海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

Control of dust emissions by geomorphic conditions, wind environments and land use in northern China: An examination based on dust storm frequency from 1960 to 2003

The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence.     

Regional characteristics of dust events in China

The regional characteristics of dust events in China has been mainly studied by using the data of dust storm, wind-blown sand and floating dust from 338 observation stations through China from 1954 to 2000. The results of this study are as follows: (1) In China, there are two high frequent areas of dust events, one is located in the area of Minfeng and Hotan in the South Xinjiang Basin, the other is situated in the area of Minqin and Jilantai in the Hexi Region. Furthermore, the spatial distributions of the various types of dust events are different. The dust storms mainly occur in the arid and semiarid areas covering the deserts and the areas undergoing desertification in northern China. Wind-blown sand and floating-dust not only occur in the areas where dust storms occur, but also extend to the neighboring areas. The range of wind-blown sand extends northeastward and southeastward, but floating-dust mainly extends southeastward to the low-latitude region such as the East China Plain and the area of the middle and lower reaches of the Yangtze River. Compared with wind-blown sand, the floating-dust seldom occurs in the high latitude areas such as North Xinjiang and Northeast China. (2) The affected areas of dust storms can be divided into seven sub-regions, that is, North Xinjiang Region, South Xinjiang Region, Hexi Region, Qaidam Basin Region, Hetao Region, Northeastern China Region and Qinghai-Xizang (Tibet) Region. The area of the most frequent occurrence of dust storms and floating-dust is in South Xinjiang Region, and of wind-blown sand in the Hexi Region. In general, the frequency of dust events in all the seven regions shows a decreasing tendency from 1954 to 2000, but there are certain differences between various dust events in different regions. The maximum interannual change and variance of dust events during this time happened in South Xinjiang Region and Hexi Region. The dust events generally occur most frequently in April in most parts of China. The spring occurred days of dust events occupied 60-70% of the whole year in Hetao Region and Northeastern China Region. However, in South Xinjiang Region and North Xinjiang Region, which was less affected by monsoon climate, dust events may occur at any time of the year, less than 50% of the events in this region occur during spring. In the remaining three regions 50-60% of the dust events occur in spring of a year.     

Significance of variations in the wind energy environment over the past 50 years with respect to dune activity and desertification in arid and semiarid northern China

Climate data from 339 meteorological stations collected from the 1950s to the early 2000s was employed to discuss aeolian activity in arid and semiarid northern China. The results show that at decadal time scales, erosivity varied greatly in this region. Most of arid and semiarid northern China was characterised by environments with moderate to low wind energy. After the 1980s, the erosivity was only 20 to 50% of that beforehand, and this difference had a significant impact on the environmental changes observed during the two periods. The dune mobility index was consistent with the observed dune activity. After the 1980s dune activity decreased and in some deserts with vegetated dune systems during the 1970s most of the dune plinths were active until the 1980s, after which only the crests were active. Some mobile dunes that had developed at the margins of mobile deserts were replaced by semi-anchored or anchored dunes. Because most desert areas with vegetated dune systems in arid and semiarid northern China are used for farming or grazing, the results of our monitoring show that the desertification trends were consistent with the trends in erosivity and dune activity in this region. Desertification was controlled much more by climatic changes than has previously been acknowledged, and especially by fluctuations in wind energy.     

Metallogenic mechanisms of super-large Cu and Au deposits in the Dexing region and simulating experiments

Based on the results of previous studies and under the direction of the theory of “ore deposit genesis”, the authors made use of high temperature and high pressure experimental facilities and conditions at the Tectono-geochemistry Research Room under the State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, and put the focus on the multi-source of tectonically controlling ore-forming materials, the characteristics of multi-stage and multi-episode hydrothermal activities and mineralization and the characteristics of multi-genesis and multi-ore deposition so as to shed light on the metallogenic mechanisms of super-large Cu and Au deposits. In addition simulating experiments were made on multi-stage and multi-episode tectonic activities and rock and ore deformation, multi-stage and multi-episode tectonic activities and mobilization and migration of ore-forming materials, and multi-stage and multi-episode tectonic activities and superimposition and enrichment of ore-forming materials. The experimental results showed that under the action of multi-stage and multi-episode tectonic stress the deformation and fragmentation of not only rocks and ores have been intensified, and but also the ore-forming materials originally disbursed in the rocks and ores have been mobilized and migrated and superimposed and enriched. The experimental results also provided the scientific experimental data and grounds for deep-going research on the rules of metallogenesis and geneses of super-large ore deposits in the Dexing region, Jiangxi Province.     

青藏高原区域性积雪增量序列及其变化特征

利用青藏高原83个气象台站的逐日积雪观测资料,充分考虑每次降雪过程所引起的积雪变化,建立了该地区1960-2007年度的区域性积雪增量序列,并讨论了其长期变化特征.结果表明:(1)积雪增量序列具有其他积雪参数指标的代表性,又较其他积雪参数指标序列有明显的统计学优点.(2)在48个年度里,1960-1966年度青藏高原区域性积雪增量处于负位相,1967-1998年度为多雪的正位相,1999-2007年度又为少雪的负位相,其中1998年度是个具有显著性的突变点.     

新一代天气雷达布网设计的有效覆盖和地形遮挡分析

一般情况下,地形影响造成的雷达波束遮挡是长期保持不变的。研究雷达地形遮挡情况有助于提升雷达探测资料的有效性和可靠性。利用先进星载热发射和反射辐射仪全球数字高程模型地形数据,对我国已建成的208个新一代天气雷达站点进行地形遮挡分析,计算业务体扫模式(Volume Coverage Pattern modes, VCP)21的九个仰角下200 km范围内雷达反射率的波束阻挡系数,绘制观测仰角分别为0.5°、1. 45°、2. 4°和3. 35°时雷达有效观测区域的覆盖图,计算相应的有效覆盖面积。结果表明全国新一代天气雷达站200 km范围内0. 5°、1. 45°、2. 4°和3. 35°仰角平均遮挡比例分别为30. 7%、8. 5%、2. 5%和1.0%,平均有效覆盖面积分别为83210.5、109354.2、118170.9、121631.5 km~2,只有少数几个雷达站受邻近山脉地形遮挡影响严重,雷达站总体有效覆盖情况较好。     

海洋环境监测的重要性研究——基于经济与管理的视角

文章通过论述海洋环境监测的CalCOFI计划经验与海洋环境监测在经济与管理方面的重要意义,最终得出如下结论:(1)加强海洋环境监测能力建设,提高监测的质量与水平;(2)加强对海洋环境的动态跟踪与管理;(3)积极做好海洋环境监测信息的发布工作,完善海洋环境监测预警机制。     

恰什坎萨伊沟玄武岩年代学、地球化学特征及其对北阿尔金洋盆闭合过程的制约

北阿尔金恰什坎萨伊沟红柳泉以南早古生代蛇绿岩剖面发育两段玄武岩岩片.北段玄武岩锆石LA-ICP-MS U-Pb定年与前人对南段玄武岩定年结果(晚奥陶世)相近,表明该玄武岩形成于中—晚奥陶世;样品TR050-10-1锆石热干扰年龄为421～412 Ma、395～388 Ma和283～228Ma,TR050-13-1锆石热干扰年龄为442～434Ma、415Ma和241～221Ma.地球化学特征显示北段玄武岩和南段玄武岩的岩浆演化过程中均以单斜辉石结晶分异为主,仅表现极轻微地壳物质混染;二者均来自尖晶石二辉橄榄岩地幔源区,前者源区为原始尖晶石二辉橄榄岩相,后者源区为原始—亏损尖晶石二辉橄榄岩过渡相,前者的部分熔融程度更高.微量元素、稀土元素及构造判别图解指示其为形成于聚合背景下的E-MORB型拉斑玄武岩,具弧后盆地性质.结合区域资料,提出北阿尔金早古生代洋盆4阶段闭合模式:①早期俯冲阶段(∈2～O1),②晚期俯冲阶段(O1～O3),③俯冲-碰撞转换阶段(O3～S2),④后碰撞造山阶段(S3～D2).     

2004年春季中国沙尘天气特征分析

利用全国681个站的沙尘天气观测资料分析得出,2004年春季中国北方的沙尘天气明显偏少、偏弱,主要表现在：（1）2004年春季681个站累计的沙尘天气日数2 080 d,相当于历史平均值的46.9%,是近四十余年中第三个偏少年份。沙尘暴的总面积约190万km2,仅为历史平均值的37.3%。（2）危害性较大的沙尘暴和强沙尘暴过程6次,不足2001年的一半。（3）4月和5月沙尘天气明显偏少导致整个春季显著偏少。沙尘天气出现时,PM10浓度相对增加,空气质量恶化,但与历史上较典型的强沙尘暴个例相比,PM10浓度增加的幅度不大。进一步分析表明,2004年春季沙尘天气偏少、偏弱的主要原因是大气动力条件不足,是比较特殊的一个年份。