Quantification of adamantane in organic media via infrared attenuated total reflection spectroscopy

In the present study, the quantitative determination of the diamondoid compound adamantane in organic solvents via infrared attenuated total reflection (IR-ATR) spectroscopy at unmodified waveguide surfaces was established. Limits of detection (LOD) and quantification (LOQ) of adamantane in dichloromethane, hexane and carbon tetrachloride were determined. Quantitative IR-ATR measurements additionally facilitated the determination of adamantane solubility limit in dichloromethane, hexane and carbon tetrachloride. The developed analytical strategy further enabled the successful detection and quantification of adamantane in crude oil matrices. Consequently, IR-ATR spectroscopy provides a promising strategy for on ship and in situ diamondoid analysis in harsh real world environments.     

Nitrate contamination in a shallow urban aquifer in East Ukraine: evidence from hydrochemical,stable isotopes of nitrate and land use analysis

A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination.     

Laboratory Experiment on Wave Induced Turbulence

A laboratory experiment was conducted inside a wind wave tank to investigate the wave induced turbulence. In this experiment, the wave surface elevation and velocity beneath the water surface were measured simultaneously to investigate the relation between the wave status and wave induced turbulence. The profile of the turbulent dissipation rate and Reynolds stress were calculated using experimental data. The effect of the wave status on turbulence is investigated with regard to the wind wave, swell, and mixed wave conditions. It was depicted that the turbulence decreased with increasing depth from the water surface and that the turbulence that was induced by a wave with larger wavelength and wave height is much stronger for the same wave status. Finally, we observed that the wind wave is more effective in activating the wave induced turbulence.     

Distribution of trace elements in waters and sediments of the Seversky Donets transboundary watershed (Kharkiv region,Eastern Ukraine)

This paper reports on the aquatic chemistry of trace elements in terms of spatial and temporal distribution, but also pollution sources in the transboundary watershed of the Seversky Donets River (Ukraine/Russia). Bed sediments and filtered water were collected from the Udy and Lopan Rivers at sites from the river source in the Belgorod region (Russia) to rural and urban areas in the Kharkiv region (Ukraine) in May and August 2009. Priority trace elements (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn), an urban tracer (Ag) and additional metals (Co, Mo, V) and Th were measured in stream water and sediments. The low levels and variability of Th-normalized concentrations indicated the absence of geochemical anomalies in the upstream part of the rivers and suggested that these data represent a regional baseline for trace elements in bed sediments. In contrast, water and sediments within the city of Kharkiv were contaminated by Ag, Pb, Cd, Cu, Cr and Zn, which are mainly attributed to municipal wastewater inputs and urban run-off. Results of the environmental quality assessment showed that element concentrations in the sediments can be considered as potentially toxic to aquatic organisms in sites downstream of the wastewater discharges.     

Petroleum surface oil seeps from a Palaeoproterozoic petrified giant oilfield

Early Palaeoproterozoic rocks from the Onega Basin in Russian Fennoscandia contain evidence for substantial accumulation and preservation of organic matter (up to 75 wt% total organic carbon) with an estimated original petroleum potential comparable to a modern supergiant oilfield. The basin contains a uniquely preserved petrified oilfield including evidence of oil traps and oil migration pathways. Here, we report the discovery of the surface expression of a migration pathway, along which petroleum was flowing from the sub-surface. This surface oil seep, the first occurrence ever reported from the Palaeoproterozoic, appears as original bitumen clasts redeposited in Palaeoproterozoic lacustrine turbidites. The δ¹³C_org of clastic pyrobitumen ranges between −35.4 and −36.0‰ ( n  = 14), which is within the range of interbed- and vein-trapped fossil oil (−46 and −24‰), suggesting similar source. Biogenic organic matter, whose isotopic composition was modified during thermal maturation, is the likely source for the migrated hydrocarbon.     

Advancing isotope-enabled hydrological modelling for ungauged calibration of data-scarce humid tropical catchments

Realistic projections of the future climate and how this translates to water availability is crucial for sustainable water resource management. However, data availability constrains the capacity to simulate streamflow and corresponding hydrological processes. Developing more robust hydrological models and methods that can circumvent the need for large amounts of hydro-climatic data is crucial to support water-related decisions, particularly in developing countries. In this study, we use natural isotope tracers in addition to hydro-climate data within a newly developed version of the spatially-distributed J2000iso as an isotope-enabled rainfall-runoff model simulating both water and stable isotope (δ²H) fluxes. We pilot the model for the humid tropical San Carlos catchment (2500 km²) in northeastern Costa Rica, which has limited time series, but spatially distributed data. The added benefit of simulating stable isotopes was assessed by comparing different amounts of observation data using three model calibration strategies (i) three streamflow gauges, (ii) three gauges with stream isotopes and (iii) isotopes only. The J2000iso achieved a streamflow Kling–Gupta efficiency (KGE) of 0.55–0.70 across all the models and gauges, but differences in hydrological process simulations emerged when including stable water isotopes in the rainfall-runoff calibration. Hydrological process simulation varied between the standard J2000 rainfall-runoff model with a high simulated surface runoff proportion of 37% as opposed to the isotope version with 84%–89% simulated baseflow or interflow. The model solutions that used only isotope data for calibration exhibited differences in simulated interflow, baseflow and model performance but captured bulk water balances with a reasonable match between the simulated and observed hydrographs. We conclude that J2000iso has shown the potential to support water balance modelling for ungauged catchments using stable isotope, satellite and global reanalysis data sets.     

土库曼斯坦外商直接投资环境研究

在“一带一路”倡议下,中国与土库曼斯坦的投资合作成为“中国—中亚—西亚经济走廊”建设的重要内容。土库曼斯坦油气资源丰富,已成为各国投资商的重要关注点。不过,该国较为封闭,相关数据资料相对匮乏。在此背景下,本文基于土库曼斯坦自然资源、经济、社会文化和投资管理等条件,借助熵权法对土库曼斯坦各州和直辖市的投资环境进行了综合评价。研究表明,自然资源是各州和直辖市投资环境演变的核心推动力量,同时投资管理特征和经济发展也发挥重要作用,社会文化特征的影响则不显著。因此,由于资源在空间上分布不均衡,土库曼斯坦各地区的投资环境也存在较大差异,从而导致油气资源不足的地区对投资管理形成较大依赖。总体来看,巴尔坎州和莱巴普州投资环境较好,而马雷、达沙古兹等地区仍有待提高。     

Seasonal Variability of Polycyclic Aromatic Hydrocarbons (PAHs) in a Coastal Marine Area in the Northwestern Region of the Sea of Japan/East Sea (Possiet Bay)

Ocean Science Journal - Contamination by persistent organic pollutants including polycyclic aromatic hydrocarbons (PAHs) constitutes a major concern in relation to aquatic ecosystems. To study the...