Hysteresis‐based analysis of overland metal transport

Introducing a concept of equivalent mass depth of flow, this study describes the phenomenon of non‐point source pollutant (metal) transport for pavement (or overland) flow in analogy with wave propagation in wide open channels. Hysteretic and normal mass rating curves are developed for runoff rate and mass of 12 dissolved and particulate‐bound metal elements (pollutants) using the rainfall‐runoff and water quality data of the 15 × 20 m² instrumented pavement in Cincinnati, USA. Normal mass rating curves developed for easy computation of pollutant load are found to be of a form similar to Manning's, which is valid for open channel flows. Based on the hysteresis analysis, wave types for dissolution and mixing of particulate‐bound metals are identified. The analysis finds that the second‐order partial‐differential equation normally used for metal transport does not have the efficacy to describe fully the strong non‐linear phenomena such as is described for various metal elements by dynamic waves. In addition, the proportionality concept of the popular SCS‐CN concept is extended for determining the potential maximum metal mass M_p of all the 12 elements transported by a rain storm and related to the antecedent dry period (ADP). For the primary metal zinc element, M_p is found to increase with the ADP and vice versa. Copyright © 2003 John Wiley & Sons, Ltd.     

Converging magnetogasdynamic cylindrical shock waves in a uniform atmosphere

A self-similar solution to the problem of the implosion of a cylindrical shock wave in the presence of a magnetic field has been investigated. A strong shock wave in a cylindrically-symmetric flow travels to the axis of symmetry through a gas of uniform initial density ₀ and zero-pressure. A comparative study has been made between the results obtained in ordinary gasdynamics and magnetogasdynamics with transverse and axial components of the magnetic field. The value of similarity exponent has been assigned from that found in the paper of Whitham (1958).     

Estimation of petrol and diesel adulteration with kerosene and assessment of usefulness of selected automobile fuel quality test parameters

Kerosene is common adulterant utilized for mixing with diesel. Five fuel-adulterant mixtures in different proportions by volume were prepared and individually tested for density and kinematic viscosity. The mixtures were administered to six light cargo vehicles and the tail pipe exhaust emission was tested for opacity value. No appreciable density variation at different levels of adulteration was observed. Density was within the prescribed value even at higher adulteration. Considerable decrease in kinematic viscosity, a departure from prescribed viscosity, was noted at higher adulteration level. The percent opacity value decreased sharply even at small level of adulteration. The probable amount of kerosene present as an adulterant in diesel dispensed at filling stations in Kathmandu city ranged between 35% and 50%. The observations suggest density test is not a good indicator of diesel adulteration. Kinematic viscosity and opacity value are useful diesel adulteration test parameters. Existing diesel adulteration warrants initiation of strict compliance regulation.     

An innovative priming system - emulsion-based booster

The mineral industry is leading towards a technology driven optimization process. Drilling and blasting are such unit operations in a mine, which can alter the balance sheet of the mine if not planned properly. The development, improvement and utilization of innovative technologies in terms of blast monitoring instruments and explosives technology are important for cost effectiveness and safety of mineral industries.

The ever-growing demand for minerals has compelled the industry to adopt large opencast projects using heavy equipment. This has necessitated use of a few hundred tonnes of explosives in each blast. The bulk delivered fourth generation explosives have solved the problem of explosive loading to a large extent as it provides improved safety in manufacturing, transportation and handling. Bulk delivered emulsion is non-explosive until gasification is complete and a large quantity of explosive can be transported and loaded into blast holes efficiently and with safety. The priming of bulk delivered explosives in Indian mines uses the conventional PETN/TNT-based boosters. The conventional booster possesses safety problems in terms of handling and use, so Indian Explosives Ltd has developed an emulsion-based booster (Powergel Boost).

This paper explores the potential of an emulsion-based booster used as a primer to initiate bulk delivered emulsion explosives used in mines. An attempt has been made at a comparative study between the conventional booster and the emulsion-based booster in terms of the initiation process developed and their capability of developing and maintaining a stable detonation process in the column explosives. The study has been conducted using a continuous velocity of detonation (VOD) measuring instrument, the VODMate two channel system manufactured by Instantel Inc. of Canada. During this study three blasts were monitored. In each blast two holes were selected for study, the first hole was initiated using a conventional booster while the other one used an emulsion-based booster. The findings of the study advocates that the emulsion-based booster is capable of the efficient priming of bulk delivered column explosive with a stable detonation process in the column.     

Hydroclimatological Perspective of the Kerala Flood of 2018

Flood is among the deadliest disasters in India, and the frequency of floods and extreme precipitation events is projected to increase under the warming climate. The frequency of floods in India varies geographically as some regions are more prone to floods than the others. The Kerala flood of 2018 caused enormous economic damage, affected millions of people, and resulted in the death of more than 400 people. Here we provide a hydroclimatological perspective on the Kerala flood of 2018. Using the observations and model simulations from the Variable Infiltration Capacity (VIC) model, we show that the 2018 extreme precipitation and runoff conditions that caused flooding were unprecedented in the record of the past 66 years (1951–2017). Our results show that mean monsoon precipitation has significantly declined while air temperature has significantly increased during 1951–2017 in Kerala. The drying and warming trends during the monsoon season resulted in a declined total runoff in large part of the state in the last 66 years. Apart from the mean hydroclimatic conditions, extreme precipitation, and extreme total runoff have also declined from 1951 to 2017. However, 1 and 2-day extreme precipitation and extreme runoff conditions in August 2018 exceeded substantially from the long-term 95^th percentiles recorded during 1951–2017. Since there is no increase in mean and extreme precipitation in Kerala over the last six decades, the extreme event during August 2018 is likely to be driven by anomalous atmospheric conditions due to climate variability rather anthropogenic climate warming. The severity of the Kerala flood of 2018 and the damage caused might be affected by several factors including land use/land cover change, antecedent hydrologic conditions, reservoir storage and operations, encroachment of flood plains, and other natural factors. The impacts of key drivers (anthropogenic and natural) on flood severity need to be established to improve our understanding of floods and associated damage.     

Daily variability of dissolved inorganic radiocarbon at three sites in the surface ocean

We report radiocarbon measurements of dissolved inorganic carbon (DIC) in surface water samples collected daily during cruises to the central North Pacific, the Sargasso Sea and the Southern Ocean. The ranges of Δ¹⁴C measurements for each cruise (11–30‰) were larger than the total uncertainty (7.8‰, 2-sigma) of the measurements. The variability is attributed to changes in the upper water mass that took place at each site over a two to four week period. These results indicate that variability of surface Δ¹⁴C values is larger than the analytical precision, because of patchiness that exists in the DIC Δ¹⁴C signature of the surface ocean. This additional variability can affect estimates of geochemical parameters such as the air–sea CO₂ exchange rate using radiocarbon.     

Behaviour of physical parameters in extended gravity with hyperbolic function

In this paper, we have constructed the cosmological model of the universe in f(R, T) theory of gravity in a Bianchi type \(\mathrm{VI}_h\) universe for the functional f(R, T) in the form \(f(R,T)=\mu R+\mu T\), where R and T are respectively Ricci scalar and trace of energy momentum tensor and \(\mu \) is a constant. We have made use of the hyperbolic scale factor to find the physical parameters and metric potentials defined in the space-time. The physical parameters are constrained from different representative values to build up a realistic cosmological model aligned with the observational behaviour. The state finder diagnostic pair is found to be in the acceptable range. The energy conditions of the model are also studied.     

Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton

Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include(1) the famous Kolar mine and the world class Hutti deposit;(2) small mines at HiraBuddini, Uti, Ajjanahalli, and Guddadarangavanahalli;(3) prospects at Jonnagiri; and(4) old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous(H_2O + CO_2 ± CH_4 + NaCl) ore fluids,which precipitated gold and altered the host rocks in a narrow P-T window of 0.7-2.5 kbar and 215-320℃. While the calculated fluid O-and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs.magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite, pyrite and arsenopyrite point toward operation of fault-valves that caused pressure fluctuation-induced fluid phase separation, which acted as the dominant process of gold precipitation,apart from fluid-rock sulfidation reactions. Therefore, results from geochemistry of hydrothermal minerals and those from fluid inclusion microthermometry corroborate in constraining source of ore fluid,nature of gold transport(by Au-bisulfide complex) and mechanism of gold ore formation in the Dharwar Craton.     

Mapping of seawater inundation along Nagapattinam based on field observations

Nagapattinam, in the east coast of India, was severely affected during the deadliest Indian Ocean tsunami of December 26, 2004. The tsunami caused heavy damage to life and property, and the death toll was about 3,378 in Nagapattinam taluk. Certain villages along the coast witnessed large inundation while adjacent villages were protected from the fury of the tsunami waves. This study was carried out to examine the underlying causes for the vulnerability along Nagapattinam coast with the help of field observations, remote sensing, and geographical information system as tools. Coastal areas with high sand dunes have been protected from tsunami, and areas adjacent to backwaters were inundated. Realtime Kinematic Global Positioning System and high-resolution satellite data were used to map the topographic information and maximum extent of inundation. Thematic maps on land use, land cover, and coastal geomorphology were generated using remote sensing and field data. Using field data as the primary source of information, tsunami hazard maps have been generated for Nagapattinam.     

Surveying Upstate NY Well Water for Pesticide Contamination: Cayuga and Orange Counties

Private wells in Cayuga and Orange counties in New York were sampled to determine the occurrence of pesticide contamination of groundwater in areas where significant pesticide use coincides with shallow or otherwise vulnerable groundwater. Well selection was based on local groundwater knowledge, risk modeling, aerial photo assessments, and pesticide application database mapping. Single timepoint samples from 40 wells in each county were subjected to 93‐compound chromatographic scans. All samples were nondetects (reporting limits ≤1 μg/L), thus no wells from either county exceeded any of 15 state groundwater standards or guidance values. More sensitive enzyme‐linked immunosorbent assays (ELISA) found two wells with quantifiable atrazine in each county (0.1–0.3 μg/L), one well with quantifiable diazinon (0.1 μg/L) in Orange County, and one well with quantifiable alachlor (0.2 μg/L) in Cayuga County. Trace detections (<0.1 μg/L) in Cayuga County included atrazine (five wells), metolachlor (six wells), and alachlor (one well), including three wells with multiple detections. All 12 Cayuga County wells with ELISA detections had either corn/grain or corn/forage rotations as primary surrounding land uses (although 20 other wells with the same land uses had no detections) and all quantified detections and most trace detections occurred in wells up to 9‐m deep. Orange County trace (<0.1 μg/L) ELISA detections (atrazine three wells, diazinon one well, and metolachlor five wells) and quantified detections were only generally associated with agricultural land uses. Finding acceptable drinking water quality in areas of vulnerable groundwater suggests that water quality in less vulnerable areas will also be good.