Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

To move or not to move: an applied study of veterinary clinic location in Wellington,New Zealand

This paper demonstrates the utility, in an applied context, of a standard Teitz and Bart heuristic for solving location-allocation problems. The example discussed is the location of veterinary clinics in Wellington, New Zealand. A distinct ‘service-poor’ area is identified in southern Wellington suggesting that the existing system of clinics, especially the largest multi-veterinary practice, is vulnerable to intrusion by competitors. A variety of strategies, involving new clinics and clinic relocation are analysed to ascertain alternative courses of action for both existing clinic operators and competitors. The appropriateness of this type of analysis as an aid to decision-making is reflected in the locational response of one practice to protect its share of the market for veterinary services.     

Some implications of statistical transport theory in rock mechanics

Summary Recently, a new theory of the subsidence of rock masses has been advanced byLitwiniszyn and coworkers, which is based on the notion that the individual rock particles perform random walks. It is shown in the present paper that the final equations of the random walk theory can be justified from general principles of statistical mechanics in which no specific theoretical model of particle behaviour has to be made. The theory appears to account appropriately for subsidence phenomena.The research reported in this paper was supported by the Petroleum Research Fund of the American Chemical Society. Acknowledgment is made to the donors of the Petroleum Research Fund administered by the American Chemical Society for support of this reseach.     

Methods of fitting the Fisher-Tippett type 1 extreme value distribution

Methods are described for estimating the parameters of the Fisher-Tippet Type 1 extreme value distribution and associated return values from measured extremes, such as maximum wave height. A comparison of these methods, with simulated data, shows that those using Gumbel's plotting position are least satifactory. Maximum likelihood methods give the smallest mean square errors, but the very much simpler method of moments is nearly as good.     

Sea-level, sediment supply and coastal changes: Examples from the coast of Ireland

Sediment supply and pre-existing shoreline morphology are crucial factors in controlling coastal changes due to sea-level rise. Using examples from both southeast and northeast Ireland, it can be shown that sea-level change may trigger a sequence of events which leads to both static and dynamic shoreline equilibrium. Cliff erosion and longshore sediment movement in east Co. Wexford has led to injection of sediment onto the shelf, and the growth, under both wave and tide regimes, of linear offshore shoals. These shoals now control the pattern of shoreline erosion and provide a template for possible stepwise evolution of the coast under any future sea-level rise. In contrast, the nearby coast of south Co. Wexford comprises a series of coarse clastic barriers moving monotonously onshore, via overwash processes. Here the behavior of the barrier is conditioned by the antecedent morphology of both the beach face and stream outlet bedforms. Finally, the rock platform coast of Co. Antrim presents a far more resistant shoreline to incident marine processes, yet even here there is strong evidence of present process control over so-called ‘raised’ platforms and embayments. It is concluded that coastal sediment supply and dynamics, together with coastal morphology and its interaction with waves, present a far more complex variety of sea-level indicators than is normally acknowledged.     

The abyssal bounty fan and lower Bounty Channel: evolution of a rifted-margin sedimentary system

The Bounty Channel and Fan system provides the basis for a model for deep-sea channel and fan development in a rifted continental margin setting. The sedimentary system results from an interplay between tectonics (fan location; sediment source), turbidity currents (sediment supply), geostrophic currents (sediment reworking and distribution) and climate (sea level, and hence sediment supply and type). Today, sediment is shed from the collisional Southern Alps, part of the Pacific/Indo-Australian plate margin, and passes east across the adjacent shelf and into the Otago Fan complex at the head of the Bounty Trough. Paths of sediment supply, and locations of sediment deposition, are controlled by the bathymetry of the Bounty Trough, with axial slopes as high as 37 m/km (2°) towards the trough head, diminishing to around 3.5 m/km (0.2°) along the trough axis. The Bounty Fan is located 800 km further east, where the Bounty Channel debouches onto abyssal oceanic crust at the mouth of the Bounty Trough. The Bounty Fan comprises a basement controlled fan-channel complex with high leveed banks exhibiting fields of mud waves, and a northward-elongated middle fan. Channel-axis gradients diminish from 6 m/km (0.35°) or more on the upper fan to less than 1 m/km (<0.06°) on the lower fan. Parts of the left bank levee and almost the entire middle fan are being eroded and re-entrained within a Deep Western Boundary Current (DWBC), which passes along the eastern New Zealand margin at depths below 2000 m. The DWBC is the prime source of deep, cold water flow into the Pacific Ocean, with a volume of ca. 20 Sv and velocities up to 4 cm/s or greater. The mouth of the Bounty Channel, at a depth of 4950 m at the south end of the middle fan, acts as a point source for an abyssal sediment drift entrained northward under the DWBC at depths below 4300 m. The Bounty Fan probably originated in the early to middle Neogene, but has mostly been built during the last 3 Myr (Plio-Pleistocene), predominantly as climate-controlled sedimentary couplets of terrigenous, micaceous mud (acoustically reflective; glacial) and biopelagic ooze (acoustically transparent; interglacial), deposited under the pervasive influence of the DWBC.     

Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.