Stable isotope study of antimony deposits in the Muratdagi region,western Turkey

The Muratdagi region is rich in antimony deposits having the following common characteristics: post Miocene age, location on the down-thrown blocks next to normal faults, in the vicinity of active or fossil thermal springs, and in contact with carbonate rocks. The isotopic composition of — 7. SMOW of the mineralizing fluid calculated from the measured ° ¹⁸O of quartz and the fluid inclusion microthermometry, is indicative of meteoric water origin. The ° ¹³C of the inclusion CO₂ of — 19.1 to — 25.4 PDB is indicative of interaction with organic material-graphite. The ° ³⁴S of stibnite — 3.6 to — 0.7 is, in view of the mineral assemblage, indicative of magmatic origin of the sulphur. A tightly confined set of structural, lithological, hydrological and geochemical features define a sequence of geochemical processes; formation of acid and reducing fluid, leaching and transport of antimony complexes and precipitation of stibnite within defined lithological units. The set of processes seems to have taken place within a space of 5000 m lateral and 1000 m vertical extension.     

Crustal structure of Iraq from receiver functions and surface wave dispersion: implications for understanding the deformation history of the Arabian–Eurasian collision

We report the crustal structure for two locations in Iraq estimated by joint inversion of P -wave receiver functions (RFs) and surface (Rayleigh) wave group velocity dispersion. RFs were computed from teleseismic recordings at two temporary broad-band seismic stations located in Mosul (MSL) in the Zagros Fold Belt and Baghdad (BHD) in the Mesopotamian Foredeep. Group velocity dispersion curves at the sites were derived from continental-scale tomography. The inversion results show that the crustal thicknesses are 39 km at MSL and 43 km at BHD. We observe a strong Ps _Moho at BHD consistent with a sharp Moho discontinuity. However, at MSL we observe a weak Ps _Moho suggesting a transitional Moho where crustal thickening is likely to be occurring in the deep crust. Both sites reveal low velocity surface layers consistent with sedimentary thickness of about 3 km at station MSL and 7 km at BHD and agreeing well with the previous reports. Ignoring the sediments, the crystalline crustal velocities and thicknesses are remarkably similar at both stations. The similarity of crustal structure suggests that the crust of the northeastern proto-Arabian Platform was uniform before subsidence and deposition of the sediments in the Cenozoic. If crystalline crustal structure is uniform across the northern Arabian Platform then crustal thickness variations in the Zagros Fold Belt and Thrust Zone should reveal the history of deformation and crustal shortening in the Arabian–Eurasian collision zone and not reflect pre-existing crustal thickness variations in the Arabian Plate.     

Sulfur isotope study of source and deposits of stibnite in the Turhal Area,Turkey

The Turhal antimony sulfide ore deposits are hosted by a Permian-Jurassic sequence which consists of black phyllites at the base followed by interbedded phyllites and calcareous quartzites with metabasite interlayers and then by brown-gray phyllites with marble blocks. Four different styles and three distinct episodes of mineralization were distinguished according to deposition features of the ores and kinkbands in the stibnite crystals. Stibnite from stratiform, disseminated and vein occurrences as well as pyrite from black phyllites showed the following sulfur isotope composition (³⁴S): +2.8 and +3.0 for stratiform stibnite (n = 2), +3.6 and +5.5 for disseminated stibnite (n = 2), +2.5 to +7.8 for vein stibnite (n = 11) and -6.1 to +0.1 for pyrite (n = 3). The ³⁴S compositions of stibnite are interpreted as suggesting an ultimately single source for sulfur in the various styles of mineralization, i.e. synsedimentary volcanic exhalations for the stratiform and disseminated together with ores and hydrothermal mobilisation of these as well as leaching of volcanic rocks to form the vein ores. Deep basinal fluids probably under normal geothermal gradient conditions caused the leaching of the primary sulfides as suggested by the oxygen isotope composition of vein quartz associated with the ores. By contrast sulfur in pyrite is essentially a derivation of seawater sulfate through bacterial and/or chemical reduction.     

Lithospheric structure of the continent–continent collision zone: eastern Turkey

We infer the lithospheric structure in eastern Turkey using teleseismic and regional events recorded by 29 broad-band stations from the Eastern Turkey Seismic Experiment (ETSE). We combine the surface wave group velocities (Rayleigh and Love) with telesesimic receiver functions to jointly invert for the S -wave velocity structure, Moho depth and mantle-lid (lithospheric mantle) thickness. We also estimated the transverse anisotropy due to Love and Rayleigh velocity discrepancies. We found anomalously low shear wave velocities underneath the Anatolian Plateau. Average crustal thickness is 36 km in the Arabian Plate, 44 km in Anatolian Block and 48 km in the Anatolian Plateau. We observe very low shear wave velocities at the crustal portion (30–38 km) of the northeastern part of the Anatolian Plateau. The lithospheric mantle thickness is either not thick enough to resolve it or it is completely removed underneath the Anatolian Plateau. The shear velocities and anisotropy down to 100 km depth suggest that the average lithosphere–asthenosphere boundary in the Arabian Plate is about 90 and 70 km in Anatolian block. Adding the surface waves to the receiver functions is necessary to constrain the trade-off between velocity and the thickness. We find slower velocities than with the receiver function data alone. The study reveals three different lithospheric structures in eastern Turkey: the Anatolian plateau (east of Karliova Triple Junction), the Anatolian block and the northernmost portion of the Arabian plate. The boundary of lithospheric structure differences coincides with the major tectonic boundaries.     

Source Parameters for 1999 North Anatolian Fault Zone Aftershocks

We develop a data set of aftershock recordings of the 1999, M = 7.4 Izmit and M = 7.2 Duzce (Turkey) earthquakes to study their source parameters. We combined seismograms from 44 stations maintained by several sources (organizations) to obtain a unified data set of events (2.1 ≤ M_w ≤ 5.5). We calculate source parameters of these small earthquakes by two methods that use different techniques to address the difficulty in obtaining source spectra for small earthquakes subject to interference from site response. One method (program NetMoment (NM), Hutchings, 2004) uses spectra of direct S waves in a simultaneous inversion of local high-frequency network data to estimate seismic moment, source corner frequency (f_c), site attenuation (k) and whole-path Q. This approach takes advantage of the source commonality in all recordings for a particular earthquake by fitting a common Brune source spectrum to the data with a and individual k. The second approach (Mayeda et al., 2003) uses the coda method (CM) to obtain “nonmodel-based” source spectra and moment estimates from selected broadband recording sites. We found that both methods do well for events that allow the comparison with seismic moment estimates derived from waveform modeling. Also, source spectra obtained from the two methods are very closely matched for most of the events they have in common. We use an F test to examine the trade-off between k and f_c picks identified by the direct S-wave method. About half of the events could be constrained to have less than a 50% average uncertainty in f_c and k. We used these source spectra solutions to calculate energy and apparent stress and compare these to estimates from the selected “good quality” source spectra from CM. Both studies have values mutually consistent and show a similar increase in apparent stress with increasing moment. This result has added merit due to the independent approaches to calculate apparent stress. We conclude that both methods are at least partially validated by our study, and they both have usefulness for different circumstances of recording local small earthquakes. CM would work well in studies for which there is a broad magnitude range of events and NM works well for local events recorded by band-limited recorders.