Sedimentologic attributes of the Proterozoic siliciclastic packages of the Garhwal–Kumaun Lesser Himalaya,India: Implication for their relationship and palaeobasinal conditions

The present work addresses the long-standing issues on the characterization aspect of the Proterozoic siliciclastic successions exposed in the central part of the Lesser Himalaya, restricted between the Main Boundary Thrust (MBT) and the Main Central Thrust (MCT). Geologic, sedimentologic, and petrographic study divides the Lesser Himalaya in two zones- northern Palaeo- Mesoproterozoic Inner Lesser Himalayan (ILH) and southern Neoproterozoic Outer Lesser Himalayan (OLH) zones. The major lithofacies recognized from the zones are - (i) coarse grained siliciclastic (CGS), (ii) interbedded medium and fine-grained siliciclastic (IMFS), (iii) argillite (ARG), and (iv) siliciclastic–argillite rhythmites (SAR). Amongst all these facies, the nearshore IMFS facies shows consistent presence in both OLH and ILH zones. From the facies distribution pattern, a northwest–southeasterly trending palaeo- shoreline has been envisaged. The CGS facies in the ILH hints towards an alluvial fan setting during 1.8 Ga rifting phase associated with penecontemporaneous basic magmatism. Compositionally, the siliciclastics of both the zones (ILH and OLH) are arenite and wacke types with minimal variation in their detrital proportions, derived from the early Proterozoic (between 2.4-1.6Ga) Aravalli-Delhi Supergroup provenance. Nearly matching types and content of detrital modes and the lithofacies pattern of the ILH and OLH siliciclastics probably conclude the derivation from the rising (nearby) Aravalli-Delhi orogen and deposition in a foreland like situation.     

Geomorphic characteristics of a bedrock river inferred from drainage quantification,longitudinal profile,knickzone identification and concavity analysis: a DEM-based study

An examination of river channels has ability to provide substantial information regarding the geomorphic characteristics, control of lithology, tectonic uplift and geomorphic evolution during the geological past of an area. In this paper, a detailed study of geomorphic and structural investigation has been carried out for Pravara basin, Maharashtra, with the help of 90-m resolution SRTM DEM and geospatial techniques. Drainage network analysis performed in this paper demonstrates the general geomorphic characteristics, while the analysis of longitudinal profile synthesises lithological control over Pravara basin. Pravara is a 6th order drainage basin, encompassing an area of 2637 km². Bifurcation ratio reveals low to moderate structural control. Due to the hard rock lithology, the drainage density and stream frequency are low, and it indicates higher permeability in the sub-surface layers. The shape parameters denote that Pravara is highly elongated and it is easier to control floods in this basin. Relief parameters show very steep slope and higher vulnerability to the slope failure in some areas. Upstream of Pravara river has shown that series of breaks and knickzones indicate active erosion and acute lithological control on the channel. Major breaks are observed only in the main channel whereas in two major tributaries, no such breaks found, instead these tributaries are characterised by several knickzones which indicate regional variation in the lithological physiognomies. Different lithological stages on knickpoint and channel incision substantiate rejuvenation of Pravara river in several phases during geological past. The geospatial methodology carried out in this study can be pragmatic elsewhere around this world to recognise the geomorphic appearances and lithological control of a drainage basin.     

Spatial–temporal variability and hydrologic connectivity of runoff generation areas in a North Alabama pasture—implications for phosphorus transport

This study delineated spatially and temporally variable runoff generation areas in the Sand Mountain region pasture of North Alabama under natural rainfall conditions, and demonstrated that hydrologic connectivity is important for generating hillslope response when infiltration‐excess (IE) runoff mechanism dominates. Data from six rainfall events (13·7–32·3 mm) on an intensively instrumented pasture hillslope (0·12 ha) were analysed. Analysis of data from surface runoff sensors, tipping bucket rain gauge and HS‐flume demonstrated spatial and temporal variability in runoff generation areas. Results showed that the maximum runoff generation area, which contributed to runoff at the outlet of the hillslope, varied between 67 and 100%. Furthermore, because IE was the main runoff generation mechanism on the hillslope, the data showed that as the rainfall intensity changed during a rainfall event, the runoff generation areas expanded or contracted. During rainfall events with high‐intensity short‐ to medium‐duration, 4–8% of total rainfall was converted to runoff at the outlet. Rainfall events with medium‐ to low‐intensity, medium‐duration were found less likely to generate runoff at the outlet. In situ soil hydraulic conductivity (k) was measured across the hillslope, which confirmed its effect on hydrologic connectivity of runoff generation areas. Combined surface runoff sensor and k‐interpolated data clearly showed that during a rainfall event, lower k areas generate runoff first, and then, depending on rainfall intensity, runoff at the outlet is generated by hydrologically connected areas. It was concluded that in IE‐runoff‐dominated areas, rainfall intensity and k can explain hydrologic response. The study demonstrated that only connected areas of low k values generate surface runoff during high‐intensity rainfall events. Identification of these areas would serve as an important foundation for controlling nonpoint source pollutant transport, especially phosphorus. The best management practices can be developed and implemented to reduce transport of phosphorus from these hydrologically connected areas. Copyright © 2009 John Wiley & Sons, Ltd.     

Cation diffusion in aluminosilicate garnets: experimental determination in pyrope-almandine diffusion couples

Diffusion couples made from homogeneous gem quality natural pyrope and almandine garnets were annealed within graphite capsules under anhydrous conditions at 22–40 kbar, 1057–1400 °C in a piston-cylinder apparatus. The concentration profiles that developed in each couple were modeled to retrieve the self diffusion coefficients [D(I)] of the divalent cations Fe, Mg, Mn and Ca. Because of their usually low concentrations and lack of sufficient compositional change across the interface of the diffusion couples, only a few reliable data can be obtained for D(Ca) and D(Mn) from these experiments. However, nine sets of D(Fe) and D(Mg) data were retrieved in the above P-T range, and cast in the form of Arrhenian relation, D=D ₀exp{−[Q(1 bar)+PΔV ⁺]/RT}. The values of the activation energy (Q) and activation volume (ΔV ⁺) depend on whether f _O2 is constrained by graphite in the system C-O or held constant. For the first case, we have for Fe:Q(1 bar)=65,532±10,111 cal/mol, D ₀=3.50 (±2.30)×10⁻⁵ cm²/s, ΔV ⁺=5.6(±2.9) cm³/mol, and for Mg:Q(1 bar)=60,760±8,257 cal/mol, D ₀=4.66 (±2.48)×10⁻⁵ cm²/s, ΔV ⁺=5.3(±3.0) cm³/mol. Here the ΔV ⁺ values have been taken from Chakraborty and Ganguly (1992). For the condition of constant f _O2, the Q values are ∼9 kcal lower and ΔV ⁺ values are ∼4.9 cm³/mol larger than the above values. Lower temperature extrapolation of the Arrhenian relation for D(Mg) is in good agreement with the Mg tracer diffusion data (D ^* _Mg) of Chakraborty and Rubie (1996) and Cygan and Lasaga (1985) at 1 bar, 750–900 °C, when all data are normalized to the same pressure and to f _O2 defined by graphite in the system C-O. The D ^* _Mg data of Schwandt et al. (1995), on the other hand, are lower by more than an order of magnitude than the low temperature extrapolation of the present data, when all data are normalized to the same pressure and to f _O2 defined by the graphite buffer. Comparison of the D(Fe), D(Mg) and D(Mn) data in the pyrope-almandine diffusion couple with those in the spessartine-almandine diffusion couple of Chakraborty and Ganguly (1992) shows that the self diffusion of Fe and Mn are significantly enhanced with the increase in Mn/Mg ratio; the enhancement effect on D(Mg) is, however, relatively small. Proper application of the self diffusion data to calculate interdiffusion coefficient or D matrix elements for the purpose of modeling of diffusion processes in natural garnets must take into account these compositional effects on D(I) along with the effects of thermodynamic nonideality, f _O2, and pressure. Received: 8 May 1997 / Accepted: 2 October 1997     

A numerical study on the role of atmospheric forcing on mixed layer depth variability in the Bay of Bengal using a regional ocean model

Ocean Dynamics - This study investigates the role of driving atmospheric forces [winds, net heat flux, and evaporation–precipitation (E–P)] and the possible mechanisms on the mixed...     

Compositionally zoned crystals and real-time degassing data reveal changes in magma transfer dynamics during the 2006 summit eruptive episodes of Mt. Etna

One of the major objectives of volcanology remains relating variations in surface monitoring signals to the magmatic processes at depth that cause these variations. We present a method that enables compositional and temporal information stored in zoning of minerals (olivine in this case) to be linked to observations of real-time degassing data. The integrated record may reveal details of the dynamics of gradual evolution of a plumbing system during eruption. We illustrate our approach using the 2006 summit eruptive episodes of Mt. Etna. We find that the history tracked by olivine crystals, and hence, most likely the magma pathways within the shallow plumbing system of Mt. Etna, differed considerably between the July and October eruptions. The compositional and temporal record preserved in the olivine zoning patterns reveal two mafic recharge events within months of each other (June and September 2006), and each of these magma supplies may have triggered the initiation of different eruptive cycles (July 14–24 and August 31–December 14). Correlation of these observations with gas monitoring data shows that the systematic rise of the CO₂/SO₂ gas values is associated with the gradual (pre- and syn-eruptive) supply of batches of gas-rich mafic magma into segments of Etna’s shallow plumbing system, where mixing with pre-existing and more evolved magma occurred.     

Petromineralogic and rock magnetic aspects of clastic sedimentation in the Surma basin, Mizoram

We present here comprehensive petromineralogic, mineral magnetic and lithologic observations from five stratigraphic sections representing the Barail Group, Middle and Upper units of Bhuban Formation, Bokabil Formation and Tipam Group in the Mizoram area. These stratigraphic units mainly display interplay of the grey and buff colored sandstones of the clast compositions varying from sub-lithic to lithic arenites (Q₇₉F₄L₁₇ to Q₅₅F₃L₄₂) including sedimentary, meta-sedimentary and subordinate igneous rock fragments. The buff sandstones with higher lithic fragments [Q₆₉F₄L₂₇ (Ls₆₁Lm₃₈Lv₁)] are dominated by recycled components with higher clast angularity (VA₁A₁₅SA₅₁SR₂₄R₈WR_0.4) relative to the grey sandstones. Mineral magnetic studies decipher bimodal (ferri- and antiferromagnetic) mineralogy with higher concentration in buff sandstones relative to the unimodal ferrimagnetic nature of the grey sandstones. The study infers that the buff sandstones mark the regressive phases driven by hinterland uplifts; whereas the growth of the grey sandstone facies is marked by transgressive basinal processes. Gradual increase in the frequency and appearance of the buff sandstones in the Surma stratigraphy, therefore, can be related to the evolution of the Indo-Burmese ranges.     

The time scales of magma mixing and mingling involving primitive melts and melt–mush interaction at mid-ocean ridges

We have studied the chemical zoning of plagioclase phenocrysts from the slow-spreading Mid-Atlantic Ridge and the intermediate-spreading rate Costa Rica Rift to obtain the time scales of magmatic processes beneath these ridges. The anorthite content, Mg, and Sr in plagioclase phenocrysts from the Mid-Atlantic Ridge can be interpreted as recording initial crystallisation from a primitive magma (~11 wt% MgO) in an open system. This was followed by crystal accumulation in a mush zone and later entrainment of crystals into the erupted magma. The initial magma crystallised plagioclase more anorthitic than those in equilibrium with any erupted basalt. Evidence that the crystals accumulated in a mush zone comes from both: (1) plagioclase rims that were in equilibrium with a Sr-poor melt requiring extreme differentiation; and (2) different crystals found in the same thin section having different histories. Diffusion modelling shows that crystal residence times in the mush were <140 years, whereas the interval between mush disaggregation and eruption was ≤1.5 years. Zoning of anorthite content and Mg in plagioclase phenocrysts from the Costa Rica Rift show that they partially or completely equilibrated with a MgO-rich melt (>11 wt%). Partial equilibration in some crystals can be modelled as starting <1 year prior to eruption but for others longer times are required for complete equilibration. This variety of times is most readily explained if the mixing occurred in a mush zone. None of the plagioclase phenocrysts from the Costa Rica Rift that we studied have Mg contents in equilibrium with their host basalt even at their rims, requiring mixing into a much more evolved magma within days of eruption. In combination these observations suggest that at both intermediate- and slow-spreading ridges: (1) the chemical environment to which crystals are exposed changes on annual to decadal time scales; (2) plagioclase crystals record the existence of melts unlike those erupted; and (3) disaggregation of crystal mush zones appears to precede eruption, providing an efficient mechanism by which evolved interstitial melt can be mixed into erupted basalts.     

Mg tracer diffusion in synthetic forsterite and San Carlos olivine as a function of P,T and fO2

We present new experimental data on Mg tracer diffusion in oriented single crystals of forsterite (Fo₁₀₀) and San Carlos olivine (Fo₉₂) between 1000–1300° C. The activation energies of diffusion are found to be 400 (±60) kJ/mol (96 kcal/mol) and 275 (±25) kJ/mol (65 kcal/ mol) in forsterite and San Carlos olivine, respectively, along [001] at a fO₂ of 10^–12 bars. There is no change in activation energy of Mg tracer diffusion within this temperature range. Mg tracer diffusion in a nominally pure forsterite is found to be anisotropic (D_c > D_a > D _b) and a function of fO₂. This fO₂ dependence is different from that in olivine containing Fe as a major element, which suggests that the diffusion mechanism of Mg in forsterite is different from that in Fe-bearing olivine at least over some range of fO₂. The diffusion mechanism in nominally pure forsterites may involve impurities present below the limits of detection or alternately, Si or Fe³⁺ interstitial defects, Fe being present as impurity (ppm level) in forsterite. Pressure dependence of Mg tracer diffusivity in forsterite measured to 10 GPa in a multianvil apparatus yields an activation volume of approximately 1–3.5 cm³/ mol. It is found that presence of small amounts of hydrogen bearing species in the atmosphere during diffusion anneal (f_H2 0.2 bars, f_H20 0.24 bars) do not affect Mg tracer diffusion in forsterite within the resolution of our measurement at a total pressure of 1 bar. The observed diffusion process is shown to be extrinsic; hence extrapolation of the diffusion data to lower temperatures should not be plagued by uncertainties related to change of diffusion mechanism from intrinsic to extrinsic.     

Interannual variability and characteristics of the East India Coastal Current associated with Indian Ocean Dipole events using a high resolution regional ocean model

The characteristics and variability of the East India Coastal Current (EICC), the western boundary current in the Bay of Bengal (BoB) during the Indian Ocean Dipole (IOD) years between 2006 and 2012 have been investigated using the high-resolution Regional Ocean Modeling System (ROMS). The evolution of temperature, mixed layer depth (MLD), and seasonal basin scale circulation in the upper ocean simulated by the model agrees well with the observations. The EICC in BoB is characterized by a seasonal reversal flow: the poleward EICC during February?May and the equatorward EICC during August?December. A long-term simulation from 2006 to 2012 suggest that the circulation pattern, boundary current structure, and transport in the western BoB are completely different in positive and negative IOD years. As IOD is mainly phase-locked to the seasonal cycle with most significant influence in the Borel autumn, the equatorward EICC is affected during the IOD years. It is found that the strength of this EICC is ~?5 Sv in October 2010 and a weaker EICC dominated by the presence of eddies is observed in October 2006. We also quantified the local and remote forcing effects on the variability of EICC and found that the seasonal coastal Kelvin waves (KWs) play a dominant role in the development of the EICC. During positive IOD year 2006, due the absence of second downwelling KW, the EICC is completely disorganized and dominated by the eddies, whereas in the negative IOD year 2010, the strong second downwelling KW plays a key role in developing organized and stable EICC in the western BoB.