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1.
Brent L. Lewis Pamela D. Holt Steven W. Taylor Steven W. Wilhelm Charles G. Trick Alison Butler George W. Luther III 《Marine Chemistry》1995,50(1-4)
Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment. 相似文献
2.
Molecular identification of ascaridoid nematodes from the deep-sea onion-eye grenadier (Macrourus berglax) from the East Greenland Sea 总被引:2,自引:0,他引:2
Esra Kellermanns Sven Klimpel Harry Wilhelm Palm 《Deep Sea Research Part I: Oceanographic Research Papers》2007,54(12):2194-2202
Macrourus berglax from the East Greenland Sea was studied for the presence of ascaridoid nematodes in 2001, 2002 and 2003. The fishes were collected between 278 and 413 m water depth using a benthopelagic net. Based on the amplification of the internal transcribed spacer ITS-1, 5.8S, ITS-2 and flanking sequences (=ITS+), three ascaridoid nematode species were identified. The prevalence of infestation during the 3 years ranged from 42.9% to 62.9% and 22.9% to 40.0% for the anisakids Anisakis simplex (s.s.) and Pseudoterranova decipiens (s.s.), respectively, and from 28.6% to 60.0% for the raphidascarid Hysterothylacium aduncum. A total of 18 specimens, two of each species and examination year, revealed no sibling species, suggesting a limited distribution of other ascaridoid siblings into the deep sea. The ITS-1, 5.8S and ITS-2 sequences of A. simplex (s.s.) from the East Greenland Sea did not differ from previously published sequence data (GenBank) from other regions in the Atlantic and Pacific oceans. The sequences of P. decipiens (s.s.) corresponded most closely to those of specimens from Richardson Bay, western Pacific, and differed in four positions (0.5%). They corresponded least to those of specimens from Japan (1.5%). The sequence data for H. aduncum differed in two positions in the ITS-1 (0.2%) and three positions in the ITS-2 (0.3%) from sequences from Japan. A high genetic similarity between the regions can be explained by (a) extensive final host migration in the case of A. simplex (s.s.), (b) an overlapping distribution of final host populations along the continental shelves for P. decipiens (s.s.) and (c) a low host specificity and large population size in the intermediate and final hosts for H. aduncum. The occurrence of the identified species in the macrourid fish underlines the potential of cosmopolitan ascaridoid nematodes to distribute not only horizontally but also vertically in the deep sea. 相似文献
3.
The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons. 相似文献
4.
The beginning of dehydration melting in the tonalite system (biotite-plagioclase-quartz) is investigated in the pressure
range of 2–12 kbar. A special method consisting of surrounding a crystal of natural plagioclase (An45) with a biotite-quartz mixture, and observing reactions at the plagioclase margin was employed for precise determination
of the solidus for dehydration melting. The beginning of dehydration melting was worked out at 5 kbar for a range of compositions
of biotite varying from iron-free phlogopite to iron-rich Ann70, with and without titanium, fluorine and extra aluminium in the biotite. The dehydration melting of phlogopite + plagioclase
(An45) + quartz begins between 750 and 770°C at pressures of 2 and 5 kbar, at approximately 740°C at 8 kbar and between 700 and
730°C at 10 kbar. At 12 kbar, the first melts are observed at temperatures as low as 700°C. The data indicate an almost vertical
dehydration melting solidus curve at low pressures which bends backward to lower temperatures at higher pressures (> 5 kbar).
The new phases observed at pressures ≤ 10 kbar are melt + enstatite + clinopyroxene + potassium feldspar ± amphibole. In addition
to these, zoisite was also observed at 12 kbar. With increasing temperature, phlogopite becomes enriched in aluminium and
deficient in potassium. Substitution of octahedral magnesium by aluminium and titanium in the phlogopite, as well as substitution
of hydroxyl by fluorine, have little effect on the beginning of dehydration melting temperatures in this system. The dehydration
melting of biotite (Ann50) + plagioclase (An45) + quartz begins 50°C below that of phlogopite bearing starting composition. Solid reaction products are orthopyroxene +
clinopyroxene + potassium feldspar ± amphibole. Epidote was also observed above 8 kbar, and garnet at 12 kbar (750°C). The
experiments on the iron-bearing system performed at ≤ 5 kbar were buffered with NiNiO. The f
O
2 in high pressure runs lies close to CoCoO. With the substitution of octahedral magnesium and iron by aluminium and titanium,
and replacement of hydroxyl by fluorine in biotite, the beginning of dehydration melting temperatures in this system increase
up to 780°C at 5 kbar, which is 70°C above the beginning of dehydration melting of the assemblage containing biotite (Ann50) of ideal composition. The dehydration melting at 5 kbar in the more iron-rich Ann70-bearing starting composition begins at 730°C, and in the Ann25-bearing assemblage at 710°C. This indicates that quartz-biotite-plagioclase assemblages with intermediate compositions of
biotite (Ann25 and Ann50) melt at lower temperatures as compared to those containing Fe-richer or Mg-richer biotites. This study shows that the dehydration
melting of tonalites may begin at considerably lower temperatures than previously thought, especially at high pressures (>5
kbar).
Received: 27 December 1995 / Accepted: 7 May 1996 相似文献
5.
Dehydration melting of tonalitic compositions (phlogopite or biotite-plagioclase-quartz assemblages) is investigated within
a temperature range of 700–1000°C and pressure range of 2–15 kbar. The solid reaction products in the case of the phlogopite-plagioclase(An45)-quartz starting material are enstatite, clinopyroxene and potassium feldspar, with amphiboles occurring occasionally. At
12 kbar, zoisite is observed below 800°C, and garnet at 900°C. The reaction products of dehydration melting of the biotite
(Ann50)-plagioclase (An45)-quartz assemblage are melt, orthopyroxene, clinopyroxene, amphibole and potassium feldspar. At pressures > 8 kbar and temperatures
below 800°C, epidote is also formed. Almandine-rich garnet appears above 10 kbar at temperatures ≥ 750°C. The composition
of melts is granitic to granodioritic, hence showing the importance of dehydration melting of tonalites for the formation
of granitic melts and granulitic restites at pressure-temperature conditions within the continental crust. The melt compositions
plot close to the cotectic line dividing the liquidus surfaces between quartz and potassium feldspar in the haplogranite system
at 5 kbar and a
H
2O = 1. The composition of the melts changes with the composition of the starting material, temperature and pressure. With increasing
temperature, the melt becomes enriched in Al2O3 and FeO+MgO. Potash in the melt is highest just when biotite disappears. The amount of CaO decreases up to 900°C at 5 kbar
whereas at higher temperatures it increases as amphibole, clinopyroxene and more An-component dissolve in the melt. The Na2O content of the melt increases slightly with increase in temperature. The composition of the melt at temperatures > 900°C
approaches that of the starting assemblage. The melt fraction varies with composition and proportion of hydrous phases in
the starting composition as well as temperature and pressure. With increasing modal biotite from 20 to 30 wt%, the melt proportion
increases from 19.8 to 22.3 vol.% (850°C and 5 kbar). With increasing temperature from 800 to 950°C (at 5 kbar), the increase
in melt fraction is from 11 to 25.8 vol.%. The effect of pressure on the melt fraction is observed to be relatively small
and the melt proportion in the same assemblage decreases at 850°C from 19.8 vol.% at 5 kbar to 15.3 vol.% at 15 kbar. Selected
experiments were reversed at 2 and 5 kbar to demonstrate that near equilibrium compositions were obtained in runs of longer
duration.
Received: 27 December 1995 / Accepted: 7 May 1996 相似文献
6.
Geochemical exploration for platinum-group elements in the Bushveld Complex, South Africa 总被引:2,自引:0,他引:2
H. J. Wilhelm H. Zhang F. L. Chen J. H. Elsenbroek M. Lombard D. de Bruin 《Mineralium Deposita》1997,32(4):349-361
Analyses of stream sediment and soil samples from the Bushveld Complex, South Africa have revealed enhanced precious metal
concentrations, which can be related both to mining activities and the presence of hidden concentrations of platinum-group
elements (PGEs) and gold. The economically important PGE deposits hosted by the Upper Critical Zone of the Rustenburg Layered
Suite are revealed by a high PGE and Au content in the overlying soils. A second zone of elevated precious metal concentrations
straddles the boundary between the Main and Upper Zones and has to date been traced for more than 100 km. This zone follows
the igneous layering of the Rustenburg Layered Suite and is offset by the Brits Graben. It is therefore thought to be the
reflection of a magmatic PGE-Au mineralisation.
Received: 31 May 1996 / Accepted: 7 January 1997 相似文献
7.
孙玉壮 《中国地球化学学报》2004,23(2):101-111
Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR). 相似文献
8.
Mary Downes Gastrich Justine A. Leigh-Bell Christopher J. Gobler O. Roger Anderson Steven W. Wilhelm Martha Bryan 《Estuaries and Coasts》2004,27(1):112-119
Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York. 相似文献
9.
Jens Radke Achim Bechtel Wilhelm Püttmann Dirk Sachse 《Geochimica et cosmochimica acta》2005,69(23):5517-5530
We investigated the influence of thermal maturity on the hydrogen isotope ratios of sedimentary hydrocarbons to prove that the isotope ratio of hydrocarbons mirrors paleoclimate signatures. δD values from n-alkanes and acyclic isoprenoids of two sediment sections (Kupferschiefer [KS], 258 Ma, and Posidonienschiefer [PS], 184 Ma) with different maturation history were investigated. Both covered thermal maturity from 0.48 to 1.3 Rc (vitrinite reflectance and reflectance calculated from MPI1). Sediment burial up to 4500 m caused thermal maturation of organic matter in the KS horizon from the Early Zechstein basin of Poland, whereas contact metamorphic thermal maturation originated in the Early Toarcian PS (Posidonienschiefer) of the North German Vlotho Massif. The δD values of the extracted n-alkanes positively correlate with thermal maturity in the KS (y = 56‰ × MPI1[x] − 160‰ [VSMOW]) and in the PS (y = 104‰ × MPI1[x] − 200‰ [VSMOW]). The δD values of isoprenoids (i.e., pristane, phytane) were even more enriched with increasing maturity (y = 179‰ × MPI1[x] − 341‰ [VSMOW] in the KS; y = 300‰ × MPI1[x] − 415‰ [VSMOW] in PS).These results explain why isotope ratios of n-alkanes and isoprenoids in mature sediments are generally enriched in D and do not have the expected isotopic difference between n-alkanes and isoprenoids of ∼190‰. Moreover, the correlation between sediment maturity parameters and δD values suggests that after correction the δD values of n-alkanes can be used to reconstruct climate and environment in the geological past. 相似文献
10.
Torgeir O. Rthe Jostein Bakke Eivind Wilhelm Nagel Stren 《Boreas: An International Journal of Quaternary Research》2019,48(3):616-634
A sudden release of large volumes of water during a glacier outburst flood (GLOF) is a major hazard worldwide. Here, we identify the sedimentary signature of glacial and non‐glacial processes, including GLOFs, based on lacustrine sediments from the distal glacier‐fed Lake Buarvatnet in western Norway. Historically documented GLOFs in 2002 CE and during the 1980s CE are identified in the 210Pb‐ and 14C‐dated sediments. These events have the same sedimentary signature as 12 earlier events throughout the Holocene interpreted to represent previous GLOFs in the catchment. The GLOFs are interpreted to have occurred during periods when the glacier extent was similar to the modern positions, and the events are thus used to pinpoint past positions of the glacier terminus and, hence, the equilibrium line altitudes (ELAs). The results indicate that the glacier Svartenutbreen, located at the eastern part of Folgefonna, had a similar size in 2002 CE as c. 8200–8300 cal. a BP, corresponding to the 8.2 ka event in the North Atlantic region. The regrowth of Sørfonna after the Holocene Thermal Optimum occurred at c. 6900 cal. a BP and Svartenutbreen was at modern size and extent in the periods c. 6400, c. 5450, c. 4850, c. 3850, c. 3550 and c. 1650 cal. a BP. Since 1650 cal. a BP, we infer that the glacier was larger than the 2002 CE glacier extent until 1910 CE when a GLOF occurred. Svartenutbreen has been retreating since 1910 CE, which led to the ice damming of the two historical GLOFs in the 1980s and 2002 CE separated by a glacier advance in the 1990s CE. The findings are discussed and compared to other regional glacier reconstructions in Norway, and emphasize the value of identifying and utilizing GLOFs as an indicator of past ELA variability. 相似文献