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In 1903 the Swiss Federal Research Institute WSL started its first forest hydrology measurements with the aim to deliver a sound scientific basis for the implementation of new forest legislation introduced in Switzerland in 1876. This legislation was triggered by several large floods that occurred in Switzerland, for which a major cause was widely seen as the poor condition of forests at that time. Consequently, hydrologic research at WSL first focused on the influence of forests on floods. In the second half of the 20th century, other hydrological issues such as water quality, snow hydrology and sediment transport complemented the hydrologic research at WSL. Some recent results of this work are presented in three papers joining this introductory paper to mark the 100th anniversary of hydrologic research at WSL. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
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Limitations of the ferrozine method for quantitative assay of mineral systems for ferrous and total iron 总被引:1,自引:0,他引:1
Alexandre S. Anastácio Hae-In Yoo Joseph W. Stucki 《Geochimica et cosmochimica acta》2008,72(20):5001-5008
The quantitative assay of clay minerals, soils, and sediments for Fe(II) and total Fe is fundamental to understanding biogeochemical cycles occurring therein. The commonly used ferrozine method was originally designed to assay extracted forms of Fe(II) from non-silicate aqueous systems. It is becoming, however, increasingly the method of choice to report the total reduced state of Fe in soils and sediments. Because Fe in soils and sediments commonly exists in the structural framework of silicates, extraction by HCl, as used in the ferrozine method, fails to dissolve all of the Fe. The phenanthroline (phen) method, on the other hand, was designed to assay silicate minerals for Fe(II) and total Fe and has been proven to be highly reliable. In the present study potential sources of error in the ferrozine method were evaluated by comparing its results to those obtained by the phen method. Both methods were used to analyze clay mineral and soil samples for Fe(II) and total Fe. Results revealed that the conventional ferrozine method under reports total Fe in samples containing Fe in silicates and gives erratic results for Fe(II). The sources of error in the ferrozine method are: (1) HCl fails to dissolve silicates and (2) if the analyte solution contains Fe3+, the analysis for Fe2+ will be photosensitive, and reported Fe(II) values will likely be greater than the actual amount in solution. Another difficulty with the ferrozine method is that it is tedious and much more labor intensive than the phen method. For these reasons, the phen method is preferred and recommended. Its procedure is simpler, takes less time, and avoids the errors found in the ferrozine method. 相似文献
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Miriam Borba-Roschel Anne Alexandre Anglica Fortes Drummond Chicarino Varajo Jean Dominique Meunier Csar Augusto Chicarino Varajo Fabrice Colin 《Journal of Geochemical Exploration》2006,88(1-3):172
This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed. 相似文献
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A design procedure is proposed to minimize water infiltration into landfills by optimizing the water diversion length of inclined
covers with capillary barrier effect (CCBE). This design procedure is based on a conceptual, mathematical and numerical approach
and aims at selecting materials and optimizing layer thickness. Selection among candidate materials is made based on their
hydraulic conductivity functions and on a threshold infiltration rate imposed on the designer. The capillary break layer (CBL;
bottom layer) is characterized by a weak capillarity, while the moisture retention layer (MRL; upper layer) is characterized
by a compromise between strong capillarity and high hydraulic conductivity. The thickness of the CBL corresponds to the height
where suction reaches its maximum value for a given infiltration rate. This height can be calculated using the Kisch [Géotechnique 9 (1959)] model. The optimal thickness of the MRL is determined by applying an adaptation of the Ross [Water Resources Research 26 (1990)] model. The results obtained using the proposed design procedure were compared to those obtained from numerical simulations
performed using a finite element unsaturated seepage software. The procedure was applied for two cover systems; one where
deinking by-products (DBP) were used as MRL and sand as CBL and another where sand was used as MRL and gravel as CBL. Using
this procedure, it has been shown that an infiltration control system composed of thin layers of sand over gravel is highly
efficient in terms of diversion length and that its efficiency can be enhanced by placing a hydraulic barrier – such as a
layer of DBP – above the MRL. 相似文献
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This is a web presentation of the work presented at the 10th Annual Conference of the CFD Society of Canada, “CFD 2002”, at the University of Windsor on June 9-11, 2002. This discussion paper presents the four-dimensional variational data assimilation (4D-VAR) technique as a tool to forecast floods. This discussion will be limited to hydrological forecast. We assume that the weather, here a large rainstorm, had already been forecasted by the meteorological services. In the 4D-VAR technique, we need to minimize, in the sense of Lagrange, a cost function which measures the difference between the forecast and the observations. The physical equations acts as a set of constraints. Here, the model is the shallow-water equations modified to include sediment transport. The minimum was found by using the steepest descent algorithm. This is made possible because the gradient of the cost function can be calculated analytically by using the adjoint equations of the model. To illustrate the 4D-VAR technique, the bypass of a simple theoretical dam as well as the more complex overflowing of the Chicoutimi River at the Chute-Garneau dam (during the 1996 flood) are investigated. 相似文献