The nature of scattered and concretion pyrite in the Upper Abalak Formation of the Salym oil field (Western Siberia)

Dispersed and concretionary pyrite in chert–clay–carbonate and carbonate rocks of the Abalak Formation (Salym oil field) have been studied. The study was conducted using Scanning Electron Microscopy (SEM), Electron Probe Microanalysis (EPMA), and high spatial resolution Secondary Ion Mass Spectrometry (Nano-SIMS). As a result, three morphological groups of pyrite have been distinguished: large cubic crystals, framboidal pyrite, and fine-crystal aggregates that replace organic remnants. The sulphur isotope ratio allows one to distinguish two genetic types of pyrite. The source of the sulphur for the first genetic group was H₂S produced by bacterial sulphate reduction, while the second group pyrite was formed with sulphur as a product of thermochemical sulphate reduction.     

Numerical simulation of migration–accumulation of oil resources

Numerical simulation of oil migration and accumulation is to describe the history of oil migration and accumulation in basin evolution. It is of great value to the evaluation of oil resources and to the determination of the location and amount of oil deposits. This thesis discusses the characteristics of petroleum geology and permeation fluid mechanics. For the three-dimensional problems of Dongying hollow of Shengli Petroleum Oil Field, it puts forward a new model and a kind of modified method of upwind finite difference fractional steps implicit interactive scheme. For the famous hydraulic experiment of secondary migration–accumulation, the numerical simulation test has been done, and both the computational and experimental results are basically identical. For the actual problem of Dongying hollow, the numerical simulation test and the actual conditions are basically coincident. Thus, the well-known problem has been solved.     

Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.     

Scattering of Semidiurnal Internal Kelvin Wave at Step Bottom Topography

A three-dimensional, multi-level model was used to study the energy dissipation of semidiurnal internal Kelvin waves due to their interaction with bottom topography. A simplified topography consisting of a channel with an additional shallow bay was used to clarify the wave’s scattering process. When the first mode semidiurnal internal wave given at an open boundary arrives at the bay mouth, higher-mode internal waves are generated at a step bottom of the bay mouth. As a result, the energy of the first mode internal Kelvin wave is effectively decayed. The decay rate of the internal Kelvin wave depends on both the width and length of the additional bay. The maximum decay rate was found when a resonance condition occurs the bay, that is, the bay length is equal to a quarter of wave length of the first mode internal wave on the shallow region. The decay rate in the wide bay cases is higher than that in a narrow case, due to a contribution from the scattering due to the Poincare wave that emanates from the corners of the bay head. The decay rate with the additional bay is 1.1–1.8 times that of the case without the additional bay. The decay rate due to the scattering process is found to be of the same order as that of the internal and bottom friction.     

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

Japan-equator XBT sections in late November 1989 and in early December 1991

A comparison between Japan-equator XBT sections along 150°E in late November 1989 and along 140°E in early December 1991 is made. The warmest surface water above 29°C diminished to the south of 2–4°N and the surface mixed layer noticeably decreased in thickness in the equatorial region in December 1991; besides, the North Equatorial Countercurrent was intensified. This is considered to be a manifestation of changes in the surface layer of the western equatorial Pacific in the mature phase of El Niño.     

Paleomagnetic constraints on Miocene rotation in the central Japan Arc

We present new Middle Miocene paleomagnetic data for the central Japan Arc, and discuss their implications for Miocene rotation. To obtain a refined paleodirection, we made magnetic measurements on basaltic to andesitic lavas and intrusive rocks from 12 sites in the Tsugu volcanic rocks (ca 15 Ma) in the northern part of the Shitara area, Japan. Significant secondary magnetizations in samples with strong magnetic intensities are interpreted as lightning‐induced components. Mean directions carried by magnetite and/or titanomagnetite were determined for all sites. An overall mean direction with a northerly declination was obtained from dual‐polarity site means for nine sites. This direction is indistinguishable from the mean direction for coeval parallel dikes in the northern part of the Shitara area, and also indistinguishable from the Miocene reference direction derived from the paleopole for the North China Block in the Asian continent. These comparisons suggest little or no rotation or latitudinal motion in the study area with respect to the North China Block since 15 Ma. We obtained a refined early Middle Miocene paleodirection (D = 9.7°, I = 52.5°, α₉₅ = 4.8°; 30 sites) and paleopole (82.0°N, 230.8°E, A₉₅ = 5.6°) for Shitara by combining data from the Tsugu volcanic rocks and a coeval dike swarm. An anomalous direction found at three sites could be a record of an extraordinary field during a geomagnetic polarity transition or excursion. Paleomagnetic data from Shitara suggest that: (i) the western wing of the Kanto Syntaxis, a prominent cuspate geologic structure in central Honshu, underwent a counterclockwise rotation with respect to the main part of the southwestern Japan Arc between ca 17.5 Ma and 15 Ma; (ii) collision between the Japan and Izu–Bonin (Ogasawara) Arcs began prior to 15 Ma; and (iii) clockwise rotation of the entire southwestern part of the Japan Arc had ceased by 15 Ma.     

Wide-Field Camera for Gravitational Microlensing Survey: MOA-cam2

We have constructed a large, mosaic CCD camera called MOA-cam2 which has 4096 × 6144-pixelsto search for gravitational microlensing events. MOA-cam2 has three4096 × 2048-pixel SITe CCD chips, which have a very high quantum efficiency (nearly 80% in the wave region 500 to 800 nm),and three buttable sides. We have placed the threechips side by side with 100 m dead space. MOA-cam2 has been installed on the 61 cm Boller and Chivens telescope of the MOA collaboration at the Mt. John University Observatory (MJUO) in NewZealand since July 1998. The field coverage is 0.92° × 1.38° per exposure. The technical details of MOA-cam2 and the first images obtained with the Boller and Chivens telescope are presented. MOA-cam2 introduces a second phase of research on gravitational microlensing by the MOA collaboration.     

Atoll island vulnerability to flooding and inundation revealed by historical reconstruction: Fongafale Islet, Funafuti Atoll, Tuvalu

The reef islands formed on coral atolls are generally small, low, and flat, with elevations of only a few meters. These islands are thus highly vulnerable to elevated sea levels caused by extreme events and global warming. Such vulnerability was recently evidenced at Fongafale Islet, the capital of Tuvalu, when it flooded during accelerated spring high tides possibly related to sea level rise caused by global warming. Many factors, not only environmental but also economic and social, determine the vulnerability of an island to sea level rise. In this study, we used data spanning 108 yrs to reconstruct changes in topography, land use/cover, population, and the distribution of buildings at Fongafale Islet. The results indicate that the vulnerability of Fongafale Islet relates to its original landform characteristics: the central part of the island was formerly dominated by swampland that flooded at high tides. Fongafale Islet experienced greater population in-migration and centralization beginning in the 1970s following the independence of Tuvalu and Kiribati. Migrants were also responding to declines in overseas mining operations and limited options for paid employment. As the population increased, construction took place in vulnerable swampland areas. Our results clearly demonstrate that examinations of global environmental issues should focus on characteristics specific to the region of interest. These characteristics should be specified using historical reconstruction to understand and address the vulnerability of an area to global environmental changes.