Microboudin structures of piemontite along the Sambagawa metamorphic belt, Japan: implications for lateral variation of differential stress during regional metamorphism

Evidence is presented of a lateral variation in differential stress during metamorphism along a regional metamorphic belt on the basis of the proportion of microboudinaged piemontite grains (p) in a quartz matrix in metacherts. It is proposed that p is a practical indicator of relative differential stress. Analysis of 123 metacherts from the 800 km long Sambagawa metamorphic belt, Japan, reveals that p‐values range from < 0.01 to 0.7 in this region. Most samples from Wakayama in the mid‐belt area have p‐values of 0.4–0.6, whereas those from western Shikoku have p‐values of < 0.1. This difference cannot be explained by variations in metamorphic temperature, and is instead attributed to a regional, lateral variation in differential stress during metamorphism.     

Standing stocks and production rates of phytoplankton and planktonic copepods in the Inland Sea of Japan

Standing stocks and production rates of phytoplankton and planktonic copepods were investigated at 15 stations in the Inland Sea of Japan during four cruises in October–November 1979, January, April and June 1980. The overall mean of phytoplankton biomass was relatively constant during the study period, ranging from 2.3 mg chl.a m^–3 in April to 3.6 mg chl.a m^–3 in October–November. Primary production was low in January (mean: 90 mg C m^–2 d^–1), but higher than 375 mg C m^–2 d^–1 on the other occasions. Integrated annual primary production was 122 g C m^–2 yr^–1. In terms of carbon weight,Paracalanus parvus was the most important copepod species. The variation of the mean copepod biomass (range: 7.6 mg C m^–3 in April to 20.2 mg C m^–3 in June) was smaller than that of copepod production, which was estimated by the Ikeda-Motoda's physiological method. Copepod producion was low in cold seasons (0.6 and 0.9 mg C m^–3 d^–1 in January and April, respectively), and increased, following the elevation of primary production, to 4.9 mg C m^–3 d^–1 in June. Annual copepod production was 33.7 g C m^–2 yr^–1, of which herbivore (secondary) production was 26.4 g C m^–2 yr^–1 (21.7% of primary production). The ratios of pelagic planktivorous fish catch and total fish catch to the primary production were 0.82 and 1.8%, respectively, indicating very high efficiency in exploiting fishery resources in the Inland Sea of Japan.     

Anelastic structure of the upper mantle beneath the northern Philippine Sea

We investigated the upper mantle anelastic structure beneath the northern Philippine Sea region, including the Izu-Bonin subduction zone and the Shikoku Basin. We used regional waveform data from 69 events in the Pacific and the Philippine Sea slabs, recorded on F-net and J-array network broadband stations in western Japan. Using the S–P phase pair method, we obtained differential attenuation factors, δt^*, which represent the relative whole path Q. We conducted a tomographic inversion using 978 δt^* values to invert for a fine-scale (50–100 km) three-dimensional anelastic structure.

The results shows two high-Q regions (Q_P>1000) which are consistent with the locations of the Pacific and the Philippine Sea slabs. Also there is a low-Q (Q_P110) area extending to the deeper parts (350–400 km) of the model just beneath the old spreading center and the Kinan Seamount Chain in the Shikoku Basin. A small depth dependence of the laterally averaged Q_P was found, with values of 266 (0–250 km), 301 (250–400 km), and 413 (400–500 km).     

Hydrogen sites in the dense hydrous magnesian silicate phase E: a pulsed neutron powder diffraction study

Hydrogen site positions and occupancy in the crystal structure of dense hydrous magnesium silicate (DHMS) phase E were determined for the first time by pulsed neutron powder diffraction. A fully deuterated pure phase E powder sample, which had space group \(R\overline{3} m\) and lattice parameters of a = 2.97065(8) Å and c = 13.9033(4) Å, was synthesized at 15 GPa and 1100 °C. Through quantitative evaluation of refined structure parameters obtained with sufficient spatial resolution and very high signal-to-background ratio, we conclude that the O–D dipoles in the refined phase E structure are tilted by 24° from the direction normal to the layers of edge-shared MgO₆ octahedra (octahedral layers). The tilted dipole structure of phase E is in remarkable contrast to that of brucite, Mg(OH)₂, which has dipoles exactly normal to the octahedral layer. This contrast exists because the O–Si–O bonding unique in the phase E structure connects two adjacent octahedral layers and thereby reduces the interlayer O···O distance. This shrinkage of the interlayer distance induces the tilting of the O–D dipole and also generates unique O–D···O hydrogen bonding connecting all the layers in the phase E structure.     

Detecting red tides in the eastern Seto inland sea with satellite ocean color imagery

A multi-spectral classification scheme is proposed to identify water with red tide(s) using satellite ocean color imagery obtained by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The study area was the eastern Seto Inland Sea in Japan, where serious red tides frequently occur. “Background Ocean Colors” (BOCs hereafter), or colors of water around a red tide or those of the water before/after a red tide, are calculated as the monthly climatological average of normalized water-leaving radiances (nLw) with 0.01 degree spatial resolution with SeaWiFS imagery. Criteria for detecting red-tide pixels are established from analyses of characteristics of the nLws (in the 443, 490, 510, and 555 nm bands) anomalies from BOCs and the nLw spectra together with the red-tide records in Osaka Bay. The proposed scheme can efficiently indicate the presence or absence of red tides for independent match-ups with 83% accuracy. Additional validations of specific events indicate that the algorithm performed well in the study area. These results suggest that the scheme is appropriate to detect red tides in the optically complex coastal water of the eastern Seto Inland Sea.     

Paleomagnetic stratigraphy and biostratigraphy of the Plio-Pleistocene in the Kinki district, Japan

The magnetostratigraphic subdivision of the Plio-Pleistocene series in the Kinki district around Osaka in southwest Japan, based on NRM measurements of volcanic ash beds, is correlated with biostratigraphic and paleoclimatic marker beds as well as past sea level oscillations. At least 10 high sea level stands occurred in the study area between about 1.5 and 0.27 million years ago, all associated with relative warming. A significant change in the composition of flora, from Metasequoia to Fagus dominated assemblages, was observed around the Jaramillo event.     

Estimation of property loss and business interruption loss caused by storm surge inundation due to climate change: a case of Typhoon Vera revisit

This paper estimates property loss and business interruption loss under scenarios of storm surge inundation to explore the economic impact of climate change on Ise Bay, Japan. Scenarios-based analyses are conducted with respect to Typhoon Vera, which caused the most severe storm surge in the recorded history of Japan in 1959. Four different hazard scenarios are chosen from a series of typhoon storm surge inundation simulations: Typhoon Vera’s landfall with respect to the condition of the past seawall; Typhoon Vera’s landfall with respect to the condition of the current seawall; intensifying Typhoon Vera, but retaining its original tracks; and intensifying Typhoon Vera, but choosing the worst tracks from various possible typhoon tracks. Our economic loss estimation takes advantage of fine geographical scale census and economic census data that enable us to understand the spatial distribution of property loss and business interruption loss as well as identify the most potentially affected areas and business sectors on a sub-city scale. By comparing the property loss and business interruption loss caused by different hazard scenarios, the effect of different seawalls is evaluated and the economic impact of future climate change is estimated. The results indicate that although the current seawall can considerably reduce the scale of losses, climate change can cause Ise Bay to experience more serious storm surge inundation. Moreover, the resulting economic losses would increase significantly owing to a combination of climate change and the worst track scenario. It is, therefore, necessary to consider more countermeasures to adapt to climate change in this area.

     

Crustal structure beneath Aso Caldera,Southwest Japan,as derived from receiver function analysis

Aso Volcano experienced a huge pyroclastic eruption 90 thousand years ago, and formed a large caldera (18 km × 25 km). In order to test the hypothesis of a magma body in the mid and lower crust that has been suggested geophysically and geochemically, we investigated seismic velocity discontinuities and velocity structure beneath Aso Caldera using receiver functions and a genetic algorithm inversion. We confirm the existence of the Moho at depths between 30 km and 35 km and a large velocity anomaly should exist in the deep portion of the crust beneath Aso Caldera, from imaging of receiver functions observed only at stations outside the caldera. As a result of a more detailed examination with GA inversion, a low velocity layer is detected at depths between 10 km and 24 km beneath the western part of the caldera. S-wave velocity of the layer is estimated to be 2.0–2.4 km/s. We estimate that the low velocity layer contains at most 15% melt or 30% aqueous fluid. The layer exists near the Conrad and at the same depths as the swarm of the low frequency earthquakes and a compressional and dilatational deformation source which are expected to be caused by fluid movement beneath the middle-eastern part of the caldera. Fluid contained in the layer might be related with huge pyroclastic eruptions of Aso Volcano.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

Local structure of (Ca, Sr)2 (Mg, Co, Zn) Si2O7 melilite solid-solution with modulated structure

The local structure around Co, Zn and Sr atoms in incommensurately modulated, melilite-type X₂T¹ T ₂ ² O₇ (X=Ca and Sr, T¹=Mg, Co and Zn, T²=Si) solid-solutions has been investigated by EXAFS analyses. The modulated structure was confirmed in Ca_2-xSr_xCoSi₂O₇ solid-solutions with X=0.0 to 0.6 and for both Ca₂Mg_1-YCo_YSi₂O₇ and Ca₂Mg_1-YZn_YSi₂O₇ solid-solutions over the whole compositional range at room temperature. The actual bond-distances determined by the EXAFS method for the T¹ site (Co-, Zn-O) in the modulated structure are longer than the mean bond-distances obtained from the X-ray diffraction method. This is attributable to the libration of the T¹ tetrahedra. In the Ca_1-XSr_XCoSi₂O₇ solid-solution both the Sr-O and Co-O distances by the EXAFS method for the X-site increase from Ca end-member to Sr end-member. These increases are respectively 0.8% and 0.6%. This means the local expansions of the tetrahedral sheets and of the XO polyhedra are well matched. In the modulated Ca₂Co_1-YMg_YSi₂O₇ and Ca₂Zn_1-YMg_YSi₂O₇ solid-solutions, the actual Co-O and Zn-O distances for the T¹-sites are nearly constant in the whole compositional range. The compositional variations of the local structure around the cations in the solid-solution are different for the X and T¹ sites. It is concluded that the local geometric restriction for the size of substituted cation in X site is larger than that in T¹ site. The dimension of the tetrahedral sheet puts restriction on the size of the cations situated at the interlayer X sites. In other words, the different behavior of the local geometric restriction between the X and T¹ sites is an important feature of the melilite structure and is also related to the modulated structure.