铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。     

基于Windows下的气象决策服务工作平台

针对当前农业气象服务工作的内容和特点，建成了基于Windows操作系统下的本溪地区气象决策服务工作平台．以便更好地为当地政府领导和有关部门提供更多气象决策服务项目。     

盘西线新海站至大塘站岩溶路基塌陷发育规律及注浆整治

通过对盘西线新海站—大塘站(K 3 500~K 38 493)岩溶路基塌陷病害注浆整治的实例,介绍了该段岩溶路基塌陷发育规律、病害情况、病害的形成机理、注浆整治方法、质量检查方法等内容。     

酸性土壤中20种元素有效态浸提体系浅析

通过对酸性土壤中Cu、Pb、Zn、Co、Ni、Fe、Mn、Cd、K、Na、Ca、Mg、Si、P、S、Mo、F、Se、As、Hg20种元素有效态的浸提与测定，拟定了一个操作条件宽松、质量稳定，能满足区域调查需要的浸提体系和分析方案。该分析配套方案对20种元素的检出限在（0.0001～4.9）×10     

高氟水处理方法研究

氟化物是水质的毒理学指标,生活饮用水标准中氟化物不能大于1．0mg／L,由于水文地质原因,一些地区地下水氟化物严重超标,部分高氟地区氟化物达到5．0mg／L以上,给当地居民安全引水带来很大困难,通过对国内外高氟水的降氟调查研究,提出无论采取哪种方法降氟,均可采用饮水和生活用水分质提供方案,投入相对较少资金,对专用饮水进行降氟处理。     

青藏铁路设计与建设——第六届国际冻土工程会议回顾

The 6^th International Symposium on Permafrost Engineering was successfully held in China in September 2004. About 150 scientists and engineers from 7 countries attended the symposium in Lanzhou on 5～7 September, and about 35 people from 6 countries participated in the field trip along the QinghaiTibet Highway/Railway on 8～13 September and the seminar in Lhasa on 14 September 2004. During the Symposium, the latest progress on permafrost engineering and the surveys, design and construction of the Qinghai-Tibet Railway were exchanged and inspected. Fifty-eight technical papers in English from the Symposium were published in the first volume of the Proceedings of the Symposium, as a supplement of the Journal of Glaciology and Geocryology, before the symposium. About 6 papers from the symposium are published in the second volume in the volume 27(1) of the Journal of the Glaciology and Geocryology, after the symposium. The Qinghai-Tibet Railway (QTR) under construction will traverse 632 km of permafrost, and the engineers are facing unprecedented engineering and environmental challenges. With the QTR under construction and to be completed in 2007, permafrost engineering has become the research focus of permafrost scientists and engineers in China. Many encouraging and promising achievements in permafrost engineering have been obtained during the past three years. However, there are still numerous engineering and environmental problems needing to be solved or resolved. In the discussions, some experts pointed out that methods, such as removal of snow cover on the embankments and toe areas, light-color embankments and side slope surfaces, awnings for shading the solar radiation, hairpin or tilted thermosyphons, could be applied to actively cool the roadbed of the QTR. Some new ideas on utilization of the natural cold reserves were proposed to protect the QTR permafrost roadbed from thawing. Many questions and answers on the survey, design, construction, operations, maintenance and environmental protection were exchanged in situ and in the Lhasa seminar with participation by some major railway designers, regulators and administrators.     

添加剂对土体的加固作用及冻胀防治研究

将研制的高分子有机材料作为添加剂，加入到土体中，经过拌和夯实、干燥固结，能够起到稳定和提高土体的强度，并具有低渗透和低吸水等特性．冻胀试验表明：加入添加剂不仅能阻止土体冻胀的产生、外来水源的入侵及水分的迁移，还能隔断土体孔隙之间的联系，使水分在土体孔隙中不能运移，从而达到了防治冻胀的目的。     

云南老王寨金矿田金的迁移形式和富集机理探讨

通过测定成矿过程不同阶段形成的包裹体温度、压力及成分，在了解成矿热液的成矿过程中温度、压力及其组分变化的基础上，将实验地球化学与热力学方法相结合，研究了金矿田成矿热液在成矿过程中的物理化学条件、迁移形式及金沉淀富集的地球化学机理。研究结果表明，金在热液中主要以AuCl4^-、AuS^-、Au（HS）2^-、AuAsS3^2-、AuSbS3^2-的形式迁移，并在物理化学条件t、p、pH、fα2、fs2降低的情况下富集。     

大坂山隧道地下水动态分析及对隧道作用评估

Base on the groundwater yield, water temperature and hydrochemistry change of the groundwater, we can analyze that the summer water content is obviously greater than winter water content where the in and-out wall rock of the Daban Mountain tunnel. The groundwater supply has the extensity and the seasonality. The groundwater content of the middle tunnel wall rock changes relatively steady, mainly supply through horizontal direction. And the total groundwater content is relatively little and steady in winter. The water pressure of the wall rock cranny is little. It has the fluent drainage system to dredge groundwater, which cannot constitute a threat to the tunnel lining. And the cold-proof sluice hole can normally work to drain water.     

开放系统下硫酸钠盐对土体冻胀的影响

易溶盐在土中的存在及其在冻结过程中的重新分布对土体的冻结过程有重要影响.在开放系统单向冻结条件下,对青藏铁路沿线粉质红粘土进行了冻结试验.结果表明:随着冷能的持续传递,硫酸钠盐和水分向温度较低处迁移,土体0℃曲线持续降低;但基于测定的含盐土大量冻结温度的基础上,对土体冻深的研究发现,在开放单向冻结条件下土体冻深随着水盐迁移进程的发展而减小,造成与补蒸馏水的土体相比,土体的冻胀较小.同时,利用冻深发展曲线和硫酸钠水溶液相图及溶解度曲线,对土柱中的冻胀和盐胀分别进行了计算,结果认为:土体变形主要是由冻胀引起,硫酸钠结晶膨胀只发生在未冻土段,这与试验结束后对土体冻土段和未冻土段的干密度分层测定的试验结果相一致.