Geochemical and structural evolution of micas in the Rožná and Dobrá Voda pegmatites,Czech Republic

Summary The chemistry, structural parameters, polytypism, optical properties and Rb-Sr isotopes were examined in 11 to 60 samples of biotite, muscovite and lepidolite from the pegmatites at Roná (the type locality of lepidolite; 323 ± 4Ma) and Dobrá Voda (306 ± 9Ma) in western Moravia. At both localities, early endocontact biotite is followed inwards by muscovite and lepidolite, which is concentrated in and around the core. At Roná, a 1M lepidolite follows after 2M₁ muscovite but all later generations of lepidolite are 2M₂, close to Tri₅₀ Ply₅₀ and in part associated with muscovite 2M₁. At Dobrá Voda, all lepidolite types are 1M and free of muscovite, and the late varieties approximate Tri₃₀ Ply₇₀. At both localities, a trend of increasing HF is indicated during the progress of mica crystallization, culminating in precipitation of topaz. Polytypism of lepidolite is not correlatable with any compositional or growth feature, or their combination. Throughout the mica crystallization, Rb/Cs decreases but K/Rb becomes reversed after an initial decrease. Boron is partitioned preferentially into muscovite (up to 1.10 wt.% B₂O₃) but Be, Zn, Mn and Sc are enhanced in lepidolite. A slight increase in Fe, Ba and Cl in the last generation of lepidolite might be possibly due to mixing of residual pegmatite fluids with metamorphic pore solutions.

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Geochemische und strukturelle Entwicklung der Glimmer in den Pegmatiten von Roná und Dobrá Voda, Tschechische Republik

Zusammenfassung In 11 bis 60 Proben von Biotit, Muskovit und Lepidolith aus den Pegmatiten von Roná (Typlokalität des Lepidoliths; 323 ± 9 Ma) in Westmähren wurden Chemie, Struktur-parameter, Polytypie, optische Eigenschaften und Rb-Sr-Isotopie untersucht. An beiden Lokalitäten wird früher Biotit an Endokontakten nach Innen von Muskovit und Lepidolith gefolgt, letzterer ist in und um den Kern konzentriert. In Roná folgt 1M-Lepidolith auf 2M₁-Muskovit, aber alle späteren Lepidolithgenerationen sind 2M₂, nahe Tri₅₀Ply₅₀ und zum Teil mit 2M₁-Muskovit vergesellschaftet. In Dobrá Voda sind alle Lepidolithe vom Typ 1M und frei von Muskovit, die späten Varietäten kommen Tri₅₀Ply₅₀ nahe. An beiden Lokalitäten ist während des Fortschreitens der Glimmerkristallisation eine Tendenz von steigendem HF angezeigt, die in der Ausfällung von Topas ihren Höhepunkt findet. Die Polytypie des Lepidoliths kann nicht mit irgendeiner Eigenheit der Zusammensetzung oder des Wachstums korreliert worden, auch nicht mit einer Kombination von diesen. Während der ganzen Glimmerkristallisation nimmt Rb/Cs ab, aber die Tendenz von K/Rb ändert sich nach anfänglichem Abfall. Das Bor verteilt sich bevorzugt auf den Muskovit (bis zu 1.10 Gew. -% B₂O₃), aber die Be-, Zn-, Mn- und Sc-Gehalte sind im Lepidolith erhöht. Ein leichter Ansteig von Fe, Ba und Cl in der letzten Lepidolithgeneration könnte vielleicht durch eine Mischung von pegmatitischen Restlösungen mit metamorphen Porenlösungen verursacht sein.

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With 9 Figures     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

A simulation model of morphological,vegetation and sediment changes in ephemeral streams

A model to simulate channel changes in ephemeral river channels and to test the effects of hydrological changes due to climate change and[sol ]or land use change was developed under the auspices of the EU funded MEDALUS programme (Mediterranean Desertification and Land Use). The model, CHANGISM (Channel Change GIS Simulation Model), is designed to simulate the effect of channel flow events and of climate conditions on morphology, sediment and vegetation, through sequences of events and conditions, over periods of up to several decades. The modelling is based on cellular automata but with calculations for water and sediment continuity. Process rules have both deterministic and stochastic elements. An important feature of the model is that it incorporates feedback elements between each event. The main aim of the model is to indicate the likely outcomes of events and combinations of conditions. It is linked to GIS for both input and output. The modelling is based on a channel reach and state is input as GIS layers of morphology (DEM), sediment and vegetation cover and state. Other initial conditions of soil moisture, groundwater level, and overall gradient are input. Parameters for processes are read from tables and can be easily changed for successive runs of the model. The bases for decisions on process specifications are discussed in this paper. Initial tests of the operation and sensitivity of the model were made on idealized reaches. The model was then tested using data from monitored sites in SE Spain. Simulations using clearwater flow worked well but initial simulations using events with sediment loads showed some tendency for excess deposition. Further tests and modifications are taking place. Overall, the model is one of the most sophisticated that simulates the interaction of flows with sediment and vegetation and the outcomes in terms of erosion, deposition, morphology, sediment cover, vegetation cover and plant survival over periods of up to 30 years for the scale of a channel reach. Copyright © 2005 John Wiley & Sons, Ltd.     

Stratigraphy of Pleistocene glaciations in the St Elias Mountains,southwest Yukon,Canada

At least five Middle to Late Pleistocene advances of the northern Cordilleran Ice Sheet are preserved at Silver Creek, on the northeastern edge of the St Elias Mountains in southwest Yukon, Canada. Silver Creek is located 100 km up‐ice of the Marine Isotope Stage (MIS) 2 McConnell glacial limit of the St Elias lobe. This site contains ~3 km of nearly continuous lateral exposure of glacial and non‐glacial sediments, including multiple tills separated by thick gravel, loess and tilted lake beds. Infrared‐stimulated luminescence (IRSL) and AMS radiocarbon dating constrain the glacial deposits to MIS 2, 4, either MIS 6 or mid‐MIS 7, and two older Middle Pleistocene advances. This chronology and the tilt of the lake beds suggest Pleistocene uplift rates of up to 1.9 mm a^?1 along the Denali Fault since MIS 7. The non‐glacial sediment consists of sand, gravel, loess and organic beds from MIS 7, MIS 3 and the early Holocene. The MIS 3 deposits date to between 30–36 ¹⁴C ka BP, making Silver Creek one of the few well‐constrained MIS 3‐aged sites in Yukon. This confirms that ice receded close to modern limits in MIS 3. Pollen and macrofossil analyses show that a meadow‐tundra to steppe‐tundra mosaic with abundant herbs and forbs and few shrubs or trees, dominated the environment at this time. The stratigraphy at Silver Creek provides a palaeoclimatic record since at least MIS 8 and comprises the oldest direct record of Pleistocene glaciation in southwest Yukon.     

Reconstruction of Holocene paleohydrological and sedimentological characteristics of Umm Ar-Rimam basin (northern Kuwait)

The paleohydrological and sedimentological characteristics of a playa lake in northern Kuwait (Arabian Gulf) are reconstructed using sedimentological, geochemical, and isotopic techniques. The sequence consists of up to 8 cycles of S-poor, alluvial sediments capped by a thin organic soil interbedded with gravity-fall calcrete sediments. The succession is locally derived from mainly Quaternary sediments and is regressive with upsection filling of the subsiding basin by cycles of sheetwash flow in response to climatic change. There is no natural, open-water lake water as indicated by low total organic carbon (TOC) data, but the presence of incised calcrete yardangs suggests that more extensive open-water conditions were operative in the past. Stable isotope (δ¹⁸O‰ and δ¹³C‰) values of the authigenic carbonates indicate the following three distinct processes: evaporation, meteoric fluid infiltration, and rapid per-descensum flow (rapid downward movement of water and playa sediment through pipes) through a porous, clastic sequence. Because evaporites are scarce, other factors besides evaporation action control chemical and isotopic compositions of the per-decensum lake fluids. Consequently, the isotopic composition cannot be interpreted exclusively as an indicator of salinity or evaporation ratio. The degassing of CO₂ during groundwater discharge may explain the enriched carbon isotope values for the authigenic carbonates precipitated in the sediments. Hydrologically closed lake water bodies tend to show low negative carbonate oxygen and carbon isotopic signatures. Isotopically negative δ¹³C values imply a strong input of soil-zone carbon to the groundwater of the top 60 cm of the sediment. Lakes that are hydrologically closed and evaporate or equilibrate with atmospheric CO₂ will tend to have low negative δ¹⁸O and δ¹³C values in the carbonates as reported by Talbot (Chem Geol: Isotope Geosci Sect 80(4):261–279, 1990). Biologically active lakes will tend toward lower δ¹³C of dissolved carbon due to the photosynthetic effects of ¹²C withdrawal as reported by Dunagan and Driese (J Sed Res 69:772–783, 1999). Increased biological activity during sedimentation may account for low carbon isotope values where plants were abundant, but in shrinkage-dominated systems (those of clay-rich soil subjecting to wet-dry conditions), carbon isotopes will be largely inherited from the calcretic limestones in the land extending landward of the coast and not influenced by coastal processes (known as hinterland), such as Umm Ar-Rimam depression. This basin does not fit the classic shallow playa-type basins of the Arabian Peninsula but rather the recharge playas of the southwestern USA.     

Mid-late Holocene anthropogenic and natural variations in geochemistry and sedimentation in the Yazoo Basin: Clark Lake,Sharkey County,Mississippi

A 4000-yr history at Clark Lake reveals natural variations in sediment geochemistry and nutrient levels and anthropogenic influence on twentieth century sedimentation rates. Sediment texture and ridge and swale topography indicate that the channel system creating Clark Lake is now occupied by the Yazoo River. Between 1.24 and 0.60 m (2522–865 cal yr BP), total carbon percentages and the C/N ratio average 42% and 17, respectively. The base of the 1650-yr interval and onset of high organic activity in the lake coincides with the abandonment of the Yazoo Meander Belt. The top of the interval is marked by a drop in C/N ratio to 11 and a geochemical transition zone. No change in the rate of sediment accumulation or clay mineralogy was observed despite increased cumulative percentages of Al, Fe, K, Mg, Mn, Ca, and Na. The decrease in organic activity at 865 cal yr BP is attributed to unfavorable growth conditions related to the entrenchment of the Yazoo River and changes in the hydroperiod of the area. Significant floodplain alteration was completed in 1978, but the only major effect was increased sedimentation in the late twentieth century due to the completion of the Whittington Auxiliary Channel.     

World oil: Hotelling depletion or accelerating use?

In theoretical Hotelling-type models of resource depletion, oil use declines monotonically over time to depletion. However, world oil use has been increasing for several years. Can theory and reality be reconciled? The answer is affirmative, if theory is modified to accommodate outward-shifting demand functions that are rising in response to growth in world population and income. Under this assumption, a Hotelling depletion model projects a 50-year period of increasing world oil use before the decline to exhaustion. This holds for both competitive and monopolistic regimes. Hotelling theory has been criticized by Adelman and others, in part because of the unreality of the theoretical projections. By combining the modified Hotelling theory with U.S. Geological Survey resource estimates, the numerical projections seem congruent with Adelman's near-term expectations. Finally, a backstop technology, such as renewable biomass ethanol, introduces a new dimension. Assuming a $2-per-gallon cost for the ethanol, the modified Hotelling theory projects accelerating use of conventional oil until depletion or substitution. Consequently, it does not seem unreasonable to believe that a finite, limited resource of conventional oil is consistent with growing use for several decades. A projected exhaustion in 100 years is consisten with increasing use for 50 years.