Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Small-scale mantle flows and induced lithospheric stress near island arcs

Summary. This paper explores the middle ground between complex thermally-coupled viscous flow models and simple corner flow models of island arc environments. The calculation retains the density-driven nature of convection and relaxes the geometrical constraints of corner flow, yet still provides semianalytical solutions for velocity and stress. A novel aspect of the procedure is its allowance for a coupled elastic lithosphere on top of a Newtonian viscous mantle. Initially, simple box-like density drivers illustrate how vertical and horizontal forces are transmitted through the mantle and how the lithosphere responds by trench formation. The flexural strength of the lithosphere spatially broadens the surface topography and gravity anomalies relative to the functional form of the vertical flow stresses applied to the plate base. I find that drivers in the form of inclined subducting slabs cannot induce self-driven parallel flow; however, the necessary flow can be provided by supplying a basal drag of 1–5 MPa to the mantle from the oceanic lithosphere. These basal drag forces create regional lithospheric stress and they should be quantifiable through seismic observations of the neutral surface. The existence of a shallow elevated phase transition is suggested in two slab models of 300 km length where a maximum excess density of 0.2 g cm⁻³ was needed to generate an acceptable mantle flow. A North New Hebrides subduction model which satisfies flow requirements and reproduces general features of topography and gravity contains a high shear stress zone (75 MPa) around the upper slab surface to a depth of 150 km and a deviatoric tensional stress in the back arc to a depth of 70 km. The lithospheric stress state of this model suggests that slab detachment is possible through whole plate fracture.     

Spinor: Visible and Infrared Spectro-Polarimetry at the National Solar Observatory

The Spectro-Polarimeter for Infrared and Optical Regions (SPINOR) is a new spectro-polarimeter that will serve as a facility instrument for the Dunn Solar Telescope at the National Solar Observatory. This instrument is capable of achromatic polarimetry over a very broad range of wavelengths, from 430 to 1600 nm, allowing for the simultaneous observation of several visible and infrared spectral regions with full Stokes polarimetry. Another key feature of the design is its flexibility to observe virtually any combination of spectral lines, limited only by practical considerations (e.g., the number of detectors available, space on the optical bench, etc.). Visiting Astronomers, National Solar Observatory, operated by the Association of Universities for Research in Astronomy, Inc. (AURA), under cooperative agreement with the National Science Foundation.     

Radar observations of Itokawa in 2004 and improved shape estimation

Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object.     

Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

The Atacama Cosmology Telescope

The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys.     

Carbon biogeochemistry of the Betsiboka estuary (north-western Madagascar)

Madagascar’s largest estuary (Betsiboka) was sampled along the salinity gradient during the dry season to document the distribution and sources of particulate and dissolved organic carbon (POC, DOC) as well as dissolved inorganic carbon (DIC). The Betsiboka was characterized by a relatively high suspended matter load, and in line with this, low DOC/POC ratios (0.4–2.5). The partial pressure of CO₂ (pCO₂) was generally above atmospheric equilibrium (270–1530 ppm), but relatively low in comparison to other tropical and subtropical estuaries, resulting in low average CO₂ emission to the atmosphere (9.1 ± 14.2 mmol m⁻² d⁻¹). Despite the fact that C4 vegetation is reported to cover >80% of the catchment area, stable isotope data on DOC and POC suggest that C4 derived material comprises only 30% of both pools in the freshwater zone, increasing to 60–70% and 50–60%, respectively, in the oligohaline zone due to additional lateral inputs. Sediments from intertidal mangroves in the estuary showed low organic carbon concentrations (<1%) and δ¹³C values (average −19.8‰) consistent with important inputs of riverine imported C4 material. This contribution was reflected in δ¹³C signatures of bacterial phospholipid derived fatty acids (i + a15:0), suggesting the potential importance of terrestrial organic matter sources for mineralization and secondary production in coastal ecosystems.