Effects of changes in canopy interception on stream runoff response and recovery following clear-cutting of a Japanese coniferous forest in Fukuroyamasawa Experimental Watershed in Japan

Understanding changes in evapotranspiration during forest regrowth is essential to predict changes of stream runoff and recovery after forest cutting. Canopy interception (Ic) is an important component of evapotranspiration, however Ic changes and the impact on stream runoff during regrowth after cutting remains unclear due to limited observations. The objective of this study was to examine the effects of Ic changes on long-term stream runoff in a regrowth Japanese cedar and Japanese cypress forest following clear-cutting. This study was conducted in two 1-ha paired headwater catchments at Fukuroyamasawa Experimental Watershed in Japan. The catchments were 100% covered by Japanese coniferous plantation forest, one of which was 100% clear-cut in 1999 when the forest was 70 years old. In the treated catchment, annual runoff increased by 301 mm/year (14% of precipitation) the year following clear-cutting, and remained 185 mm/year (7.9% of precipitation) higher in the young regrowth forest for 12–14 years compared to the estimated runoff assuming no clear-cutting. The Ic change was −358 mm/year (17% of precipitation) after cutting and was −168 mm/year (6.7% of precipitation) in the 12–14 years old regrowth forest compared to the observed Ic during the pre-cutting period. Stream runoff increased in all seasons, and the Ic change was the main fraction of evapotranspiration change in all seasons throughout the observation period. These results suggest that the change in Ic accounted for most of the runoff response following forest cutting and the subsequent runoff recovery in this coniferous forest.     

Noble gases in ureilites released by crushing

Abstract— Noble gases in two ureilites, Kenna and Allan Hills (ALH) 78019, were measured with two extraction methods: mechanical crushing in a vacuum and heating. Large amounts of noble gases were released by crushing, up to 26.5% of ¹³²Xe from ALH 78019 relative to the bulk concentration. Isotopic ratios of the crush‐released Ne of ALH 78019 resemble those of the trapped Ne components determined for some ureilites or terrestrial atmosphere, while the crush‐released He and Ne from Kenna are mostly cosmogenic. The crush‐released Xe of ALH 78019 and Kenna is similar in isotopic composition to Q gas, which indicates that the crush‐released noble gases are indigenous and not caused by contamination from terrestrial atmosphere. In contrast to the similarities in isotopic composition with the bulk samples, light elements in the crush‐released noble gases are depleted relative to Xe and distinct from those of each bulk sample. This depletion is prominent especially in the ²⁰Ne/¹³²Xe ratio of ALH 78019 and the ³⁶Ar/¹³²Xe ratio of Kenna. The values of measured ³He/²¹Ne for the gases released by crushing are significantly higher than those for heating‐released gases. This suggests that host phases of the crush‐released gases might be carbonaceous because cosmogenic Ne is produced mainly from elements with a mass number larger than Ne. Based on our optical microscopic observation, tabular‐foliated graphite is the major carbon mineral in ALH 78019, while Kenna contains abundant polycrystalline graphite aggregates and diamonds along with minor foliated graphite. There are many inclusions at the edge and within the interior of olivine grains that are reduced by carbonaceous material. Gaps can be seen at the boundary between carbonaceous material and silicates. Considering these petrologic and noble gas features, we infer that possible host phases of crush‐released noble gases are graphite, inclusions in reduction rims, and gaps between carbonaceous materials and silicates. The elemental ratios of noble gases released by crushing can be explained by fractionation, assuming that the starting noble gas composition is the same as that of amorphous carbon in ALH 78019. The crush‐released noble gases are the minor part of trapped noble gases in ureilites but could be an important clue to the thermal history of the ureilite parent body. Further investigation is needed to identify the host phases of the crush‐released noble gases.     

Feasibility of dumping fossil-fuel CO2 into the deep ocean

An idea has been proposed to recover and dispose of the fossil-fuel CO₂ generated by stationary power plants into the deep sea, thereby reducing the CO₂ emission to the atmosphere. The assessment of its environmental effects and risks is essential for developing new technology for the recovery/disposal system, which has recently received growing attention in Japan.The simple calculation made here did not yield any decisively significant environmental risks so far. However, a further detailed study is needed for the consequences of lowering local pH and the abrupt dissolution of CaCO₃ in the deep-sea sediments. It is also shown that, on longer term, the atmospheric concentration of CO₂ may be influenced by the degree at which the reaction between the disposed fossil-fuel CO₂ and the sedimentary CaCO₃ takes place under such conditions. At any rate, the problem should be brought to serious scientific attention much like the case of ocean dumping of radioactive wastes.     

Geochemistry and Origin of Ananai Stratiform Manganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Major and trace element contents are reported for Permian manganese ore and associated greenstone from the Ananai manganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The manganese deposit occurs between greenstone and red chert, or among red chert beds. Chemical compositions of manganese ore are characterized by enrichments in Mn, Ca, P, Co, Ni, Zn, Sr and Ba, and negative Ce and positive Eu anomalies relative to post-Archean average Australian Shale (PAAS). Geochemical features of the manganese ore are similar to those of modern submarine hydrother-mal manganese deposits from volcanic arc or hotspot setting. In addition, geochemical characteristics of the greenstone closely associated with the Ananai manganese deposit are analogous to those of with-in plate alkaline basalt (WPA). Consequently, the Ananai manganese deposit was most likely formed by hydrothermal activity related to hotspot volcanism in the Panthalassa Ocean during the Middle Permian. This is the first report documenting the terrestrially-exposed manganese deposit that was a submarine precipitate at hotspot.     

Evaluating the thermal metamorphism of CM chondrites by using the pyrolytic behavior of carbonaceous macromolecular matter

The degrees of thermal metamorphism of 10 CM chondrites and of the Allende CV3 chondrite were evaluated from the viewpoint of “graphitization” of the carbonaceous macromolecular matter by means of flash pyrolysis-gas chromatography (GC). The unheated chondrites, Yamato- (Y-) 791198, Murray and Cold Bokkeveld, yielded larger amounts and wider varieties of pyrolyzates than the chondrites strongly heated in the parent asteroids, Y-82054, Y-86695, and Belgica- (B-) 7904, and Asuka- (A-) 881334 (more strongly heated than Y-793321, which has been weakly heated, but lesser than the other strongly heated meteorites). The weakly heated chondrites, Y-793321 and A-881458, showed intermediate features. The data indicate that graphitization of the carbonaceous matter is most extreme in the strongly heated chondrites and that during graphitization, the matter has lost its labile portion, which can generate pyrolyzates such as naphthalene. In order to establish a new method for the evaluation of the degree of graphitization of chondritic carbonaceous matter, a diagram was developed to show the relationship between the total amounts of pyrolyzates with retention times later than 5 min (=S_RT>5) and the ratio of the amount of naphthalene, a pyrolysis product, to S_RT>5 (=S_N/S_RT>5). The diagram indicates a possible evolutionary pathway of graphitization of the carbonaceous matter in carbonaceous chondrites.     

Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Continuous measurement of whole‐tree water balance for studying urban tree transpiration

Street and garden trees in urban areas are often exposed to advection of strong vapour pressure deficit (VPD) air that can raise the whole‐tree transpiration rate (E_T), known as the oasis effect. However, urban trees tend to have small soil volume compared with natural conditions, and so they are believed to strongly regulate stomata. E_T characteristics of such urban trees have not been well understood because of a lack of reliable measurement methods. Therefore, we propose a novel weighing lysimeter method and investigate the whole‐tree water balance of an isolated container‐grown Zelkova serrata to examine (a) which biotic and abiotic factors determine E_T and (b) which spatial and temporal information is needed to predict E_T under urban conditions. Whole‐tree water balance and environmental conditions were measured from 2010 to 2012. Although leaf area substantially increased in the study period, daily E_T did not vary much. E_T increased with VPD almost linearly in 2010 but showed saturation in 2011 and 2012. Root water uptake lagged E_T by 40 min in 2012. These results suggest that the small planter box interfered with root growth and that hydraulic supply capacities did not increase sufficiently to support leaf area increase. From analysis of water balance, we believe that neglecting soil drought effects on street trees without irrigation in Japan will overestimate E_T over 4–5 sunny days at the longest. This is unlike previous studies of forest.