Seasonal patterns of carbon chemistry and isotopes in tufa depositing groundwaters of southwestern Japan

Annually laminated carbonates, known as tufas, commonly develop in limestone areas and typically record seasonal patterns of oxygen- and carbon-isotope compositions. δ¹⁸O values are principally controlled by seasonal changes of water temperature, whereas δ¹³C values are the result of complex reactions among the gaseous, liquid, and solid sources of carbon in the system. We examined the processes that cause the seasonal patterns of δ¹³C in groundwater systems at three tufa-depositing sites in southwestern Japan by applying model calculations to geochemical data. Underground inorganic carbon species are exchanged with gaseous CO₂, which is mainly introduced to the underground hydrological system by natural atmospheric ventilation and by diffusion of soil air. These processes control the seasonal pattern of δ¹³C, which is low in summer and high in winter. Among the three sites we investigated, we identified two extreme cases of the degree of carbon exchange between liquid and gaseous phases. For the case with high radiocarbon composition (Δ¹⁴C) and low pCO₂, there was substantial carbon exchange because of a large contribution of atmospheric CO₂ and a small water mass. For the other extreme case, which was characterized by low Δ¹⁴C and high pCO₂, the contribution of atmospheric CO₂ was small and the water mass was relatively large. Our results suggest that at two of the three sites water residence time within the soil profile was longer than 1 year. Our results also suggested a short residence time (less than 1 year) of water in the soil profile at the site with the smallest water mass, which is consistent with large seasonal amplitude of the springwater temperature variations. The Δ¹⁴C value of tufas is closely related to the hydrological conditions in which they are deposited. If the initial Δ¹⁴C value of a tufa-depositing system is stable, ¹⁴C-chronology can be used to date paleo-tufas.     

In situ strength measurements on natural upper-mantle minerals

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.     

Early deformation fabrics of melange in the Mesozoic Waipapa Terrane, North Island, New Zealand

Abstract The Waipapa Terrane in northern North Island, New Zealand, is a Mesozoic accretion-ary complex formed along the Gondwana margin. It contains abundant melange rocks with distinctive characteristics. Precise analyses of their mesoscopic fabrics in Waiheke Island near Auckland have revealed the following sequence of deformation. The earliest phase of deformation of the sandstone/mudstone association, which is the main constituent of this terrane, originated by chaotic mixing of sand and mud due to liquidization of water-saturated, poorly consolidated sediments. The second phase was characterized by hydrofracturing and subsequent forceful injection of ductile mud into rather brittle sand. Local intrusions of sand forming dykes and sills followed these events, as well as intrusions of pelagic/hemipelagic green argillite originally underlying the sandstone/mudstone association. An abundant occurrence of these mixing and multi-stage injection/intrusion fabrics strongly suggest that the Waipapa Terrane around the study area was a site of high pore-fluid pressure. Scaly-foliated melange fabrics with monoclinic symmetry, originating from layer-parallel shearing, were then locally superimposed on the pre-existing melange fabrics. Similar scaly-foliated fabrics also developed in the chert beds originally intercalated between the green argillite and the uppermost part of the oceanic crust. These scaly fabrics might have been related to the regional stacking and juxtaposition of the accreted sediments. The sequence and variation in style of deformation forming the melange fabrics presumably reflected changes in porosity and state of compaction of accreted sediments in a shallow tectonic level.     

Quaternary vertical offset and average slip rate of the Nojima Fault on Awaji Island, Japan

Abstract Drilling was carried out to penetrate the Nojima Fault where the surface rupture occurred associated with the 1995 Hyogo-ken Nanbu earthquake. Two 500 m boreholes were successfully drilled through the fault zone at a depth of 389.4 m. The drilling data show that the relative uplift of the south-east side of the Nojima Fault (south-west segment) was approximately 230 m. The Nojima branch fault, which branches from the Nojima Fault, is inferred to extend to the Asano Fault. From the structural contour map of basal unconformity of the Kobe Group, the vertical component of displacement of the Nojima branch–Asano Fault is estimated to be 260–310 m. Because the vertical component of displacement on the Nojima Fault of the north-east segment is a total of those of the Nojima Fault of the south-west segment and of the Nojima branch–Asano Fault, it is estimated to total to 490–540 m. From this, the average vertical component of the slip rate on the Nojima Fault is estimated to be 0.4–0.45 m/10³ years for the past 1.2 million years.     

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.     

A comparison of neighbourhood relations based on ordinary Delaunay diagrams and area Delaunay diagrams: an application to define the neighbourhood relations of buildings

ABSTRACT

The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%.     

<Emphasis Type="Bold">Synplutonic Mafic Dykes from Late Archaean Granitoids in the Eastern Dharwar Craton,Southern India</Emphasis> by M. Jayananda,T. Miyazaki,R.V. Gireesh,N. Mahesha and T. Kano. Jour. Geol. Soc. India,v.73, 2009, pp.117–130

Discussion

Synplutonic Mafic Dykes from Late Archaean Granitoids in the Eastern Dharwar Craton, Southern India by M. Jayananda, T. Miyazaki, R.V. Gireesh, N. Mahesha and T. Kano. Jour. Geol. Soc. India, v.73, 2009, pp.117–130     

A Miocene coarse volcaniclastic mass-flow deposit in the Shimane Peninsula,SW Japan: product of a deep submarine eruption?

 A subaqueous volcaniclastic mass-flow deposit in the Miocene Josoji Formation, Shimane Peninsula, is 15–16 m thick, and comprises mainly blocks and lapilli of rhyolite and andesite pumices and non- to poorly vesiculated rhyolite. It can be divided into four layers in ascending order. Layer 1 is an inversely to normally graded and poorly sorted lithic breccia 0.3–6 m thick. Layer 2 is an inversely to normally graded tuff breccia to lapilli tuff 6–11 m thick. This layer bifurcates laterally into minor depositional units individually composed of a massive, lithic-rich lower part and a diffusely stratified, pumice-rich upper part with inverse to normal grading of both lithic and pumice clasts. Layer 3 is 2.5–3 m thick, and consists of interbedded fines-depleted pumice-rich and pumice-poor layers a few centimeters thick. Layer 4 is a well-stratified and well-sorted coarse ash bed 1.5–2 m thick. The volcaniclastic deposit shows internal features of high-density turbidites and contains no evidence for emplacement at a high temperature. The mass-flow deposit is extremely coarse-grained, dominated by traction structures, and is interpreted as the product of a deep submarine, explosive eruption of vesicular magma or explosive collapse of lava. Received: 10 January 1996 / Accepted: 23 February 1996     

A new geotechnical method for natural slope exploration and analysis

Natural Hazards - Geotechnical investigation of natural slopes is challengeable especially when natural slopes having higher gradients and access is difficult. Also, it is even more problematic to...     

Long-Term Variations of Potential Temperature and Dissolved Oxygen of the Japan Sea Proper Water

Observed potential temperatures and concentrations of dissolved oxygen are analyzed to elucidate their variations during the period from 1958 to 1996 at Stn. P (37°43′ N, 134°43′ E) and from 1965 to 1996 at Stn. H (40°30′ N, 137°40′ E) in the Japan Sea. At Stn. P, increases of the potential temperature for the period are found below 800 m depth with the largest value of 0.16 ± 0.09°C per century at 800 m depth. At Stn. H, the potential temperature increased below 500 m depth. The increase rate has the largest value of 0.50 ± 0.18°C per century at 500 m depth and it is 0.30 ± 0.09°C per century at 800 m depth. The concentrations of dissolved oxygen increased around 800 m depth at Stn. P. At Stn. H, they increased above 800 m depth. On the other hand, they decreased below 1200 m depth at both stations. The layer of the dissolved oxygen minimum has deepened in these decades. These features appearing in the distributions of temperature and dissolved oxygen are successively simulated by a vertical one-dimensional advection-diffusion model including consumption of dissolved oxygen and termination of the deep water supply. These results suggest that the supply of the Japan Sea Proper Water into the deep layer, which is cold and rich in dissolved oxygen, has been decreasing for the last four decades. This revised version was published online in August 2006 with corrections to the Cover Date.