Effects of alkaline earth metals on the surface,structure, and reactivity of α-alumina

A series of strontium- and barium-doped alumina samples were prepared by hydrolysis, in neutral medium, starting from commercial Al₂O₃, SrCO₃, and BaCO₃ materials. The precursors thus obtained were calcined under air at 700 °C; then, the bulk and surface properties of the resulting mixed oxides were characterized by nitrogen physisorption, X-ray diffraction (XRD), hydrogen temperature-programmed reduction (H₂-TPR), thermogravimetry (TGA), and differential thermal analysis (DTA). Contrary to SrCO₃, an addition of BaCO₃ to α-Al₂O₃ increases slightly the specific surface area. XRD patterns essentially reveal the characteristic reflections assigned to α-Al₂O₃. In agreement with TGA and XRD analysis, strontium and barium carbonates remain after calcination at 700 °C, their decomposition starting above 800 °C. Let us note that this decomposition occurs more readily on AlSr-100 than on AlBa-100 with no apparent relationship with the evolution observed on the specific surface areas. H₂-TPR experiments underline a significant bulk reduction of barium and strontium carbonates taking place significantly above 900 °C with similar trend noticed during TGA regarding their thermal decomposition. However, the most relevant observation is related to a sharp enhancement of the reducibility of AlSr-y with the appearance two reduction ranges highlighting the existence of different types of interactions with strontium and the alumina substrate.     

Influence of random heterogeneity of the friction angle on bearing capacity factor Nγ

ABSTRACT

Probabilistic methods in geotechnical engineering have received a lot of attention during the last decade and different methodologies are used to capture the inherent variability of soil in different geotechnical engineering problems. In this paper, numerical simulations are conducted to obtain the bearing capacity factor, N_γ, for a purely frictional heterogenous soil where the friction angle is modelled as randomly distributed throughout the domain and the effect of its spatial variability on N_γ is investigated. A finite element method, based on the upper bound limit analysis was combined with random field theory and linear programming to develop a probabilistic analysis. Monte Carlo simulations were performed and the effect of the variability of the friction angle defined by statistical parameters on the bearing capacity factor was investigated. Results show that the mean bearing capacity factor N_γ of a footing on a spatially variable cohesionless soil is generally higher than the deterministic N_γ obtained from a constant mean value. Increasing the heterogeneity of the friction angle by an increase in the coefficient of variation generally increases this deviation. This can be explained by the nonlinearity of the relationship between N_γ and the friction angle.     

Assessment of the potential of semi-arid plants to reduce soil erosion in the Konartakhteh watershed,Iran

Soil erosion is a major environmental problem in arid and semi-arid areas. Although bioengineering is important in preventing soil erosion, plant architecture and mechanical properties in these areas are rarely studied. In this study, in order to evaluate the potential of native plants to reduce soil erosion in semi-arid regions, their above-ground (e.g., stem density, radius of the stem, etc.) and below-ground (e.g., root area ratio, root tensile strength, etc.) characteristics were measured in the field and laboratory. Five indicators, namely, stem density (SD), sediment obstruction potential (SOP), plant stiffness (MEI), relative soil detachment (RSD), and root cohesion (Cr), were taken into account. Each indicator was scored according to a five-point scale (0?=?low, 4?=?high), and then, the score of each indicator was represented on an ameba diagram. Finally, for understanding traits of plants and evaluating their potential to control rill and gully erosion, the area occupied by the ameba diagram was studied. The results indicated that the shrub Ziziphus spina-christi (MEI?=?108.35 N, RSD?=?0.398, Cr?=?8.34 kPa, SOP?=?0.097, and SD?=?0.00270) is a very suitable native plant species for controlling both the gully and rill erosion. In addition, Scariola orientalis is effective for sediment obstruction, but its low scores on the MEI and RSD indicators imply that it is not able to control gully development. Furthermore, Noaea mucronata, Platychaete glaucescens, Astragalus gummifer, Alhagi persarum, Lycium shawii, and Prosopis farcta have a distinct potential to reduce the rate of gully erosion. These results have wide applicability for adopting soil conservation measures to other semi-arid environments.     

Conventional vs. modified pseudo-dynamic seismic analyses in the shallow strip footing bearing capacity problem

The conventional pseudo-dynamic(CPD) and modified pseudo-dynamic(MPD) methods are invoked to obtain the seismic bearing capacity of strip foundations using the limit equilibrium method, with a two-wedge failure mechanism.A spectral version of the conventional pseudo-dynamic method(SPD) is also invoked by considering the ground motion amplification factor, to be a function of the non-dimensional frequency λ/B and soil damping. Numeric analyses show that bearing capacity results obtained by the MPD and SPD methods are generally consistent. Both experience the same general reduction in bearing capacity with the increase of λ/B, with successive ups and downs corresponding to soil′s natural frequencies. For 5λ/B10, SPD and MPD results fluctuated between falling above and below CPD results. For λ/B2.5, SPD and MPD results were consistent with attenuation of the shear wave, while for 10λ/B, amplification was exhibited. Results obtained by the CPD method monotonically decrease, due to the fact that CPD fails to inherently consider site effects and damping, and instead and relies on a single factor to consider the ground motion amplification.