Origins of high pH mineral waters from ultramafic rocks, Central Portugal

This paper reviews the geochemical, isotopic (²H, ¹⁸O, ¹³C, ³H and ¹⁴C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO₃ type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ²H and δ¹⁸O suggest a common meteoric origin and that the Mg–HCO₃ type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO₃ to Mg–HCO₃ waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO₂ (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of ¹⁴C and ¹³C values, which is in agreement with the ³H concentrations being below the detection limit.     

Management of a shallow temperate estuary to control eutrophication: The effect of hydrodynamics on the system’s nutrient loading

The Mondego estuary, a shallow warm-temperate intertidal system located on the west coast of Portugal, has for some decades been under severe ecological stress, mainly caused by eutrophication. Water circulation in this system was, until 1998, mainly dependent on tides and on the freshwater input of a small tributary artificially controlled by a sluice. After 1998, the sluice opening was effectively minimised to reduce the nutrient loading, and the system hydrodynamics improved due to engineering work in the upstream areas. The objective of the present study was to evaluate the effect of the mitigation measures implemented in 1998. Changes to the hydrodynamics of the system were assessed using precipitation and salinity data in relation to the concentrations of dissolved inorganic nutrients, as well as the linkage between dissolved N:P ratios and the biological parameters (phytoplankton chlorophyll a concentrations, green macroalgal biomass and seagrass biomass). Two distinctive periods were compared, over a ten year period: from January 1993 to January 1997 and from January 1999 until January 2003. The effective reduction in the dissolved N:P atomic ratio from 37.7 to 13.2 after 1998 is a result of lowered ammonia, but not the oxidised forms of nitrogen (nitrate plus nitrite), or increased concentrations of dissolved inorganic phosphorus. Results suggest that the phytoplankton is not nutrient limited, yet maximum and mean biomass of green macroalgae was reduced by one order of magnitude after the mitigation measures. This suggests that besides lowering the water residence time of the system, macroalgal growth became nitrogen limited. In parallel to these changes the seagrass-covered area and biomass of Zostera noltii showed signs of recovery.     

Comparison of the biology, dynamics, and secondary production of Talorchestia brito (Amphipoda, Talitridae) in Atlantic (Portugal) and Mediterranean (Tunisia) populations

The biology, population dynamics, and production of Talorchestia brito were studied at two sandy beaches located on the Atlantic (Portugal) and on the Mediterranean (Tunisia) coasts, respectively. The seasonal variation in abundance and the overall densities were similar in both populations. Reproduction occurred from February to September in the Atlantic, and from March to early November in the Mediterranean. The sex ratio was male biased in the Atlantic, and female biased in the Mediterranean. Based on data from the Atlantic population, both abundance and the proportion of reproductive females were positively correlated with temperature, while the proportion of juveniles in the population was positively correlated with temperature and sediment moisture. On average, individuals from the Atlantic were larger than the ones from the Mediterranean. Life span was estimated at six to nine months in the Atlantic, and five to eight months in the Mediterranean. Talorchestia brito was shown to be a semiannual species, with iteroparous females producing two broods per year, and exhibited a bivoltine life cycle. The minimum age required for males' and females' sexual differentiation and for female sexual maturation was shorter in the Mediterranean. Growth production (P) was estimated at 0.19 g m⁻² y⁻¹ ash free dry weight (AFDW; 4.3 kJ m⁻² y⁻¹) in the Atlantic population, and 0.217 g m⁻² y⁻¹ AFDW (4.9 kJ m⁻² y⁻¹) in the Mediterranean one. Elimination production (E) was estimated at 0.35 g m⁻² y⁻¹ AFDW (7.9 kJ m⁻² y⁻¹) in the Atlantic, and 0.28 g m⁻² y⁻¹ AFDW (6.3 kJ m⁻² y⁻¹) in the Mediterranean. The average annual biomass ( ) (standing stock) was estimated at 0.032 g m⁻² in the Atlantic beach, and 0.029 g m⁻² in the Mediterranean one, resulting, respectively, in ratios of 5.9 and 7.5 and ratios of 10.8 and 9.6. Like other talitrids, T. brito exhibited geographic variation in morphometrical characteristics, sex ratio, growth rates, life span, and reproduction period, with the Atlantic population presenting a slower life history.     

The July 1974 solar events: A possible lower limit for microwave activity

The active region McMath 10433 was the source of several flares and radio outbursts during the early part of July 1974. This region was tracked continuously, for several periods during the month at 22.2 GHz using a telescope with a 4 beam. Comparison with the results obtained simultaneously with a normal 7 GHz solar patrol instrument indicate that there is important burst activity occurring at levels below the detection limit of normal solar patrol instruments. The time-development morphology of these bursts is similar to those normally observed and has enabled the simple events to be re-interpreted. A completely new type of event - the fast absorption - has also been recognized. The correlation of the microwave events with SPA events observed on VLF propagation is also discussed.Spending a sabbatical year at CRAAM, São Paulo, Brazil.     

Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

Mineralogy, geochemistry, and Nd isotope composition of the Rainbow hydrothermal field, Mid-Atlantic Ridge

Petrological, geochemical, and Nd isotopic analyses have been carried out on rock samples from the Rainbow vent field to assess the evolution of the hydrothermal system. The Rainbow vent field is an ultramafic-hosted hydrothermal system located on the Mid-Atlantic Ridge characterized by vigorous high-temperature venting (∼365°C) and unique chemical composition of fluids: high chlorinity, low pH and very high Fe, and rare earth element (REE) contents (Douville et al., Chemical Geology 184:37–48, 2002). Serpentinization has occurred under a low-temperature (<270°C) retrograde regime, later overprinted by a higher temperature sulfide mineralization event. Retrograde serpentinization reactions alone cannot reproduce the reported heat and specific chemical features of Rainbow hydrothermal fluids. The following units were identified within the deposit: (1) nonmineralized serpentinite, (2) mineralized serpentinite—stockwork, (3) steatite, (4) semimassive sulfides, and (5) massive sulfides, which include Cu-rich massive sulfides (up to 28wt% Cu) and Zn-rich massive sulfide chimneys (up to 5wt% Zn). Sulfide mineralization has produced significant changes in the sulfide-bearing rocks including enrichment in transition metals (Cu, Zn, Fe, and Co) and light REE, increase in the Co/Ni ratios comparable to those of mafic Cu-rich volcanic-hosted massive sulfide deposits and different ¹⁴³Nd/¹⁴⁴Nd isotope ratios. Vent fluid chemistry data are indicative of acidic, reducing, and high temperature conditions at the subseafloor reaction zone where fluids undergo phase separation most likely under subcritical conditions (boiling). An explanation for the high chlorinity is not straightforward unless mixing with high salinity brine or direct contribution from a magmatic Cl-rich aqueous fluid is considered. This study adds new data, which, combined with the current knowledge of the Rainbow vent field, brings compelling evidence for the presence, at depth, of a magmatic body, most likely gabbroic, which provides heat and metals to the system. Co/Ni ratios proved to be good tools used to discriminate between rock units, degree of sulfide mineralization, and positioning within the hydrothermal system. Deeper units have Co/Ni <1 and subsurface and surface units have Co/Ni >1.     

Topography as a major factor in the development of arcuate thrust belts: insights from sandbox experiments

We have used sandbox experiments to investigate and to illustrate the effects of topography upon the development of arcuate thrust belts. In experiments where a sand pack shortened and thickened in front of an advancing rectilinear piston, the geometry of the developing thrust wedge was highly sensitive to variations in surface topography. In the absence of erosion and sedimentation, the surface slope tended to become uniform, as predicted by the theory of critical taper. Under these conditions, the wedge propagated by sequential accretion of new thrust slices. In contrast, where erosion or sedimentation caused the topographic profile to become irregular, thrusts developed out of sequence. For example, erosion throughout a hinterland caused underlying thrusts to remain active and inhibited the development of new thrusts in the foreland. Where initial topography was irregular in plan view, accreting thrusts tended to be arcuate. They were convex towards the foreland, around an initially high area; concave towards the foreland, around an initially low area. Initial plateaux tended to behave rigidly, while arcuate thrust slices accreted to them. Thrust motions were radial with respect to each plateau. Within transfer zones to each side, fault blocks rotated about vertical axes and thrust motions were oblique-slip. At late stages of deformation, the surface slope of the thrust wedge tended towards a uniform value. Initial mountains of conical shape (representing volcanoes) also escaped deformation, except at depth, where they detached. Arcuate thrust slices accreted to front and back. Where a developing thrust wedge was subject to local incision, accreting thrust slices dipped towards surrounding areas of high topography, forming Vs across valleys.Arcuate structural patterns are to be found around the three highest plateaux on Earth (Tibet, Pamirs and Altiplano) and around the Tromen volcanic ridge in the Neuquén Basin of northern Patagonia. We infer that these areas behaved in quasi-rigid fashion, protected as they were by their high topography.     

Hazard mapping based on macroseismic data considering the influence of geological conditions

The object of this study is to consider directly the influence of regional geological conditions on the assessment of seismic hazard. It is assumed that macroseismic data at individual locations contain, in an average way, the influence of geological conditions.A Data Base referring to 199 historical (5) and instrumental (194, in the 1947–1993 period) events with macroseismic information in 1195 locations of Portugal was built. For any given seismic event, whenever macroseismic information was available at a location (town, village, etc.), an EMS-92 intensity value was estimated. To each one of those locations a geological unit, representing the most common type of soil, was assigned, based on the Geological Portuguese Map at a scale 1:500 000; the geological units were grouped into three categories: soft, intermediate and hard soils.The Data Base was used to determine the attenuation laws in terms of macroseismic intensity for the three different geological site conditions, using multiple linear regression analysis. The reasonability of the laws was tested by (i) checking residual distributions and (ii) comparing the map of isoseismals of important earthquakes with the isoseismals generated by the attenuation curves derived for each one of the three different soil classes, taking into consideration the soil class of each site. The main results of attenuation modeling are: high dispersion on macroseismic intensity data; all the models predict intensity values, for short hypocentral distances, lower than the ones observed; and for some important analyzed earthquakes and for the observed range of distances, the models confirm the expectancy that macroseismic intensity increases from hard to soft soil.The approach to obtain the hazard assessment at each location consisted in the use of the attenuation law specifically derived for the class of soil of that particular location. This method, which considers the influence of the regional geology, was illustrated with the mapping of hazard for the country for several return periods. Comparison with previous maps not taking into consideration the regional geological conditions emphasizes the importance of this new parameter. It can be concluded that (i) soil segmentation is clearly the cause for hazard increase in the region to the north of Lisbon, especially at sites with soft and intermediate soils as the ones in lower Tagus valley; the maximum increase on hazard is, in any case, less than one degree; (ii) when geological conditions are disregarded in the attenuation regression analysis, hazard pattern is similar to the one obtained for the case of hard soil everywhere.     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.