Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)

Sphene (CaTiSiO₅), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO₃, TiO₂ and SiO₂ using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 °C, sphene undergoes into phase transition, from room-temperature phase P2₁ /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy.     

Dependence of the power consumed by the magnetosphere on the solar wind parameters

The results of the previous studies, where the expressions were obtained for the electric current, which is generated at the bow shock front and is closed through the magnetosphere, and for the magneto-pause potential as a function of such solar wind parameters as the plasma density and velocity and the IMF intensity, are used. The power (W) consumed by the magnetosphere is equal to the Poynting vector flux S through the magnetopause. According to the special case of the Poynting theorem applied by Heikkila to the-magnetosphere, the energy flux can be expressed in terms of the electric potential (the integration is carried out over the entire surface of the magnetosphere). As a result, the required dependence, which is quadratic with respect to the IMF B _z component, has been obtained for W. It is discussed why the magnetosphere is energy-isolated at the northward IMF B _z component despite this.