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1.
Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater. 相似文献
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Community-based coastal resource management projects facilitated by non-governmental organizations (NGOs) in the Philippines have explored approaches to decrease poverty-driven over-exploitation of coastal resources. There has been little reporting and analysis of such activities until recently. Nine case studies have recently been published and this paper presents a brief summary of these, along with an analysis of the trends and themes identified. Though diverse and covering the Philippines from Mindanao to Luzon, the case studies highlight the value of community commitment and participation in decisions regarding, and in the implementation of, resource management in ways that consider not only the bio-physical aspects of resource management but the social, economic and legal implications. Experience in working with local government has been both successful and limited. Successful projects raise hopes for further progress through education and organization of communities to improve livelihoods and protect coastal resources. 相似文献
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Mohamed Chaker Raddadi Annie Arnaud Vanneau Grard Poupeau Elisabeth Carrio-Schaffhauser Hubert Arnaud Alice Rivera 《Comptes Rendus Geoscience》2005,337(16):96
High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005). 相似文献
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Manuel Castillo‐Rivera Rocío Zárate‐Hernández Selene Ortiz‐Burgos José Zavala‐Hurtado 《Marine Ecology》2010,31(4):633-642
We hypothesized that temporal variation in fish species composition and community structure in a low complexity habitat in the Pueblo Viejo Lagoon, Mexico, is influenced by diel light/dark cycles and tidal stage, and by seasonal changes in salinity and temperature. We collected a total of 17,661 individuals during 2‐h interval sampling over six bi‐monthly 24‐h sampling cycles representing 53 species, of which 11 (~20%) were previously unknown in the system. Diel variation indicated that significantly higher numbers of individuals and species were caught at night, whereas diversity and evenness were higher during the day. Species richness was significantly higher in July and January, whereas diversity and evenness peaked around May; both were correlated with temperature. Diel variation in species composition was influenced primarily by the light/dark cycle. Cluster analyses of each diel cycle separated fish assemblages from midday samples from those of nocturnal samples, separated by an extended wide transition period as fish moved at dawn and during the late afternoon/dusk. Significant shifts (as determined by MANOVA) in assemblage structure occurred between months. Canonical correspondence analysis showed that temperature and day/night effects were the most important environmental variables structuring the fish community. This constrained ordination also defined species with specific habitat preferences as follows: (i) diurnal, warm temperature species (mainly planktivores) (Brevoortia gunteri, Cetengraulis edentulus, Diapterus auratus, and Membras martinica); (ii) nocturnal, warm temperature species (mainly predators) (Citharichthys spilopterus, Cathorops melanopus, and Bairdiella spp.); and (iii) low temperature, diurnal species (Brevoortia patronus and Mugil curema) or those with twilight and nocturnal distributions (Anchoa mitchilli, the most numerically abundant species). Our results indicate that diel and seasonal changes in fish community structure were mainly related to day/night cycles and temperature regimes. 相似文献
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Daniel Paradis Laurie Tremblay René Lefebvre Erwan Gloaguen Alfonso Rivera Michel Parent Jean-Marc Ballard Yves Michaud Patrick Brunet 《Environmental Earth Sciences》2014,72(5):1325-1348
Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km2. The workflow involves characterization and data integration steps that were applied on a 12-km2 study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive. 相似文献
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The North Anatolian Fault (NAF) extends for about 1500 km from Karliova to the east, to the Egean Sea in the west. The Marmara region, located near the western end of the NAF, is a tectonically active zone characterized by the transition between a strike slip stress regime and an extensional one in the Aegean Sea. Microseismic studies performed around the Marmara Sea in 1995 [Tectonophysics 316, 2000, 1], and just before the 1999 Izmit Earthquake Bull. Seism. Soc. Am. 92, 2002a, 361;J. Seismol. 6, 2002b, 287) permitted the analysis of the evolution of seismicity connected to this destructive earthquake and its sequels. Several observations indicate that the aftershock distribution fits well the EW orientation of the NAF, but the ruptures are not simple and linear as a first glance would suggest. Instead they are segmented in at least five pieces as shown by the slip variation and aftershock clusters, showing complexity at different scales (Bull. Seism. Soc. Am. 92, 2002a, 361). There is still a gap, across the northern border of the Marmara Sea that has not ruptured, and this is the only sector that did not break on the NAF since the 1939 great Erzincan earthquake. Will it rupture as a whole with a large magnitude earthquake, or by segments with smaller magnitude events? The Hurst analysis of the overall behaviour of the seismicity in the Marmara region since historical times shows that if a large earthquake occurs in the near future, it might break the complete gap. The Hurst character of the time variation of seismicity is persistent with H= 0.82. The aftershocks of the 1999 Izmit earthquake can be analyzed by using the Hurst method, showing an exceptionally high persistent memory. 相似文献