Impact of mercury emissions from incineration of automobile shredder residue in Japan

Mercury emissions from the incineration of automobile shredder residues (ASRs) were investigated. Continuous monitoring of elemental and reactive gaseous Hg in flue gas was performed in lab-scale and plant-scale ASR incineration. Results of continuous monitoring agreed with those obtained using the JIS K0222 method and Ontario-Hydro method. Before cleaning by air pollutant control devices (APCDs), reactive Hg was the dominant form of that element in both lab-scale and plant-scale results. Emission factors of reactive Hg before APCDs estimated from monitoring results showed large differences between plant-scale and lab-scale emissions. The emission factor in the plant scale was more than 10 times larger than that in the lab-scale, which is explainable by the different Hg contents of ASR. Based on plant-scale monitoring at the stack, emission factors after APCDs were estimated as 0.79 mg-Hg/Mg-ASR for elemental Hg and 6.8 mg-Hg/Mg-ASR for reactive Hg. Using these emission factors, total Hg emissions from ASR incineration were estimated as 2.2 kg/a. An ASR incineration plant investigated in this study used highly effective APCDs. Consequently, these emission factors might result in underestimation of national Hg emissions from ASR incineration. Emission factors estimated from lab-scale monitoring at a fabric filter outlet side might be more appropriate. However, even if emission factors calculated from plant-scale or the lab-scale monitoring are used, estimated emissions are still less than 1.0% of total Hg emissions in Japan. Therefore, Hg emissions from ASR incineration can be evaluated as insignificant. Unless Hg contents of ASR increase extremely, ASR incineration would be a minor source of Hg atmospheric emission in Japan, even if all ASRs were incinerated.     

Monitoring the Kuroshio Extension with Dynamically Constrained Synthesis of the Acoustic Tomography, Satellite Altimeter and in situ Data

A finite-difference quasigeostrophic (QG) model of an open ocean region has been employed to produce a dynamically constrained synthesis of acoustic tomography and satellite altimetry data with in situ observations. The assimilation algorithm is based upon the 4D variational data interpolation scheme controlled by the model's initial and boundary conditions. The data sets analyzed include direct and differential travel times measured at the array of five acoustic transceivers deployed by JAMSTEC in the region of the Kuroshio Extension in 1997, Topex/Poseidon altimetry, CTD soundings, and ADCP velocity profiles. The region monitored is located within the area 27.5°–36.5°N, 143°–155°. The results of assimilation show that mesoscale variability can be effectively reconstructed by five transceivers measuring direct and reciprocal travel times supported by relatively sparse in situ measurements. The misfits between model and data lie within the observational error bars for all the data types used in assimilation. We have compared the results of assimilation with the statistical inversion of travel time data and analyzed energy balances of the optimized model solution. Energy exchange between the depth-averaged and shear components of the observed currents reveals a weak decay of the barotropic mode at the rate of 0.2 ± 0.7⋅10⁻⁵ cm²/s³ due to topographic interaction. Mean currents in the region are unstable with an estimate of the available potential energy flux from the mean current to the eddies of 4.7 ± 2.3⋅10⁻⁵ cm²/s³. Kinetic energy transition has the same sign and is estimated as 2.8 ± 2.5⋅10⁻⁵ cm²/s³. Potential enstrophy is transferred to the mesoscale at a rate of 5.5 ± 2.7⋅10⁻¹⁸ s⁻³. These figures provide observational evidence of the properties of free geostrophic turbulence which were predicted by theory and observed in numerical experiments. This revised version was published online in July 2006 with corrections to the Cover Date.     

Reconstruction of sea surface dimethylsulfide in the North Pacific during 1970s to 2000s

We proposed an empirical equation of sea surface dimethylsulfide (DMS, nM) using sea surface temperature (SST, K), sea surface nitrate (SSN, μM) and latitude (L, °N) to reconstruct the sea surface flux of DMS over the North Pacific between 25°N and 55°N: ln DMS = 0.06346 · SST − 0.1210 · SSN − 14.11 · cos(L) − 6.278 (R² = 0.63, p < 0.0001). Applying our algorithm to climatological hydrographic data in the North Pacific, we reconstructed the climatological distributions of DMS and its flux between 25 °N and 55 °N. DMS generally increased eastward and northward, and DMS in the northeastern region became to 2–5 times as large as that in the southwestern region. DMS in the later half of the year was 2–4 times as large as that in the first half of the year. Moreover, applying our algorithm to hydrographic time series datasets in the western North Pacific from 1971 to 2000, we found that DMS in the last three decades has shown linear increasing trends of 0.03 ± 0.01 nM year^− 1 in the subpolar region, and 0.01 ± 0.001 nM year^− 1 in the subtropical region, indicating that the annual flux of DMS from sea to air has increased by 1.9–4.8 μmol m^− 2 year^− 1. The linear increase was consistent with the annual rate of increase of 1% of the climatological averaged flux in the western North Pacific in the last three decades.     

Lithology and palynology of Neogene sediments on the narrow edge of the Kitakami Massif (basement rocks), northeast Japan: Significant change for depositional environments as a result of plate tectonics

Abstract A controversial stratigraphic section, the Taneichi Formation, is exposed along the Pacific Coast of northeastern Honshu, the main island of the Japanese Archipelago. Although most sediments of the formation have long been dated as late Cretaceous, the northern section of it has been assigned to (i) the Upper Cretaceous; (ii) the Paleogene; or (iii) the Neogene. In the present report, we present the data of palynological and sedimentological studies, showing that the northern section should be assigned to the Neogene. A more important point in the present study is that we invoke some basic principles of fluvial sedimentology to resolve this stratigraphic subject. The lignite layers full of Paleogene–Miocene dinoflagellate cysts and pollen assemblages drape over the boulder‐sized (>40 cm in diameter) clasts in the northern section. However, the layers totally consist of aggregates of small lignite chips, indicating that the lignites are allochthonous materials. The mega‐clasts with derived microfossils in the lignites are thought to have been deposited as Neogene fluvial (flood) sediments in the newly formed Japanese Archipelago. Prior to the Miocene, the northern Honshu was part of the Eurasian Plate, thus the boulder‐sized clasts cannot be envisaged as long river flood deposits along the continental Paleogene Pacific Coast. Instead, the mega‐clasts with the draping lignites were probably derived from nearby Miocene highlands in the newly born island arc.     

Seafloor spreading, obduction and triple junction tectonics of the Mineoka Ophiolite, Central Japan

The Tertiary Mineoka ophiolite occurs in a fault zone at the intersection of the Honshu and Izu forearcs in central Japan and displays structural evidence for three major phases of deformation: normal and oblique-slip faults and hydrothermal veins formed during the seafloor spreading evolution of the ophiolite at a ridge-transform fault intersection. These structures may represent repeated changes in differential stress and pore-fluid pressures during their formation. The second series of deformation is characterized by oblique thrust faults with Riedel shears and no significant mineral veining, and is interpreted to have resulted from transpressional dextral faulting during the obduction of the ophiolite through oblique convergence and tectonic accretion. This deformation occurred at the NW corner of a TTT-type (trench–trench–trench) triple junction in the NW Pacific rim before the middle Miocene. The third series of deformation of the ophiolite is marked by contractional and oblique shear zones, Riedel shears, and thrust faults that crosscut and offset earlier structures, and that give the Mineoka fault zone its lenticular (phacoidal) fabric at all scales. This deformation phase was associated with the establishment and the southward migration of the TTT Boso triple junction and with the kinematics of oblique subduction and forearc sliver fault development. The composite Mineoka ophiolite hence displays rocks and structures that evolved during its complex geodynamic history involving seafloor spreading, tectonic accretion, and triple junction evolution in the NW Pacific Rim.     

Efficient analysis of pile-group effect on seismic stiffness and strength design of buildings

A new efficient method is developed for the analysis of pile-group effects on the seismic stiffness and strength design of buildings with pile foundations. An efficient continuum model consisting of a dynamic Winkler-type soil element and a pile is used to express the dynamic behavior of the structure-pile-soil system with only a small numerical error. The pile-group effect is taken into account through the influence coefficients among piles which are defined for interstory drifts and pile-head bending moments. It is shown that, while the pile-group effect reduces the interstory drift of buildings in general, it may increase the bending moment of piles at the head. This means that the treatment without the pile-group effect results in the conservative design for super-structures and requires a revised member design for piles.     

Changes in the abundance and composition of picophytoplankton in relation to the occurrence of a Kyucho and a bottom intrusion in the Bungo Channel,Japan

The Bungo Channel in southwestern Japan receives both warm, called Kyucho, and cold deep-water intrusions (bottom intrusion) from the Pacific Ocean. Abundances of Prochlorococcus, Synechococcus, and eukaryotic picophytoplankton were monitored from 18 July to 17 August 2001 to clarify whether advected picophytoplankton from the Pacific Ocean can grow in the channel or not. Synechococcus cells were further discriminated into low- and high-PUB types according to their fluorescence property in flow cytometry. From 18 to 25 July, the water temperature decreased by 3 °C at a 5-m depth at all stations, indicating the occurrence of a bottom intrusion. From 25 July to 4 August, a Kyucho occurred and the water temperature rapidly increased. From 4 to 17 August, a bottom intrusion and a Kyucho both occurred twice, although the intensities were smaller than those occurring until 4 August. From 18 to 30 July, the abundance of both Prochlorococcus and a high-PUB type of Synechococcus drastically decreased because of a bottom intrusion; however, the abundances rapidly increased due to the advection by a Kyucho. These advected cells increased from 4 to 17 August in the channel and Kitanada Bay. Changes in the abundance of low-PUB type of Synechococcus and eukaryotic picophytoplankton were less noticeable than those in the abundance of Prochlorococcus and high-PUB type. The present study demonstrated that oceanic picophytoplankton advected by the Kyucho could grow in the channel. However, abundances of low-PUB type and eukaryotic picophytoplankton increased higher than those of Prochlorococcus and high-PUB type did. Thus, these oceanic phytoplankters will be excluded when Kyucho does not occur for a long time. The co-occurrence of various types of picophytoplankton found in the channel is probably achieved by both Kyucho event and their growth capability in the channel.     

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

Transport of water in frozen soil: V, Method for measuring the vapor diffusivity when ice is absent

A new experimental method is introduced for determining the relative magnitudes of liquid and vapor diffusion by using a small amount of soluble chemical as a tracer. The theoretical justification of the method is presented for the case where ice is absent. The feasibility of the method is demonstrated by an experiment using marine-deposited clay.