Uranium co-precipitation with iron oxide minerals

In oxidizing environments, the toxic and radioactive element uranium (U) is most soluble and mobile in the hexavalent oxidation state. Sorption of U(VI) on Fe-oxides minerals (such as hematite [α-Fe₂O₃] and goethite [α-FeOOH]) and occlusion of U(VI) by Fe-oxide coatings are processes that can retard U transport in environments. In aged U-contaminated geologic materials, the transport and the biological availability of U toward reduction may be limited by coprecipitation with Fe-oxide minerals. These processes also affect the biological availability of U(VI) species toward reduction and precipitation as the less soluble U(IV) species by metal-reducing bacteria.To examine the dynamics of interactions between U(VI) and Fe oxides during crystallization, Fe-oxide phases (containing 0.5 to 5.4 mol% U/(U + Fe)) were synthesized by means of solutions of U(VI) and Fe(III). Wet chemical (digestions and chemical extractions) and spectroscopic techniques were used to characterize the synthesized Fe oxide coprecipitates after rinsing in deionized water. Leaching the high mol% U solids with concentrated carbonate solution (for sorbed and solid-phase U(VI) species) typically removed most of the U, leaving, on average, about 0.6 mol% U. Oxalate leaching of solids with low mol% U contents (about 1 mol% U or less) indicated that almost all of the Fe in these solids was crystalline and that most of the U was associated with these crystalline Fe oxides. X-ray diffraction and Fourier-transform infrared (FT-IR) spectroscopic studies indicate that hematite formation is preferred over that of goethite when the amount of U in the Fe-oxides exceeds 1 mol% U (∼4 wt% U). FT-IR and room temperature continuous wave luminescence spectroscopic studies with unleached U/Fe solids indicate a relationship between the mol% U in the Fe oxide and the intensity or existence of the spectra features that can be assigned to UO₂²⁺ species (such as the IR asymmetric υ₃ stretch for O = U = O for uranyl). These spectral features were undetectable in carbonate- or oxalate-leached solids, suggesting solid phase and sorbed U(VI)O₂²⁺ species are extracted by the leach solutions. Uranium L₃-edge x-ray absorption spectroscopic (XAFS) analyses of the unleached U-Fe oxide solids with less than 1 mol% U reveal that U(VI) exists with four O atoms at radial distances of 2.19 and 2.36 Å and second shell Fe at a radial distance at 3.19 Å.Because of the large ionic radius of UO₂²⁺ (∼1.8 Å) relative to that of Fe³⁺ (0.65 Å), the UO₂²⁺ ion is unlikely to be incorporated in the place of Fe in Fe(III)-oxide structures. Solid-phase U(VI) can exist as the uranyl [U(VI)O₂²⁺] species with two axial U-O double bonds and four or more equatorial U-O bonds or as the uranate species (such as γ-UO₃) without axial U-O bonds. Our findings indicate U⁶⁺ (with ionic radii of 0.72 to 0.8 Å, depending on the coordination environment) is incorporated in the Fe oxides as uranate (without axial O atoms) until a point of saturation is reached. Beyond this excess in U concentration, precipitating U(VI) forms discrete crystalline uranyl phases that resemble the uranyl oxide hydrate schoepite [UO₂(OH)₂·2H₂O]. Molecular modeling studies reveal that U⁶⁺ species could bond with O atoms from distorted Fe octahedra in the hematite structure with an environment that is consistent with the results of the XAFS. The results provide compelling evidence of U incorporation within the hematite structure.     

Galactic Dynamo and Spiral Arms - 3D MHD Simulations

In the present project we investigate the evolution of a three-dimensional (3D), large-scale galactic magnetic field under the influence of gas flows in spiral arms and in the presence of dynamo action. Our principal goal is to check how the dynamical evolution of gaseous spiral arms affects the global magnetic field structure and to what extent our models could explain the observed spiral patterns of polarization B-vectors in nearby galaxies. A two-step scheme is used: the N-body simulations of a two-component, self-gravitating disk provide the time-dependent velocity fields which are then used as the input to solve the mean-field dynamo equations. We found that the magnetic field is directly influenced by large-scale non-axisymmetric density wave flows yielding the magnetic field locally well-aligned with gaseous spiral arms in a manner similar to that discussed already by Otmianowska-Mazur et al. 1997. However, an additional field amplification, introduced by a non-zero -term in the dynamo equations, is required to cause a systematic increase of magnetic energy density against the diffusive losses. Our simulated magnetic fields are also used to construct the models of a high-frequency (Faraday rotation-free) polarized radio emission accounting for effects of projection and limited resolution, thus suitable for direct comparisons with observations.     

Magnetic Fields in Cluster and Interacting Galaxies

Our VLA and Effelsberg radio polarization studies of the interacting and cluster galaxies (NGC 3627, NGC 4038/39, NGC 4254) show that magnetic fields could help us in understanding galaxy peculiar gas motions and cluster environmental effects. This revised version was published online in September 2006 with corrections to the Cover Date.     

Locating the transgenic landscape: Animal biotechnology and politics of place in Massachusetts

The first major wave in the conflict over modern biotechnologies took place in the United States at the federal level. Biotechnology proponents were able to capture the federal regulatory structure, so today, a second wave of anti-biotech activism focused at the local and state levels is emerging. This article examines what enables or constrains place-based anti-biotech activism through a case study of the conflict over genetically engineered (GE) animals in Massachusetts. I demonstrate how, in spite of a highly visible animal advocacy and anti-GE presence, GE animal proponents have mobilized effective politics of place strategies to suppress local debate by exercising territorial control in relation to two places – the state of Massachusetts as a whole and the animal research laboratory specifically.     

Acceleration of cosmic-ray electrons by large-scale galactic spiral shocks — An observational report

The hypothesis that large-scale shocks accompanying spiral density waves are the main sources of cosmic-ray electrons for whole galactic disks has been tested utilizing results of 10.7 GHz observations of spiral galaxies. It is suggested that the 10.7 GHz emission of galactic disks is largely controlled by star-forming processes, and that large-scale shocks apparently play a minor role.