Tephrochronology and tephrostratigraphy of two Pleistocene continental fossiliferous successions from central Italy

The stratigraphical context of two Middle Pleistocene fossiliferous palaeosols from Central Italy (Abruzzo and Tuscany) have been studied. Small mammals and molluscs occur in both palaeosols, which are covered by tephra layers that were analysed using an interdisciplinary approach. Application of fission‐track dating to apatites separated from the Case Picconetto tephra (Pescara, Abruzzo), yielded an age of 0.48 ± 0.04 Ma, indistinguishable from those previously determined for the Campani Quarry (Lower Valdarno, Tuscany) (0.46 ± 0.05 Ma and 0.48 ± 0.05 Ma). Geochemical and petrographic investigations indicate that these tephra originated from different volcanoes, the Alban Hills Volcanic Complex and the Vico Volcano (Latium) respectively. Small mammal and mollusc assemblages indicate different palaeoclimatic and palaeoenvironmental conditions for the Case Picconetto and Campani Quarry palaeosols. Warm and humid conditions can be inferred for the Campani Quarry site, whereas open and cold conditions can be inferred for Case Picconetto. On the basis of faunal data, fission‐track dates and attribution of tephra to specific volcanic eruptions, we suggest a correlation of these faunas with marine oxygen isotope stage 14 (Case Picconetto) and with marine oxygen isotope stage 11 (Campani Quarry), respectively. Copyright © 2003 John Wiley & Sons, Ltd.     

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

The gas/steam ratio as indicator of heat transfer at the Solfatara fumaroles,Phlegraean Fields (Italy)

A simple geochemical model of Solfatara, Phlegraean Fields (Italy), is proposed on the basis of gas composition and temperature at the surface.Data on the Solfatara fumaroles have been collected since 1979 within the framework of a geochemical monitoring for the surveillance of the Phlegraean volcanic system.Surface manifestations of Solfatara are likely to be fed through isoenthalpic expansion of dry steam, which separates from a geothermal liquid in an intensively fractured zone at about 236°C. This value is consistent both with gas composition and surface temperature.The gas/steam ratio appears to be the most effective parameter to detect changes of heat flow at depth.Actually a remarkable decrease in the gas/steam ratio has been observed since 1981, while the gas composition and the temperature did not change significantly. These facts suggest increased heat flow at depth.     

A lunar cryptomare dome near Mee H and Drebbel F

In this study, we examine the lunar mare dome Mee 1 situated near the craters Mee H and Drebbel F in a region showing evidence of ancient (pre-Orientale) mare volcanism and cryptomare deposits. Regional stratigraphic relations indicate that Mee 1 was formed prior to the Orientale impact at the beginning of the Imbrian period. Based on a combined photoclinometry and shape from shading technique applied to telescopic CCD images of the dome acquired under oblique illumination, we determined a diameter of Mee 1 of 25 km, a height of 250 m, a flank slope of 1.15^°, and a volume of . Based on rheologic modelling of the dome and a viscoelastic model of the feeder dike, we obtained a magma viscosity of , an effusion rate of , a duration of the effusion process of 1.6 years, a magma rise speed of , a width of the feeder dike of 32 m, and a horizontal dike length of 144 km. A comparison of Mee 1 with domes with similar morphometric properties, which are located near Milichius and inside the crater Petavius, reveals strong similarities with respect to the viscosity of the dome-forming magma and the feeder dike geometry, while the effusion rate and magma rise speed of Mee 1 are somewhat higher. The pronounced morphometric differences between Mee 1 and a smaller dome situated close to the crater Doppelmayer and characterised by a similar magma viscosity suggest that the growth of that dome was limited by exhaustion of the magma reservoir, while Mee 1 and the other larger domes display morphometric properties presumably coming closer to the cooling limit. The comparison of the ancient dome Mee 1 with the younger (Eratosthenian) edifices near Milichius and Doppelmayer suggests that the conditions in the upper mantle and the crust favoured high eruption volumes, effusion rates, and magma rise speeds, implying the occurrence of large magma reservoirs preventing the limitation of dome growth by magma exhaustion. On the other hand, we observe similar general morphometric, rheologic, and feeder dike characteristics and, thus, conclude that the formation conditions of lunar mare domes did not change fundamentally during the Imbrian period.     

Lunar intrusive domes: Morphometric analysis and laccolith modelling

This study examines a set of lunar domes with very low flank slopes which differ in several respects from the frequently occurring lunar effusive domes. Some of these domes are exceptionally large, and most of them are associated with faults or linear rilles of presumably tensional origin. Accordingly, they might be interpreted as surface manifestations of laccolithic intrusions formed by flexure-induced vertical uplift of the lunar crust (or, alternatively, as low effusive edifices due to lava mantling of highland terrain, or kipukas, or structural features). All of them are situated near the borders of mare regions or in regions characterised by extensive effusive volcanic activity. Clementine multispectral UVVIS imagery indicates that they do not preferentially occur in specific types of mare basalt. Our determination of their morphometric properties, involving a combined photoclinometry and shape from shading technique applied to telescopic CCD images acquired at oblique illumination, reveals large dome diameters between 10 and more than 30 km, flank slopes below 0.9°, and volumes ranging from 0.5 to 50 km³. We establish three morphometric classes. The first class, In1, comprises large domes with diameters above 25 km and flank slopes of 0.2°-0.6°, class In2 is made up by smaller and slightly steeper domes with diameters of 10-15 km and flank slopes between 0.4° and 0.9°, and domes of class In3 have diameters of 13-20 km and flank slopes below 0.3°. While the morphometric properties of several candidate intrusive domes overlap with those of some classes of effusive domes, we show that a possible distinction criterion are the characteristic elongated outlines of the candidate intrusive domes. We examine how they differ from typical effusive domes of classes 5 and 6 defined by Head and Gifford [Head, J.W., Gifford, A., 1980. Lunar mare domes: classification and modes of origin. Moon Planets 22, 235-257], and show that they are likely no highland kipukas due to the absence of spectral contrast to their surrounding. These considerations serve as a motivation for an analysis of the candidate intrusive domes in terms of the laccolith model by Kerr and Pollard [Kerr, A.D., Pollard, D.D., 1998. Toward more realistic formulations for the analysis of laccoliths. J. Struct. Geol. 20(12), 1783-1793], to estimate the geophysical parameters, especially the intrusion depth and the magma pressure, which would result from the observed morphometric properties. Accordingly, domes of class In1 are characterised by intrusion depths of 2.3-3.5 km and magma pressures between 18 and 29 MPa. For the smaller and steeper domes of class In2 the magma intruded to shallow depths between 0.4 and 1.0 km while the inferred magma pressures range from 3 to 8 MPa. Class In3 domes are similar to those of class In1 with intrusion depths of 1.8-2.7 km and magma pressures of 15-23 MPa. As an extraordinary feature, we describe in some detail the concentric crater Archytas G associated with the intrusive dome Ar1 and discuss possible modes of origin. In comparison to the candidate intrusive domes, terrestrial laccoliths tend to be smaller, but it remains unclear if this observation is merely a selection effect due to the limited resolution of our telescopic CCD images. An elongated outline is common to many terrestrial laccoliths and the putative lunar laccoliths, while the thickness values measured for terrestrial laccoliths are typically higher than those inferred for lunar laccoliths, but the typical intrusion depths are comparable.     

Water chemistry of Lake Quilotoa (Ecuador) and assessment of natural hazards

A geochemical survey carried out in November 1993 revealed that Lake Quilotoa was composed by a thin (14 m) oxic epilimnion overlying a 200 m-thick anoxic hypolimnion. Dissolved CO₂ concentrations reached 1000 mg/kg in the lower stratum. Loss of CO₂ from epilimnetic waters, followed by calcite precipitation and a consequent lowering in density, was the apparent cause of the stratification.The Cl, SO₄ and HCO₃ contents of Lake Quilotoa are intermediate between those of acid–SO₄–Cl Crater lakes and those of neutral-HCO₃ Crater lakes, indicating that Lake Quilotoa has a ‘memory’ of the inflow and absorption of HC1- and S-bearing volcanic (magmatic) gases. The Mg/Ca ratios of the lake waters are governed by dissolution of local volcanic rocks or magmas, but K/Na ratios were likely modified by precipitation of alunite, a typical mineral in acid–SO₄–Cl Crater lakes.The constant concentrations of several conservative chemical species from lake surface to lake bottom suggest that physical, chemical and biological processes did not have enough time, after the last overturn, to cause significant changes in the contents of these chemical species. This lapse of time might be relatively large, but it cannot be established on the basis of available data. Besides, the lake may not be close to steady state. Mixing of Lake Quilotoa waters could presently be triggered by either cooling epilimnetic waters by 4°C or providing heat to hypolimnetic waters or by seismic activity.Although Quilotoa lake contains a huge amount of dissolved CO₂ (3×10¹¹ g), at present the risk of a dangerous limnic eruption seems to be nil even though some gas exsolution might occur if deep lake waters were brought to the surface. Carbon dioxide could build up to higher levels in deep waters than at present without any volcanic re-awakening, due to either a large inflow of relatively cool CO₂-rich gases, or possibly a long interval between overturns. Periodical geochemical surveys of Lake Quilotoa are, therefore, recommended.     

The determination of deep temperatures by means of the CO-CO2-H2-H2O geothermometer: an example using fumaroles in the Campi Flegrei,Italy. A comment

Three points raised in the paper by Tedesco and Sabroux (1987) are dealt with. (1) The inconsistency between the water partial pressure calculated by Tedesco and Sabroux (1987) and saturation pressure is due to the improper use of the water-gas-shift reaction as a geothermometer. In fact Tedesco and Sabroux (1987) do not take into account the distribution of gas species between the coexisting vapour and liquid phases. (2) The depth of the “steam reservoir” is evaluated by Tedesco and Sabroux (1987) in too simplistic a way. This matter should be treated with greater care owing to the high social impact of any consideration on the Phlegraean Fields system. (3) The reliability of carbon monoxide determination at the concentration level encountered at Solfatara depends on the collection method rather than on the gas-chromatographic technique.     

Formation of lunar mare domes along crustal fractures: Rheologic conditions, dimensions of feeder dikes, and the role of magma evolution

In this study we examine a set of lunar mare domes located in the Hortensius/Milichius/T. Mayer region and in northern Mare Tranquillitatis with respect to their formation along crustal fractures, their rheologic properties, the dimensions of their feeder dikes, and the importance of magma evolution processes during dome formation. Many of these domes display elongated summit vents oriented radially with respect to major impact basins, and several dome locations are also aligned in these preferential directions. Analysis of Clementine UV/VIS and Lunar Prospector gamma ray spectrometer data reveals that the examined mare domes formed from low-Si basaltic lavas of high FeO and low to moderate TiO₂ content. Based on their morphometric properties (diameter, height, volume) obtained by photoclinometric and shape from shading analysis of telescopic CCD images, we derive rheologic quantities (lava viscosity during eruption, effusion rate, duration of the effusion process, magma rise speed) and the dimensions of the feeder dikes. We establish three rheologic groups characterised by specific combinations of rheologic properties and dike dimensions, where the most relevant discriminative parameter is the lava viscosity η. The first group is characterised by and contains the domes with elongated vents in the Milichius/T. Mayer region and two similar domes in northern Mare Tranquillitatis. The second group with comprises the very low aligned domes in northern Mare Tranquillitatis, and the third group with the relatively steep domes near Hortensius and in the T. Mayer region. The inferred dike dimensions in comparison to lunar crustal thickness data indicate that the source regions of the feeder dikes are situated within the upper crust for six of the domes in northern Mare Tranquillitatis, while they are likely to be located in the lower crust and in the upper mantle for the other examined domes. By comparing the time scale of magma ascent with the time scale on which heat is conducted from the magma into the host rock, we find evidence that the importance of magma evolution processes during ascent such as cooling and crystallisation increases with lava viscosity. We conclude that different degrees of evolution of initially fluid basaltic magma are able to explain the broad range of lava viscosities inferred for the examined mare domes. The spectral data reveal that differences in TiO₂ content may additionally account for the systematic difference in lava viscosity between the two examined lunar regions. We show that the described mechanisms are likely to be valid also for other lunar mare domes situated near Cauchy and Arago, regarded for comparison. On the other hand, we find for the Gruithuisen and Mairan highland domes that despite their inferred high lava viscosities of , no significant magma cooling in the dike occurred during ascent, supporting previous findings that the highland domes were formed during a specific phase of non-mare volcanism by highly silicic viscous lavas.