An experimental study of dispersion of an interactive tracer in chemically heterogeneous medium at a column scale

This paper aims at examining the increase of phenol adsorption breakthrough curves spreading caused by the chemical heterogeneity of granular activated carbon fixed beds. The local and the thermodynamic equilibrium assumption, as well as the nonlinear adsorption obeying to Langmuir isotherm, are considered. This study particularly tempts to link the reduced variance of phenol breakthrough curves to a measurable quantifying parameter of the chemical heterogeneity. The investigated artificial heterogeneous media are prepared by alternating layers of two types of granular activated carbon, active and non-active ones, that have similar physical properties. On the one hand, the chemical heterogeneity is quantified by the active layer relative thickness of the column length, l₁/L. On the other hand, it is quantified by the mean value of the probability distribution γ. The latter also represents the mean active grains mass ratio of the total medium mass, hence the medium mean capacity. The obtained results show an increase in the reduced variance and thus the effective global dispersion with the heterogeneity; the increase is as important as the medium capacity decreases. However, the dispersion increase achieves a limit value, even when the heterogeneity increases. The results are statistically modelled using a regression equation function of the capacity variation in terms of γ and the chemical heterogeneity in terms of l₁/L. The relationship combining the medium capacity and the chemical heterogeneity is obtained. The relationship implicitly takes into account the effect of the column length.     

Characters of Nummulites multiplicutiospiralis n. sp. from theQarara Formation,Maghagha, Nile Valley,Egypt

Nummulites multiplicutiospiralis n.sp.is described and illustrated for both generations from a claystone of Lutetian age in the Middle Eocene Qarara Formation, Maghagha,Nile valley,Egypt.Previously considered to be Nummulites gizehensis,we describe this form as a new species based on diameter of the test and protoconch sizes,septal shape and granulations.The primary feature of this species is spiral multiplication,seen in spiral section.The species is also characterized morphologically by lenticular to flat tests with rounded periphery,wrinkled to broadly meandering septal filaments and few granules on the periphery in microspheric forms.The granules are spirally arranged on the septal filaments in megalospheric forms.Chambers are longer than high and the spire is irregular.The new taxon belongs to the Nummulites partschi Group,Subgroup N.gizehensis.Reflexive coiling in the spiral may develop through ontogeny as in N.rollandi,the species which was considered to be an index species in the southern Tethys (Boukhary et al.,1982 and Boukhary et al.2010).The characters of the new species,as well as its retrogenesis and reflexive coiling,should be further studied in general in Nummulites spp.,to understand the importance of such characters phylogenetically.     

On the Validity and Evolution of Assilina Species during the Ypresian–Lutetian: Example from Bir Dakhl, Eastern Desert, Egypt

The genus Assilina is a taxon within the Nummulitacea that appeared early in the Ypresian (Early Eocene) and continued until the end of the Lutetian (Middle Eocene). Thus, this taxon could be useful for the chronostratigraphy of this time interval. Lower Eocene rocks in southern Galala, Egypt are exposed at Bir Dakhl. This section includes marl sediments with debris flow shallow-marine facies deposits laid down during early Eocene times and includes fossils of large foraminifera: Assilina placentula Deshayes, 1838 and Nummulites burdigalensis de la Harpe, 1926. These are systematically treated, described and illustrated. Nummulites burdigalensis belongs to the N. burdigalensis group, and Assilina placentula belongs to the group of Assilina exponens. This assumption is based on qualitative morphology and quantitative measurements. Both species, together with Operculina libyca Schwager, 1883, enable the assignment of the Bir Dakhl (D5-40 Section) to the Early Eocene, Ypresian (SBZ10 of Serra- Kiel et al., 1998) supporting an earlier opinion that Assilina placentula belongs to that zone in the calibrated larger foraminiferal biostratigraphic zonation.     

The “Taourirt” magmatic province, a marker of the closing stage of the Pan-African orogeny in the Tuareg Shield: review of available data and Sr–Nd isotope evidence

The Tuareg Shield, located between the Archaean to Palaeoproterozoic Saharan metacraton and the West African craton, is composed of 23 recognized terranes that welded together during the Neoproterozoic Pan-African orogeny (750–520 Ma). Final convergence occurred mainly during the 620–580 Ma period with the emplacement of high-K calc-alkaline batholiths, but continued until 520 Ma with the emplacement of alkali-calcic and alkaline high-level complexes. The last plutons emplaced in central Hoggar at 539–523 Ma are known as the “Taourirt” province. This expression is redefined and three geographical groups are identified: the Silet-, Laouni- and Tamanrasset-Taourirts. The Silet-Taourirts are cross-cutting Pan-African island arc assemblages while the two others intrude the Archaean–Palaeoproterozoic LATEA metacraton. The Taourirts are high-level subcircular often nested alkali-calcic, sometimes alkaline, complexes. They are aligned along mega-shear zones often delimiting terranes. Mainly granitic, they comprise highly differentiated varieties such as alaskite (Silet-Taourirts) and topaz–albite leucogranite (Tamanrasset-Taourirts). Different subgroups were defined on the basis of REE patterns and major and other trace elements. The Taourirt province displays a wide transition from dominant alkali-calcic to minor alkaline granite varieties. Sr isotopes indicate that these complexes were affected by fluid circulation during the Ordovician along shear zones probably contemporaneous to the beginning of the Tassilis sandstone deposition. Nd isotope systematic indicates a major interaction with the upper crust during the emplacement of highly differentiated melts, particularly in samples showing seagull wing-shaped REE patterns. On the other hand, all Taourirt plutons are strongly contaminated by the lower crust: _Nd vary from −2 to −8 and T_DM from 1200 to 1700 Ma. This implies the presence of an old crust at depth, also below the Silet-Taourirts, which are emplaced within Pan-African island arc assemblages. A model is proposed for the genesis of the Taourirt province where reworking of the mega-shear zones, which dissected the LATEA metacraton, provoked a linear delamination of the lithospheric mantle, asthenosphere uprise and partial melting of the lower crust (or strong interaction with), giving rise to a mixed source.