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Sophie GODIN-BEEKMANN Irina PETROPAVLOSKIKH Stefan REIS Paul NEWMAN Wolfgang STEINBRECHT Markus REX Michelle L. SANTEE Richard S. ECKMAN Xiangdong ZHENG Matthew B. TULLY David S. STEVENSON Paul YOUNG John PYLE Mark WEBER Johanna TAMMINEN Gina MILLS Alkiviadis F. BAIS Clare HEAVISIDE Christos ZEREFOS 《大气科学进展》2018,35(3):368-369
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Marie L. Kuessner Alkiviadis Gourgiotis Gerard Manhs Julien Bouchez Xu Zhang Jrme Gaillardet 《Geostandards and Geoanalytical Research》2020,44(1):57-67
The demand for large and reliable data sets on isotopic composition has increased in geochemistry and environmental sciences over recent years. We present an automated ion chromatographic separation method using a robotic pipetting arm, termed ‘ChemCobOne’, to reduce sample separation time. Its performance was tested for lithium isotope separation in geological reference materials using a single‐step separation with HCl (0.2 mol l?1) and a 2 ml resin volume. This refined lithium purification method does not forfeit precision, accuracy or purity compared with manual sample processing. In addition, a δ7Li value for NASS‐6 of 30.99 ± 0.50‰ (2s) (95% CI = 0.14‰, n = 44) was determined and the first δ7Li values for the granite rock reference material GS‐N (?0.57 ± 0.25‰ (2s), 95% CI = 0.15‰, n = 15), and for the soil reference material NIST SRM 2709a (?0.37 ± 0.67‰ (2s), 95% CI = 0.15‰, n = 63) are proposed. 相似文献
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