Wetlands and low-gradient topography are associated with longer hydrologic transit times in Precambrian Shield headwater catchments

The estimation of hydrologic transit times in a catchment provides insights into the integrated effects of water storage, mixing dynamics, and runoff generation processes. There has been limited effort to estimate transit times in southern boreal Precambrian Shield landscapes, which are characteristically heterogeneous with surface cover including till, thin soils, bedrock outcrops, and depressional wetland features that play contrasting hydrologic roles. This study presents approximately 3.5 years of precipitation and streamflow water isotope data and estimates mean transit times (MTTs) and the young water fraction (p_y) across six small catchments in the Muskoka-Haliburton region of south-central Ontario. The main objectives were to define a typical range of MTTs for headwater catchments in this region and to identify landscape variables that best explain differences in MTTs/p_y using airborne light detection and ranging and digital terrain analysis. Of the transit time distributions, the two parallel linear reservoir and gamma distributions best describe the hydrology of these catchments, particularly because of their ability to capture more extreme changes related to events such as snowmelt. The estimated MTTs, regardless of the modelling approach or distribution used, are positively associated with the percent wetland area and negatively with mean slope in the catchments. In this landscape, low-gradient features such as wetlands increase catchment scale water storage when antecedent conditions are dryer and decrease transit times when there is a moisture surplus, which plausibly explains the increases in MTTs and mean annual runoff from catchments with significant coverage of these landscape features.     

OSIRIS: AO-assisted integral-field spectroscopy at the Keck Observatory

OSIRIS (OH-Suppressing Infra-Red Integral-field Spectrograph) is a new facility instrument for the Keck Observatory. After seeing first light in February 2005, OSIRIS is currently undergoing commissioning. OSIRIS provides the capability of performing three-dimensional spectroscopy in the near-infrared z, J, H, and K bands at the resolution limit of the Keck II telescope, which is equipped with adaptive optics and a laser guide star. The science case for OSIRIS is summarized, and the instrument and associated data reduction software are described.     

Optical properties of solid and liquid sulfur at visible and infrared wavelengths

Knowledge of the optical constants of elemental sulfur has potential applications to Venus, Jupiter, Io, Amalthea, and the Earth. The real part, n, of the index of refraction of liquid sulfur (at 133°C) and of solid orthorhombic sulfur (at 25°C) for the wavelength range 0.4–2.0 μm were measured ellipsometrically. The imaginary part, k, of the refractive index of liquid sulfur was obtained by transmittance measurements at the same temperature and wavelength range. The reflectance of semi-infinite slabs of solid and liquid sulfur is calculated using the measured n and k values. We confirm that sulfur melts on Io would be classified as “black” by the Voyager imaging system.     

Confirmation of a meteoritic component in impact‐melt rocks of the Chesapeake Bay impact structure,Virginia, USA—Evidence from osmium isotopic and PGE systematics

Abstract— The osmium isotope ratios and platinum‐group element (PGE) concentrations of impact‐melt rocks in the Chesapeake Bay impact structure were determined. The impact‐melt rocks come from the cored part of a lower‐crater section of suevitic crystalline‐clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The ¹⁸⁷Os/¹⁸⁸Os ratios of impact‐melt rocks range from 0.151 to 0.518. The rhenium and platinum‐group element (PGE) concentrations of these rocks are 30–270x higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact‐melt rocks. Because the PGE abundances in the impact‐melt rocks are dominated by the target materials, interelemental ratios of the impact‐melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact‐melt rocks include a bulk meteoritic component of 0.01–0.1% by mass. Several impact‐melt rocks with lowest initial ¹⁸⁷Os/¹⁸⁸Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%–0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01–0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact‐melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact‐melt rocks, and 2) variable fractionations of PGE during syn‐ to post‐impact events.     

Controls on the chemistry of runoff from an upland peat catchment

This study uses 2 years of data from a detailed weekly water sampling programme in a 11·4 km² upland peat catchment in the Northern Pennines, UK. The sampling comprised precipitation, soil‐water samples and a number of streams, including the basin outlet. Samples were analysed for: pH, conductivity, alkalinity, Na, K, Ca, Mg, Fe, Al, Total N, SO₄, Cl and colour. Principal component analysis (PCA) was used to identify end‐members and compositional trends in order to identify controls on the development of water composition. The study showed that the direct use of PCA had several advantages over the use of end‐member mixing analysis (EMMA) as it combines an analysis of mixing and evolving waters without the assumption of having to know the compositional sources of the water. In its application to an upland peat catchment, the study supports the view that shallow throughflow at the catotelm/acrotelm boundary is responsible for storm runoff generation and shows that baseflow is controlled by cation exchange in the catotelm and mixing with a base‐rich groundwater. Copyright © 2003 John Wiley & Sons, Ltd.     

Stationary distribution function for non-adiabatic particle motion in a one dimensional current sheet

The problem of pitch angle scattering in field configurations similar to those found in the geomagnetic tail has been studied previously by Tsyganenko (1982). Tsyganenko used a scattering matrix to map pitch angle distributions through the current sheet. By using numerical solutions of the resulting integral equations he showed for weakly non-adiabatic particles the Stationary Distribution Function (SDF) was isotropic. Using his procedure the SDF was found to develop anisotropies with increasing non-adiabaticity. The work presented here shows analytically that for any degree of scattering the SDF must be isotropic for a general planar field reversal. Computations of particle trajectories have been used to verify some aspects of the analytic work.     

Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

Middle Stone Age starch acquisition in the Niassa Rift, Mozambique

The quest for direct lines of evidence for Paleolithic plant consumption during the African Middle Stone Age has led scientists to study residues and use-wear on flaked stone tools. Past work has established lithic function through multiple lines of evidence and the spatial breakdown of use-wear and microscopic traces on tool surfaces. This paper focuses on the quantitative analysis of starch assemblages and the botanical identification of grains from flake and core tools to learn about human ecology of carbohydrate use around the Niassa woodlands, in the Mozambican Rift. The processing of starchy plant parts is deduced from the occurrence of starch assemblages that presumably got attached to stone tool surfaces by actions associated with extractive or culinary activities. Specifically, we investigate starch grains from stone tools recently excavated in northern Mozambique at the site of Mikuyu; which presumably spans the middle to late Pleistocene and represents similar sites found along the Malawi/Niassa corridor that links East, Southern, and Central Africa. Starch was extracted and processed with a diverse tool kit consisting of scrapers, cores, points, flakes, and other kinds of tools. The microbotanical data suggests consumption of seeds, legumes, caryopses, piths, underground storage organs, nuts, and mesocarps from more than a dozen families. Our data suggest a great antiquity for starch use in Africa as well as an expanded diet and intensification.     

Inhomogeneous substrate analysis using EM300 backscatter imagery

Backscatter reflectivity from multibeam echo-sounders provides a powerful tool to efficiently characterize seafloor substrates. A comprehensive EM300 bathymetric and backscatter survey has been completed of Cook Strait, in central New Zealand. This paper presents a detailed analysis of the realtime corrections applied to the raw EM300 multibeam data and additional corrections required to compute angular variations of the backscatter strength. The corrections, including the local absorption coefficient, the influence of seafloor topography and sound refraction in the water column, are determined for different Cook Strait seafloor substrates. Modifying MB-System software code, we extracted the backscatter signal parameters in order to quantify the raw backscatter strength and apply additional processing. Profiles of backscatter strength versus incidence angle were computed for a variety of sites characterized by flat seafloor and homogeneous substrates, and for which ground-truth data were available. For each homogeneous site, different but characteristic backscatter profiles are observed that can be interpreted in terms of sediment facies. To analyze heterogeneous substrates, we present a statistical technique, based on a 3-dimensional distribution of (incidence angle, backscatter strength) couples that preserves geological information of the substrate components. This analysis, using backscatter data acquired on a submarine volcano, north of New Zealand, clearly differentiates soft sediments and lava flows within a heterogeneous substrate.     

Morphodynamics of a bar-trough surf zone

A field study was made of the distinguishing morphodynamic processes operating in a surf zone which perennially exhibits accentuated bar-trough topography (the “longshore-bar-trough” and “rhytmic-bar-and-beach” states as described by Wright and Short, 1984). Characteristic features of the morphology include a shallow bar with a steep shoreward face, a deep trough, and a steep beach face. This morphology, which is favored by moderate breaker heights and small tidal ranges, strongly controls the coupled suite of hydrodynamic processes. In contrast to fully dissipative surf zones, the bar-trough surf zone is not at all saturated and oscillations at incident wave frequency remain dominant from the break point to the subaerial beach. The degree of incident wave groupiness does not change appreciably across the surf zone. Infragravity standing waves which, in dissipative surf zones, dominate the inshore energy, remain energetically secondary and occur at higher frequencies in the bar trough surf zone. Analyses of the field data combined with numerical simulations of leaky mode and edge wave nodal—antinodal positions over observed surf-zone profiles, indicate that the frequencies which prevail are favored by the resonant condition of antinodes over the bar and nodes in the trough. Standing waves which would have nodes over the bar are suppressed. Sediment resuspension in the surf zone appears to be largely attributable to the incident waves which are the main source of bed shear stress. In addition, the extra near-bottom eddy viscosity provided by the reformed, non-breaking waves traversing the trough significantly affects the vertical velocity profile of the longshore current. Whereas the bar is highly mobile in terms of onshore—offshore migration rates, the beach face and inner regions of the trough are remarkably stable over time.