Oil source analysis of Upper Tertiary Shawan Formation in Chepaizi area,in the northwest margin of Junggar basin

Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.

     

Oil source analysis of Upper Tertiary Shawan Formation in Chepaizi area,in the northwest margin of Junggar basin

Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.     

金顶超大型铅锌矿床的成矿金属来源——来自铅同位素组成的制约

金顶矿床是世界著名的超大型铅锌矿床,其巨量的金属堆积引起许多学者对成矿金属来源的关注。前人通过铅同位素示踪研究,提出了成矿金属来自地幔、上地壳、下地壳及不同端员混合等不同认识。理论分析表明,这些观点认识的差异可能源于不同作者分析铅同位素数据存在测试误差。基于此,笔者在金顶矿床选择了7个代表性硫化物样品,再次进行了铅同位素分析。结果显示,矿床铅同位素组成为~(206)Pb/~(204)Pb=18.3945~18.4429、~(207)Pb/~(204)Pb=15.6412~15.6583、~(208)Pb/~(204)Pb=38.6266~38.6772,在铅同位素演化模式图解(Zartman et al.,1979)中数据点分布集中,处于"造山带"和"上地壳"演化曲线之间,未显示出明显的线性分布特点,表明金顶矿床成矿金属来源主要为壳源;区域对比表明,金顶矿床明显比白秧坪矿带铅锌矿床贫放射性成因铅,而与区域VMS型矿床铅同位素组成更为接近,这表明金顶矿床与白秧坪矿带矿床有着不同的金属物源区,其金属可能来自盆地底部晚三叠世火山岩或其内早期的VMS矿化。     

玲珑黑云母花岗岩成因:矿物学特征约束

晚侏罗世玲珑黑云母花岗岩广泛分布于胶东半岛西北部,是胶东半岛众多中生代侵入岩中出露面积最大的岩体,为区内主要赋矿围岩。有关其成岩物理化学条件、岩石成因类型和源区特征却一直存在争议。本文在系统的岩石学和岩相学研究基础上,对钾长石、斜长石、黑云母和角闪石等主要造岩矿物进行了成分分析,以期厘定成岩物理化学条件,并进一步约束岩石成因。研究结果表明:钾长石K_2O含量为14.17%~15.85%,平均15.14%,Na_2O含量为0.62%~1.50%,平均1.04%,属于正长石(Or=86.51~94.35);斜长石Na_2O含量为8.41%~10.02%,平均9.11%,CaO含量为3.05%~4.54%,平均3.99%,属于更长石(Ab=74.97~84.56);黑云母相对富铁(FeO为18.49%~21.64%,平均20.13%)、贫镁(Mg O为8.06%~10.89%,平均9.50%),为镁铁黑云母或富铁黑云母;角闪石富铁(FeO为21.24%~22.24%,平均21.68%)、贫镁(Mg O为5.75%~6.57%,平均6.11%),均为含铁韭闪石质普通角闪石。花岗岩不同温压条件下的水逸度图解显示岩体形成压力为2.7~3.2kbar,深度为10~12km;锆石饱和温度计(综合前人数据计算得到)、角闪石-斜长石温度计和二长石温度计结果分别表明岩浆侵位温度为728~795℃,结晶温度为614~682℃,最后在531~565℃温度下固结成岩;黑云母和角闪石成分表明岩体形成时氧逸度较低,为-21.67~-16.73。黑云母化学成分Mg O与Al_2O_3呈现负相关性,说明其结晶过程中可能发生了Mg~(2+)和Al~(3+)的置换反应,结合黑云母Mg O-FeO-Al_2O_3图解可知岩体具有钙碱性花岗岩的特征。黑云母的含铁系数、MF值、AlⅥ值和较低的氧逸度指示玲珑黑云母花岗岩为S型花岗岩。黑云母具有由核部到边部FeO、Mg O和K_2O含量均一的特征,结合黑云母FeO/(FeO+Mg O)-Mg O图解、黑云母MF值以及角闪石Mg#值说明岩石物质来源为壳源。玲珑黑云母花岗岩中斜长石和黑云母的种属,岩体内大量太古宙继承锆石和产出方向与区域胶东群一致的胶东群残留体进一步说明其可能是胶东群部分熔融的产物,形成过程中没有明显幔源物质的参与。