Spectral Study of Ionized Xenon Using a Capillary Pulsed Discharge

This work presents preliminaries spectroscopic results about ionized xenon and xenon-helium mixture using a capillary pulsed discharge under several experimental results.     

Ocean floor222Rn standing crops in the Atlantic and Pacific Oceans

Excess²²²Rn standing crops have been calculated from bottom profiles obtained at 119 locations in the Atlantic and Pacific Oceans during the GEOSECS cruises. They range over more than two orders of magnitude with clear north-south and east-west patterns. The standing crops are inversely related to the sedimentation rate and the zones of highest standing crops are also areas which have a high coverage of manganese nodules.     

Evidence for discrete subpopulations of sea perch (Helicolenus ercoides) across four fjords in Fiordland,New Zealand

In coastal populations of invertebrates and fishes, the distribution of discrete subpopulations is influenced by adult and larval dispersal, as well as by the effects of habitat heterogeneity on site fidelity or connectivity. Here, we examine evidence for spatial structure of sea perch, Helicolenus percoides, populations among four fjords in the Fiordland region of southwestern New Zealand. We examine patterns in adult morphology, length-at-age, δ¹³C and δ¹⁵N of muscle tissue, and trace elemental composition of whole otoliths as proxies for population isolation among the four inner fjord regions. A multivariate analysis of morphometrics reveals significant differences among populations from each of the four sites, suggesting existence of four distinct subpopulations. These patterns are consistent with observed differences in δ¹³C and δ¹⁵N, and length-at-age estimates among the four subpopulations. Differences in whole otolith concentrations of Sr, Ba, Mg and Li, and high classification scores based on the whole otolith elemental fingerprint are also consistent with significant subdivision among areas. Patterns across all four markers are consistent with discrete subpopulation structure of adult sea perch among the four study sites. These data indicate that the newly implemented network of marine protected areas in Fiordland is likely to contain discrete populations of sea perch.     

Evaluation of heavy metals and arsenic speciation discharged by the industrial activity on the Tinto-Odiel estuary, SW Spain

This study reports the annual amount of heavy metals discharged by industrial activity into the estuary of the Ría of Huelva (SW Spain). The findings showed that the discharged metals found in highest amounts were Fe (11 t y⁻¹), Zn (3.4 t y⁻¹) and Mo (0.88 t y⁻¹). There were other metals with high pollutant charge, such as Ti (232 kg y⁻¹), As (228 kg y⁻¹), Ni (195 kg y⁻¹), Pb (100 kg y⁻¹), Cr (39 kg y⁻¹) and Cd (33 kg y⁻¹). These results were compared with pollutants transported via the Tinto and Odiel rivers from abandoned mining activities in the Iberian Pyrite Belt (IPB), and it was deduced that the amounts spilled exclusively by industries were less than 1% in relation to the total discharge. Hence, the treatment of residues from the IPB should be the priority goal to improve water quality in the estuary.     

On the use of IPCC-class models to assess the impact of climate on Living Marine Resources

The study of climate impacts on Living Marine Resources (LMRs) has increased rapidly in recent years with the availability of climate model simulations contributed to the assessment reports of the Intergovernmental Panel on Climate Change (IPCC). Collaboration between climate and LMR scientists and shared understanding of critical challenges for such applications are essential for developing robust projections of climate impacts on LMRs. This paper assesses present approaches for generating projections of climate impacts on LMRs using IPCC-class climate models, recommends practices that should be followed for these applications, and identifies priority developments that could improve current projections. Understanding of the climate system and its representation within climate models has progressed to a point where many climate model outputs can now be used effectively to make LMR projections. However, uncertainty in climate model projections (particularly biases and inter-model spread at regional to local scales), coarse climate model resolution, and the uncertainty and potential complexity of the mechanisms underlying the response of LMRs to climate limit the robustness and precision of LMR projections. A variety of techniques including the analysis of multi-model ensembles, bias corrections, and statistical and dynamical downscaling can ameliorate some limitations, though the assumptions underlying these approaches and the sensitivity of results to their application must be assessed for each application. Developments in LMR science that could improve current projections of climate impacts on LMRs include improved understanding of the multi-scale mechanisms that link climate and LMRs and better representations of these mechanisms within more holistic LMR models. These developments require a strong baseline of field and laboratory observations including long time series and measurements over the broad range of spatial and temporal scales over which LMRs and climate interact. Priority developments for IPCC-class climate models include improved model accuracy (particularly at regional and local scales), inter-annual to decadal-scale predictions, and the continued development of earth system models capable of simulating the evolution of both the physical climate system and biosphere. Efforts to address these issues should occur in parallel and be informed by the continued application of existing climate and LMR models.     

Riverine dominance of a nearshore marine demersal food web: evidence from stable isotope and C/N ratio analysis

The Thukela Bank, KwaZulu-Natal, supports a diverse ecosystem and South Africa’s only prawn fishery. Oceanographic studies suggest riverine input is not important for the biology of this system, whereas biological studies suggest the contrary, with prawn catches increasing with increased fluvial run-off. The aim of this study was to determine (i) the importance of riverine and marine organic matter for the Thukela Bank food web; and (ii) whether there are seasonal changes in the Thukela River stable isotope values, and, if so, whether these are reflected in the isotope values of demersal organisms. Estuarine organic matter, sediments and demersal organisms were collected from several sites across the bank in the wet and dry seasons of 2008, 2009 and 2010. Marine particulate organic matter was also collected in 2010 and analysed for δ13C and δ15N, as well as C/N ratios. There were strong seasonal changes in isotopic values of organic matter and fauna, especially faunal δ13C. There was an apparent time-lag in organisms assimilating riverine organic matter isotopic values, with the isotopic signature of demersal organisms reflecting that of riverine organic matter from the previous season, which is likely the result of tissue turnover time. In 2010, Thukela Bank sediment organic matter was of riverine origin and this maintained the demersal food web. We conclude that Thukela River organic matter is an important input to the food web of the Thukela Bank, indicating that any future damming of the catchment area could have serious consequences for this ecosystem.     

The role of sea ice in coastal and bottom dynamics in the Pechora Sea

This article deals with the morpho- and lithodynamic role of ice in shaping the Arctic coasts. Taking the Pechora Sea as an example, the direct and indirect impact of ice on the sea floor and shores is described. Active gouging by ice floes, ice-rafting of sedimentary material, formation of strudel scour depressions and frozen rocks on shallows are all direct impacts. The indirect impact of ice that arrests the coastal zone for most of the year is a considerable reduction of the overall energy of waves and currents. Based on the performed analysis, we plot a schematic zonation of the Pechora Sea according to the probable impact of ice on the shores and seafloor.     

The relationship between vertical eddy diffusion and buoyancy gradient in the deep sea

Vertical eddy diffusivities (K_v's) have been estimated at fourteen widely separated locations from fourteen²²²Rn profiles and two²²⁸Ra profiles measured near the ocean floor as part of the Atlantic and Pacific GEOSECS programs. They show an inverse proportionality to the local buoyancy gradient [(g/?)(??_pot/?z)] calculated from hydrographic measurements. The negative of the constant of proportionality is the buoyancy flux [?K_v(g/?)(??_pot/?z)] which has a mean of ?4 × 10^?6 cm²/sec³. Our results suggest that the buoyancy flux varies very little near the ocean floor. K_v's for the interior of the deep Pacific calculated from the relationship K_v = (4 × 10^?6cm²/sec³)/[(g/?)(??_pot/?z)] agree well with published estimates. K_v's calculated for the pycnocline are one to two orders of magnitude smaller than upper limits estimated from tritium and⁷Be distributions.Heat fluxes calculated with the model K_v's obtained from the²²²Rn profiles average 31 μcal cm^?2 sec^?1 in the Atlantic Ocean and 8 μcal cm^?2 sec^?1 in the Pacific Ocean.     

Conodont colour alteration indices (CAI) of Upper Ordovician limestones from the Iberian Peninsula

Conodont colour alteration index (CAI) data in Upper Ordovician rocks from several areas of the Variscan domain in the Iberian Peninsula indicate conditions ranging from diagenesis to low-grade metamorphism. In most of the areas, where studies using other indicators, such as illite crystallinity (IC) or where vitrinite reflectance are lacking, the CAI method has permitted a preliminary estimation of the metamorphic grade. In the Almadén syncline (Central-Iberian Zone), where IC studies are available, the thermal conditions inferred from CAI data agree with those obtained by the IC method. In the Puertollano–Almuradiel syncline, the thermal interval obtained primarily from fluid inclusions (270–370°C) overlaps considerably with that obtained from CAI data (180–340°C). In general, cleavage in rocks is present in anchizonal or epizonal conditions, whereas in diagenetic conditions with CAI 2.5, cleavage is scarce. The conodont texture changes with increasing metamorphism, and apatite recrystallisation appears in general with CAI 5. Variation of CAI values within a single sample and/or within short stratigraphic distances observed at several localities is due to hydrothermal activity.     

Refining the estimation of metal loads dissolved in acid mine drainage by continuous monitoring of specific conductivity and water level

The accurate estimation of metal loads transported by streams is necessary to calculate reliable mass transfers of metals between compartments, both at local and global scales. This estimation is particularly relevant in the case of the Tinto and Odiel Rivers (SW Spain) due to their significant contribution to the total metal transfer from continents to the ocean. At a local scale, the metal load transported by streams plays a key role in predicting the biogeochemical evolution of water reservoirs affected by Acid Mine Drainage (AMD). This work uses the relationships between specific conductivity (SC) and dissolved elements to calculate the metal load of the River Meca, a tributary of the Odiel. The SC and the water level were continuously monitored from April 2009 to June 2010. Water samples were also collected and measurements of the discharge were carried out manually once a month. The relationships between the SC and the concentration of dissolved elements are, in general, very good (R² > 0.90). However, some key elements such as Fe show a very poor correlation. A simple methodology based on the MIX code (a maximum likelihood method to estimate mixing ratios) was used to elucidate their different behaviours. During the dry period (April–December, 2009) the Fe concentration was lower than that deduced from the SC recorded value due to the precipitation of Fe-oxihydroxides, which also reduced the concentrations of As, Cr, Pb and, to a lesser extent, Cu. At the same time Na, Sr, Ca and Li were enriched because of the higher interaction with the riverbed materials. Correlations between the SC and the metal concentration improved significantly when each period was considered separately. A second dry period (April–June 2010) shows high SC values, although no dissolution/precipitation of solid phases is evidenced. This indicates that SC alone is not enough to predict the dissolved metal loads in Mediterranean AMD streams. The metal load transported by the River Meca was determined for the hydrological year 2009/10 as 1933 ± 129 tonnes of Fe, 990 ± 155 of Al and 378 ± 41 of Zn.