Metamorphic evolution of lawsonite eclogites from the southern Motagua fault zone,Guatemala: insights from phase equilibria and Raman spectroscopy

Lawsonite eclogite (metabasalt and metadolerite) and associated metasedimentary rocks in a serpentinite mélange from an area just south of the Motagua fault zone (SMFZ), Guatemala, represent excellent natural records of the forearc slab–mantle interface. Pseudosection modelling of pristine lawsonite eclogite reproduces the observed predominant mineral assemblages, and garnet compositional isopleths intersect within the phase fields, yielding a prograde P–T path that evolves from 20 kbar, 470 °C (M1) to 25 kbar, 520 °C (M2). The dominant penetrative foliation within the eclogite blocks is defined by minerals developed during the prograde evolution, and the associated deformation, therefore, took place during subduction. Thermometry using Raman spectra of carbonaceous material in metasedimentary rocks associated with the SMFZ eclogites gives estimates of peak‐T of ～520 °C. Barometry using Raman spectroscopy shows unfractured quartz inclusions in garnet rims retain overpressures of up to ～10 kbar, implying these inclusions were trapped at conditions just below the quartz/coesite transition, in agreement with the results of phase equilibrium analysis. Additional growth of Ca‐rich garnet indicates initial isothermal decompression to 20 kbar (M3) followed by hydration and substantial cooling to the lawsonite–blueschist facies (M4). Further decompression of the hydrated eclogite blocks to the pumpellyite–actinolite facies (3–5 kbar, 230–250 °C) is associated with dehydration and veining (M5). The presence of eclogite as m‐ to 10 m‐sized blocks in a serpentinite matrix, lack of widespread deformation developed during exhumation and derived prograde P–T path associated with substantial dehydration of metabasites within the antigorite stability field suggest that the SMFZ eclogites represent the uppermost part of the forearc slab crust sampled by an ascending serpentinite diapir in an active, moderate‐T subduction zone.     

Geological and microbial anomalies in the extinct submarine volcano, Shiribeshi Seamount, in the eastern margin of the Japan Sea

Abstract   The manned submersible Shinkai 2000 investigated yellow patches on the near-summit slope of Shiribeshi Seamount in the Japan Sea. Yellowish patches are often associated with seepage, and the possibility of seepage at Shiribeshi Seamount was tested by the following four lines of observation: (i) high subsurface temperature was measured at a ring-like patch, although no increase in subsurface temperature was observed at other patches; (ii) high gamma ray (γ-ray) intensity from the thorium series was recorded in the patch zone; (iii) the yellowish deposit was composed of calcite, quartz and amorphous iron compound, as seen at the yellowish patches in other seeps and volcanoes; (iv) lipid phosphate, a measure of microbial abundance, in sediments of the ring-like patch was determined, and the recorded microbial abundance was higher inside the patch than outside it. The four lines of observation are explained consistently by postulating that the seepage of warm fluid contained Fe and γ-ray sources. A hydrothermal origin of the yellow patches is not ruled out for the extinct but young (0.9 Ma) arc volcano.