Identifying the potential loss of monitoring wells using an uncertainty analysis

From the mid-1940s through the 1980s, large volumes of waste water were discharged at the Hanford Site in southeastern Washington State, causing a large-scale rise (>20 m) in the water table. When waste water discharges ceased in 1988, ground water mounds began to dissipate. This caused a large number of wells to go dry and has made it difficult to monitor contaminant plume migration. To identify monitoring wells that will need replacement, a methodology has been developed using a first-order uncertainty analysis with UCODE, a nonlinear parameter estimation code. Using a three-dimensional, finite-element ground water flow code, key parameters were identified by calibrating to historical hydraulic head data. Results from the calibration period were then used to check model predictions by comparing monitoring wells' wet/dry status with field data. This status was analyzed using a methodology that incorporated the 0.3 cumulative probability derived from the confidence and prediction intervals. For comparison, a nonphysically based trend model was also used as a predictor of wells' wet/dry status. Although the numerical model outperformed the trend model, for both models, the central value of the intervals was a better predictor of a wet well status. The prediction interval, however, was more successful at identifying dry wells. Predictions made through the year 2048 indicated that 46% of the wells in the monitoring well network are likely to go dry in areas near the river and where the ground water mound is dissipating.     

An Injectable Apatite Permeable Reactive Barrier for In Situ 90Sr Immobilization

An injectable permeable reactive barrier (PRB) technology was developed to sequester ⁹⁰Sr in groundwater through the in situ formation of calcium‐phosphate mineral phases, specifically apatite that incorporates ⁹⁰Sr into the chemical structure. This injectable barrier technology extends the PRB concept to sites where groundwater contaminants are too deep or where site conditions otherwise preclude the application of more traditional trench‐emplaced barriers. An integrated, multiscale development and testing approach was used that included laboratory bench‐scale experiments, an initial pilot‐scale field test, and the emplacement and evaluation of a 300‐feet‐long treatability‐test‐scale PRB. The apatite amendment formulation uses two separate precursor solutions, one containing a Ca‐citrate complex and the other a Na‐phosphate solution, to form apatite precipitate in situ. Citrate is needed to keep calcium in solution long enough to achieve a more uniform and areally extensive distribution of precipitate formation. In the summer of 2008, the apatite PRB technology was applied as a 91‐m‐long (300 feet) PRB on the downgradient edge of a ⁹⁰Sr plume beneath the Hanford Site in Washington State. The technology was deployed to reduce ⁹⁰Sr flux discharging to the Columbia River. Performance assessment monitoring data collected to date indicate that the barrier is meeting treatment objectives (i.e., 90% reduction in ⁹⁰Sr concentration). The average reduction in ⁹⁰Sr concentrations at four downgradient compliance monitoring locations was 95% relative to the high end of the baseline range approximately 1 year after treatment, and continues to meet remedial objectives more than 4 years after treatment.     

River-induced flow dynamics in long-screen wells and impact on aqueous samples

Previously published field investigations and modeling studies have demonstrated the potential for sample bias associated with vertical wellbore flow in conventional monitoring wells constructed with long-screened intervals. This article builds on the existing body of literature by (1) demonstrating the utility of continuous (i.e., hourly measurements for ～1 month) ambient wellbore flow monitoring and (2) presenting results from a field experiment where relatively large wellbore flows (up to 4 L/min) were induced by aquifer hydrodynamics associated with a fluctuating river boundary located approximately 250 m from the test well. The observed vertical wellbore flows were strongly correlated with fluctuations in river stage, alternating between upward and downward flow throughout the monitoring period in response to changes in river stage. Continuous monitoring of ambient wellbore flows using an electromagnetic borehole flowmeter allowed these effects to be evaluated in concert with continuously monitored river-stage elevations (hourly) and aqueous uranium concentrations (daily) in a long-screen well and an adjacent multilevel well cluster. This study demonstrates that when contaminant concentrations within the aquifer vary significantly over the depth interval interrogated, river-induced vertical wellbore flow can result in variations in measured concentration that nearly encompass the full range of variation in aquifer contaminant concentration with depth.     

Field Test of Enhanced Remedial Amendment Delivery Using a Shear‐Thinning Fluid

Heterogeneity of hydraulic properties in aquifers may lead to contaminants residing in lower‐permeability zones where it is difficult to deliver remediation amendments using conventional injection processes. The focus of this study is to examine use of a shear‐thinning fluid (STF) to improve the uniformity of remedial amendment distribution within a heterogeneous aquifer. Previous studies have demonstrated the significant potential of STFs for improving remedial amendment delivery in heterogeneous aquifers, but quantitative evaluation of these improvements from field applications is lacking. A field‐scale test was conducted that compares data from successive injection of a tracer in water followed by injection of a tracer in an STF to evaluate the impact of the STF on tracer distribution uniformity in the presence of permeability contrasts within the targeted injection zone. Data from tracer breakthrough at multiple depth‐discrete monitoring intervals and electrical resistivity tomography (ERT) showed that inclusion of STF in the injection solution improved the distribution of the injected fluid within the targeted treatment zone. One improvement was a reduction in the movement of injected fluids through high‐permeability pathways, as evidenced by slower breakthrough of tracer at monitoring locations where breakthrough in baseline tracer‐only injection data was faster. In addition, STF‐amended injection solutions arrived faster and to a greater extent in monitoring locations within low‐permeability zones. ERT data showed that the STF injection covered a higher percentage of a two‐dimensional cross section within the injection interval between the injection well and a monitoring well about 3 m away.     

Vertical Dynamics of the Energy Release Process in a Simple two-Ribbon Flare

Observations of the quiescent filament eruption and the spotless two-ribbon flare of 12 September 2000 are presented. A simple flare morphology, large spatial scales, and a suitable viewing angle provide insight into characteristics of the energy release process which is attributed to the reconnection process in the current sheet formed below the eruptive filament. The flare ribbons appeared and started to expand laterally while the filament was still recognizable, enabling simultaneous measurements of the ribbon separation w and the height of the lower edge of the filament, h. The ratio w/h estimated for the expanding portions of ribbons indicates that the width-to-length ratio of the current sheet at the onset of the fast reconnection ranges between and . The ribbon elements characterized by w/h> remained stationary. The Nançay radioheliograph data in the decimeter–meter wavelengths show one group of radio bursts ahead of the filament (moving type IV burst) and another group behind the filament. The centroids of the radio sources behind the filament were confined to the region outlined by the lower edge of the filament and the magnetic inversion line, suggestive of emission from the current sheet. Sources were preferably located close to the lower edge of the filament and some appeared close to the magnetic inversion line. Two possible explanations are discussed: one in terms of the fast-mode bow shocks in the reconnection outflow jets, and another in terms of a multiple tearing of the current sheet and subsequent coalescence of plasmoids.     

Use of Improved Hydrologic Testing and Borehole Geophysical Logging Methods for Aquifer Characterization

Depth-discrete aquifer in formal ion was obtained using recently developed adaptations and improvements to conventional characterization techniques. These improvements included running neutron porosity and hulk density geophysical logging tools through a cased hole, performing an enhanced point-dilution tracer test for monitoring tracer concentration as a function of Lime and depth, and using pressure derivatives for diagnostic and quantitative analysis of constant rate discharge lest data. Data results from the use of these techniques were used to develop a conceptual model of a heterogeneous aquifer. Depth-discrete aquifer information was required to effectively design field-scale deployment and monitoring of an in situ bioremediation technology.
Geophysical logging and point-dilution tracer test results provided the relative distribution of porosity and horizontal hydraulic conductivity, respectively, with depth and correlated well. Hydraulic pumping tests were conducted to estimate mean values for transmissivity and effective hydraulic conductivity, Tracer lest and geophysical logging results indicated that ground water flow was predominant in the upper approximate 10 feet of the aquifer investigated. These results were used to delineate a more representative interval thickness for estimating effective hydraulic conductivity. Hydraulic conductivity, calculated using this representative interval, was estimated lo be 73 ft/d, approximately three limes higher than that calculated using the full length of the screened test interval.     

Injection of Zero‐Valent Iron into an Unconfined Aquifer Using Shear‐Thinning Fluids

Approximately 190 kg of 2 μm‐diameter zero‐valent iron (ZVI) particles were injected into a test zone in the top 2 m of an unconfined aquifer within a trichloroethene (TCE) source area. A shear‐thinning fluid was used to enhance ZVI delivery in the subsurface to a radial distance of up to 4 m from a single injection well. The ZVI particles were mixed in‐line with the injection water, shear‐thinning fluid, and a low concentration of surfactant. ZVI was observed at each of the seven monitoring wells within the targeted radius of influence during injection. Additionally, all wells within the targeted zone showed low TCE concentrations and primarily dechlorination products present 44 d after injection. These results suggest that ZVI can be directly injected into an aquifer with shear‐thinning fluids to induce dechlorination and extends the applicability of ZVI to situations where other emplacement methods may not be viable.     

ON THE POSSIBLE CHANGES OF THE SOLAR DIFFERENTIAL ROTATION DURING THE ACTIVITY CYCLE DETERMINED USING MICROWAVE LOW-BRIGHTNESS-TEMPERATURE REGIONS AND Hα FILAMENTS AS TRACERS

The solar rotation rate obtained using the microwave Low-brightness-Temperature Regions (LTRs) as tracers in the heliographic range ± 55° from the years 1979–1980, 1981–1982, 1987–1988, and 1989–1991 varied from 3% to 4% in medium latitudes, and below 1% at the equator. Using H filaments as tracers at higher latitudes from the years 1979, 1980, 1982, 1984, and 1987, the solar rotation rate variation was between 2% and 8%. This represents an upper limit on the rotation rate variation during the solar activity cycle. Such changes could be caused by short-lived, large-scale velocity patterns on the solar surface. The Sun revealed a higher rotation rate on the average during the maxima of the solar activity cycles 21 and 22, i.e., in the periods 1979–1980 and 1989–1991, respectively, which differs from the rotation rates (lower on the average) in some years, 1981–1982 and 1987–1988, between the activity maximum and minimum (LTR data). Simultaneous comparison of rotation rates from LTRs and H filament tracings was possible in very limited time intervals and latitude bands only, and no systematic relationship was found, although the rotation rates determined by LTRs were mostly smaller than the rotation rates determined by H filaments. The errors obtained by applying different fitting procedures of the LTR data were analyzed, as well as the influence of the height correction. Finally, the north–south asymmetry in the rotation rate investigated by LTRs indicates that the southern solar hemisphere rotated slower in the periods under consideration, the difference being about 1%. The reliability of all obtained results is discussed and a comparison with other related studies was performed.     

Vertical Wellbore Flow Monitoring for Assessing Spatial and Temporal Flow Relationships with a Dynamic River Boundary

A useful tool for identifying the temporal and spatial ambient wellbore flow relationships near a dynamic river boundary is to monitor ambient vertical wellbore flow with an electromagnetic borehole flowmeter. This is important because the presence of the wellbore can result in significant mixing or exchange of groundwater vertically across the aquifer. Mixing or exchanging groundwater within the well-screen section can have significant impacts on the distribution of contaminants within the aquifer and adverse effects on the representativeness of groundwater samples collected from the monitoring well. Ambient monitoring data, collected from long screened wells at Hanford’s 300-Area Integrated Field Research Challenge site, located approximately 260 m from the Columbia River, demonstrate that vertical wellbore flow exhibits both a positive and inverse temporal relationship with periodic river-stage fluctuations that can change over short distances between wells. The spatial distribution of these vertical flows across the well field indicates two general regions of ambient wellbore flow behavior. The western region of the site is characterized by vertical flows that are positively related to river-stage fluctuations. In contrast, the eastern region of the site exhibits vertical flows that are inversely related to river-stage fluctuations. The cause of this opposite relationship is not completely understood; however, the positive relationships appear to be associated with high-energy Hanford formation flood deposits. These flood deposits have a well-defined northwest-southeast trend and are believed to coincide with a local paleochannel. The inverse relationships are attributed to an erosional, subsurface high in the Hanford/Ringold Formation contact between the site and the Columbia River. Under these complex hydrogeologic and hydrodynamic conditions, the behavior of ambient vertical wellbore flow in monitoring wells near a dynamic river boundary can have important implications for collecting groundwater-quality samples, for contributing to contaminant distribution within an aquifer system, and for implementing effective remediation strategies.