The Signs and the Role of Structures of Subsurface Flow in Permafrost Zone

Water Resources - The subsurface runoff in the permafrost zone shows considerable structural and seasonal specifics. The structural features are due, on the one hand, to the lithologically...     

Crystal chemistry of selenates with mineral-like structures: VIII. Butlerite chains in the structure of K(UO<Subscript>2</Subscript>)(SeO<Subscript>4</Subscript>)(OH)(H<Subscript>2</Subscript>O)

A new potassium uranyl selenate compound K(UO₂)(SeO₄)(OH)(H₂O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P2₁/c,a = 8.0413(9) Å, b = 8.0362(9) Å, c = 11.6032(14) Å, β = 106.925(2)°, V = 717.34(14) ų) and refined to R ₁ = 0.0319 (wR ₂ = 0.0824) for 1285 reflections with |F ₀| > 4σ _F . The structure consists of [(UO₂(SeO₄)(OH)(H₂O)]^? chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO₄]^2?. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds.     

The Organic Component of Particulate Matter in Small Streams of the Northern Yenisei Region During the Summer-Autumn Period

A quantitative assessment is made of suspended sediment load, including particulate organic matter and organic carbon, in 2014 for the small streams of the Northern Yenisei region, in the taiga–tundra transition zone (near the city of Igarka, Krasnoyarsk krai). It was found that the suspended sediment concentration (SSC) of the streams under investigation fluctuated between 2 and 18 mg/L during the summer–autumn low-water period of 2014. The proportion of dissolved organic matter (DOM) in the total sediment yield varied from 16.4% to 74.1%, depending on landscape-geomorphological conditions for suspended sediment formation: it is higher for streams with tundra catchments and lower on forest watersheds underlain by sandy and clayey loams. The DOM content varies from catchment to catchment from 1.63 to 2.42 mg/L, and the mean concentration of dissolved organic carbon (DOC) is estimated at 0.73 to 1.09 mg C/L. It is shown that the local channel transformations serve as the main source of POM and DOC input to the water of two out of three streams under study. Surface runoff or fast subsurface flow in the organic soil horizon is the external source of DOM input to the water of the third stream during flooding. Regional empirical dependencies were obtained, which correlate the water discharge, total SSC and the proportion of DOM are obtained. The long-term proportion of DOM in the annual suspended sediment flow of the Graviika river makes up 25% and DOC, 11%, or, in absolute values, 406 and 183 t/year, and in units of layer 1.26 and 0.57 t/km², respectively.     

Estimation of the annual discharge of suspended matter by the rivers of North Siberia and the Far East

New estimates of the suspended sediment fluxes from the medium and large rivers of Siberia and the Russian Far East are presented on the basis of the calculations over the period of the instrumental surveys. The method of calculations accounting for the intra-annual discharge variability is considered and its hydrogeological substantiation is given. The obtained estimates are compared with the results of previous studies. The role of the geological evolution and glaciation history concerning the contemporary suspended sediment fluxes is shown. The prevalence of the valley (coastal and slope) generation of the suspended flux over the watershed generation on the territory of the Russian drainage basin is assumed.     

Applying regression analysis to calculating suspended sediment runoff: Specific features of the method

Major theoretical prerequisites for the application of regression analysis are considered as applied to calculating suspended sediment given observational data on water discharge and sediment load in rivers. A concept of sediment transport curve as a calculation model based on regression analysis is introduced. The role of the probabilistic structure of raw data in the determination of the optimal form of sediment transport curve and the potential structure of errors of regression models is discussed. The most widely used theoretical models of curves, as well as the methods and algorithms for assessing regression coefficients are analyzed. The application limits and the accuracy of the method are derived from its stochastic nature, and the most common methodological mistakes in its use are discussed.     

Hysteresis effect in the seasonal variations in the relationship between water discharge and suspended load in rivers of permafrost zone in Siberia and Far East

Regularities in the manifestation of hysteresis effect in the relationship between water discharge and suspended load in rivers in the permafrost zone of Siberia and Far East are studied for individual phases of water regime. The existing typifications of hysteresis curves, the formation mechanisms of suspended load peaks in permafrost zone rivers are considered. Data of regime observations are used to determine the predominant types of hysteresis curves discharge-sediment load for 27 gages on 16 large rivers in the region. The role of permafrost conditions and processes in the formation of the hysteresis effect is identified and a relationship between the type of the hysteresis curve and the predominant sediment source is established.     

Evaluating the annual runoff of traction load on the rivers in the north of Siberia and the Far East

For determining the water regime characteristics we suggest a modification of the technique which is based on taking into consideration the parameters of alluvium ridge movement and which has been used in evaluating the annual runoff of traction load on the rivers in the north of Siberia and in the north-east of Russia. The intrazonal character of the runoff of traction load is substantiated. We examine the role of geological and hydroclimatic conditions and ascertain a correlation between the flow rate of traction load and water flow rates.     

Hydrochemical Conditions at the Lena River in August 2018

Oceanology - The information is presented on hydrochemical studies performed in August 2018 at the middle and lower reaches of the Lena River from Yakutsk to Kyusyur settlements. The studies...     

An extreme flood caused by a heavy snowfall over the Indigirka River basin in Northeastern Siberia

Flooding is one of the greatest disasters that produces strong effects on the ecosystem and livelihoods of the local population. Flood frequency is expected to increase globally making its risk assessment an urgent issue. In spring-summer 2017, an extreme flooding occurred in the Indigirka River lowland of Northeastern Siberia that inundated a large area. In this study, the extent and climatic drivers of the flooding were determined using the results of field observations, satellite images, and climate reanalysis dataset, and its possible effects on the ecosystem were discussed. In 2017, a significant lowland area of around 16,016 km² was covered with water even in July, which was 5,217 km² (around 4% of the total area) greater than the water-covered area in 2015 when usual hydrological condition in the area was observed. The hydrographic signature obtained for the Indigirka River water level in 2017 was unusual. Although the water level rose sharply at the end of May (which was typical for the Arctic region), it did not fall afterwards and even increased again to an annual daily maximum value in the middle of July. The climate reanalysis dataset obtained for the temporal–spatial variations of snow water equivalent, snowmelt, and runoff over the lowland revealed that a large amount of snowmelt runoff in June and July 2017 produced a large water-covered area and unusually high river water levels that lasted until summer. Snow depth from winter to spring was largest in 2017 over the period from 2009 to 2017, and the surface of the lower reach of the lowland was partially covered with snow even in the end of June due to the extreme snowfall that occurred in October 2016. Such unusual hydrological conditions waterlogged most trees over the lowland, which caused serious ecosystem devastation and changes in the material cycle.