Multiple Enrichment Processes and their Relationships in the Subcrustal Lithosphere Beneath the Eifel (Germany)

Three types of enrichment processes may be distinguished inspinel peridotite mantle xenoliths from the West Eifel (Germany):

1. Enrichmentof light rare earth elements (LREE) occurs in wholerocks andclinopyroxenes in conjunction with the formation ofTi-pooramphiboles (<0•5%) in a low-tempetature suite(900C).
2. Enrichment in high field strength elements (HFSE; Ti and Hf)is associated with strong zoning of TiO₂ in amphibole adjacentto mica hornblendite veins. A reheating from 900 to 1050C associatedwith this vein formation is reflected by the zoning profilesin orthopyroxenes with Ca, Al, and Cr increasing from core torim.
3. Moderate enrichment of LREE without amphibole formationin ahigh-temperature suite (1125C) is observed at the contactofperidotites to pyroxenite veins yielding the same temperature.
4. Based on geochemical and isotopic evidence, enrichment process(1) is inferred to be due to interaction of peridotites fromthe subcrustal lithosphere with low-density fluids. Process(2) represents a subsequent interaction of amphibole-bearingperidotites formed during the first process with basic meltsmoving through a system of cross-cutting dykes and veins. Processes(2) and (3) are linked to the Quaternary West Eifel volcanism.Geothermobarometry of the xenoliths shows that these processesare related to different depth regimes of the lower lithosphere.

     

Putting Japanese investment in Europe in its place

Summary Research on Japanese economic activity in Europe concentrates almost exclusively on investment in manufacturing. However, this paper demonstrates that this emphasis both underestimates the longevity of Japanese direct investment in Europe and also grossly underdefines the importance of services. Not only does Japanese direct investment have a much longer history in Europe than is usually recognized but also—and perhaps more significantly—the bulk of that investment is not in manufacturing production per se but in a variety of circulation services. Using establishment-level data, this paper shows that the spatial manifestation of these circulation services is very different from that of manufacturing production.     

Effects of forest roads on the hydrological response of a small‐scale mountain watershed in Greece

The effects of land use changes on the ecology and hydrology of natural watersheds have long been debated. However, less attention has been given to the hydrological effects of forest roads. Although less studied, several researchers have claimed that streamflow changes related to forest roads can cause a persistent and pervasive effect on hillslope hydrology and the functioning of the channel system. The main potential direct effects of forest roads on natural watersheds hydrologic response are runoff production on roads surfaces due to reduced infiltration rates, interruption of subsurface flow by road cutslopes and rapid transfer of the produced runoff to the stream network through roadside ditches. The aforementioned effects may significantly modify the total volume and timing of the hillslope flow to the stream network. This study uses detailed field data, spatial data, hydro‐meteorological records, as well as numerical simulation to investigate the effects of forest roads on the hydrological response of a small‐scale mountain experimental watershed, which is situated in the east side of Penteli Mountain, Attica, Greece. The results of this study highlight the possible effects of forest roads on the watersheds hydrological response that may significantly influence direct runoff depths and peak flow rates. It is demonstrated that these effects can be very important in permeable watersheds and that more emphasis should be given on the impact of roads on the watersheds hydrological response. Copyright © 2014 John Wiley & Sons, Ltd.     

Three-dimensional stability of landslides based on local safety factor

Unlike the limit equilibrium method (LEM), with which only the global safety factor of the landslide can be calculated, a local safety factor (LSF) method is proposed to evaluate the stability of different sections of a landslide in this paper. Based on three-dimensional (3D) numerical simulation results, the local safety factor is defined as the ratio of the shear strength of the soil at an element on the slip zone to the shear stress parallel to the sliding direction at that element. The global safety factor of the landslide is defined as the weighted average of all local safety factors based on the area of the slip surface. Some example analyses show that the results computed by the LSF method agree well with those calculated by the General Limit Equilibrium (GLE) method in two-dimensional (2D) models and the distribution of the LSF in the 3D slip zone is consistent with that indicated by the observed deformation pattern of an actual landslide in China.     

Correlation of spectroscopic properties and substitutional sites of Cr3+ in aluminosilicates: II. Andalusite and sillimanite

This paper is an extension of the earlier one dealing with kyanite in which the best fitting value of the oxygen ligand distance for Cr³⁺ is adopted to study the spectroscopic properties of Cr³⁺ ions doped at the two possible Al sites in the other two polymorphs of the aluminosilicate group (Al₂O₃ · SiO₂), namely, andalusite and sillimanite. The superposition model and the crystal field analysis package recently developed for 3d ions doped at arbitrary low symmetry sites in crystals are used to predict energy levels and statevectors within the whole 3d ³ configuration. Then the values of the ground state zerofield splitting for Cr³⁺ ions at each Al sites in the two crystals are obtained. The splittings of the lower excited states ² E and ⁴ T ₂ as well as the admixture of ⁴ T ₂ into ² E have also been predicted. Comparison of our results with the available experimental data enable us to correlate the optical and EPR Spectroscopic properties with the substitutional Cr³⁺ sites. The conclusion is that in andalusite and sillimanite only the Al sites with nearly-octahedral six-fold coordination seem to be occupied by Cr³⁺ ions.     

SEPARATION OF REGIONAL AND RESIDUAL ANOMALIES BY LEAST-SQUARES ORTHOGONAL POLYNOMIAL AND RELAXATION TECHNIQUES: A PERFORMANCE EVALUATION1

The performances of least-squares orthogonal polynomial and relaxation techniques in the separation of regional and residual anomalies have been evaluated with a view to minimizing personal biasing. The advantage of orthogonal over nonorthogonal polynomials is their ability to estimate an optimum order of polynomial to represent the predominant regional trend in the data using an approximate 2D difference table, the Z-matrix. The correlation coefficients between residuals of two consecutive orders also give the same result. In the relaxation technique, a linear trend is assumed within each cell of the mesh of a square grid. A set of such linear segments can approximate any complicated regional trend. The performances of these two techniques have been evaluated using simulated gravity anomalies produced by 2D and 3D complex regional structures superimposed on residual fields due to cylinders and prismatic bodies, as well as three field examples taken from the published literature. The analyses have revealed that the relaxation technique produces excellent results when an optimum polynomial order rather than an arbitrary fixed one is used for computing the boundary conditions along the periphery of the map. Analyses have revealed that such boundary conditions provide minimum distortion near the two ends of the profile.     

Development of an operational rainfall data quality-control scheme based on radar-raingauge co-kriging analysis

Abstract

Automatic raingauge data often serve as an important input to hydrological and weather warning operations. They are not only fundamental in quantitative rainfall analysis, but also act as the ground truth in warning operation and forecast validation. Quality control is required before the data can be used quantitatively due to systematic and random errors. Extremely large random errors and unreasonably small or false zero values can hamper effective monitoring of heavy rain. Yet both are difficult to detect in real-time by objective means. In an attempt to address these problems, a rainfall data quality-control scheme based on radar-raingauge co-kriging analysis was developed. The important threshold values required in the data quality control of 60-min raingauge rainfall were determined from a detailed analysis of the distributions of rainfall residuals defined as the arithmetic difference and the logarithm of the ratio between a raingauge measurement and its co-kriging estimate. The scheme has been developed and is in real-time use in Hong Kong, a coastal city of about 1100 km² area with more than 150 raingauges installed. Geographically, it is located in the subtropics and dominated by heavy convective rainfall in the summer. As a basis of the quality-control scheme, the co-kriging rainfall analysis was shown through a verification exercise to be superior to those obtained by the Barnes analysis and ordinary kriging of raingauge data. The performance of the quality-control algorithm was assessed using selected cases and controlled tests, and was found to be satisfactory, with a high error detection rate for the two targeted types of error. Limitations and operational issues identified during a real-time trial of the quality-control scheme are also discussed.

Citation Yeung, H.Y., Man, C., Chan, S.T., and Seed, A., 2014. Development of an operational rainfall data quality-control scheme based on radar-raingauge co-kriging analysis. Hydrological Sciences Journal, 59 (7), 1285–1299. http://dx.doi.org/10.1080/02626667.2013.839873