near resonance may exist between downward phase-propagating internal gravity and diffusion waves near the 165-km level at periods near 29 min. As a result, if very large He wave amplitudes are observed near this level, it will indicate that the wave source is below the 150- to 175-km level and that the exospheric temperature is close to 350°K. Wave energy dissipation may be an important mechanism for heating of the nightside Venus thermosphere. Large-density oscillations in stratospheric cloud layer constituents are also possible and may be detectable by the Pioneer Venus large probe neutral mass spectrometer.     

Short-term beach–dune sand budgets on the north sea coast of France: Sand supply from shoreface to dunes, and the role of wind and fetch

Three experimental plots, covering the transition from the upper beach to the dune, on the North Sea coast of France were monitored at various intervals over a period of 18–24 months via high resolution terrain surveys in order to determine inter-site sand budget variability, as well as patterns and processes involved in sand exchanges between the upper beach and dune. The wind regime consists of a fairly balanced mix of moderate (80% of winds are below 8 m/s) onshore, offshore and shore-parallel winds. Sustained dune accretion over several years depends on the periodic local onshore welding of shoreface tidal banks that have developed in the storm- and tide-dominated setting of the southern North Sea. The only site where this has occurred in the recent past is Calais, where bank welding has created a wide accreting upper beach sand flat. At this site, significant sand supply from the subtidal sand bank reservoir to the upper beach flat occurred only once over the 18-month survey following a major storm. The bulk of the sand deposited over this large flat is not directly integrated into the adjacent embryo dunes by onshore winds but is progressively reworked in situ into developing dunes or transported alongshore by the balanced wind regime, thus resulting in alongshore stretching of the embryo dune system. The Leffrinckoucke site near Belgium shows moderate beach–dune mobility and accretion, while the Wissant site exhibits significant upper beach bedform mobility controlled by strong longshore currents that result in large beach budget fluctuations with little net budget change, to the detriment of the adjacent dunes. Accretion at these two sites, which are representative of the rest of the North Sea coast of France, is presently constrained by the absence of a shore-attached sand bank supply reservoir, while upper beach–dune sand exchanges are further limited by the narrow wave-affected upper beach, the intertidal morphology of bars and troughs which segments the aeolian fetch, and the moderate wind energy conditions. The balanced wind regime limits net sand mobilisation in favour of either the beach or the dune, and may explain the relatively narrow longshore morphology of the dune ridges bounding this coast.