On the detailed magnetostratigraphy of greigite — (Smythite) mineralization,Sokolov Brown-Coal Basin,bohemia

Summary In the Middle Miocene claystones containing fossil micro-organic matter and overlying the brown-coal seams in the Jii quarry of the Sokolov Brown-Coal Basin, a strongly magnetic layer was found and subjected to detailed palaeomagnetic investigations. The principal carrier of magnetism in this bed (called Kocián's bed) is the ferrimagnetic mineralization of greigite or greigitesmythite showing pronounced metastable properties. This mineralization must be treated with caution during laboratory tests aimed at deriving palaeomagnetic directions. In Kocián's bed, about two metres thick, two zones of palaeomagnetic field transition were identified. The high degree of demagnetization achieved by using thermal stepwise procedures and a MAVACS apparatus enabled the origin of the self-reversal of remanence to be defined after heating to 360°C. The process of chemo-remanent magnetization of the authigenic greigite-(smythite) mineralization fossilizing the palaeomagnetic field was relatively fast; the transition of the palaeomagnetic field is recorded in layers not exceeding a thickness of 2 × 10^–2 m.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990.     

Magnetic properties,self-reversal remanence and thermal alteration products of smythite

Summary This study is a follow up of the investigation of some magnetic properties and metastability of greigite in samples obtained from Miocene claystones in the Kruné hory (Erzgebirge) Piedmont basins (Bohemia). Three different methods of upgrading the smythite were applied; the magnetic properties of the concentrates are compared. The thermal conversion of smythite sets in at 200°C while greigite converts at 250°C. The first intermediate products to be formed are iron sulphides, marcasite clearly dominating over pyrite and pyrrhotite. Apart from a Fe³⁺ sulphate with a composition of Fe₂(SO₄)₃, oxidation of these sulphides gives rise to -Fe₂O₃. The result of the subsequent decomposition of the mentioned sulphate is the formation of -Fe₂O₃, which retains the sulphate structure. The final product of the thermal decomposition at 800°C is -Fe₂O₃. In the smythite concentrate the conversion to Fe³⁺ sulphate and -Fe₂O₃ is about twice as intensive as in greigite. No direct conversion to -Fe₂O₃ was found. During the thermal process self-reversals of remanence were observed, in various samples as many as four reversals in the temperature interval from 340 to 590°C. The occurrences of self-reversals of remanence were only observed at high degrees of thermal demagnetization, of the order of 10^–2 down to 10^–3 in the temperature interval of sulphide origin (below 400°C), and of the order of 10^–4 down to 10^–6 in the temperature interval of Fe-oxides origin (above 400°C).Presented at the 3rd Conference on New Trends in Geomagnetism, Castle of Smolenice, Czechoslovakia, June 22–29, 1992     

Magnetic record associated with tree ring density: Possible climate proxy

A magnetic signature of tree rings was tested as a potential paleo-climatic indicator. We examined wood from sequoia tree, located in Mountain Home State Forest, California, whose tree ring record spans over the period 600 – 1700 A.D. We measured low and high-field magnetic susceptibility, the natural remanent magnetization (NRM), saturation isothermal remanent magnetization (SIRM), and stability against thermal and alternating field (AF) demagnetization. Magnetic investigation of the 200 mm long sequoia material suggests that magnetic efficiency of natural remanence may be a sensitive paleoclimate indicator because it is substantially higher (in average >1%) during the Medieval Warm Epoch (700–1300 A.D.) than during the Little Ice Age (1300–1850 A.D.) where it is <1%. Diamagnetic behavior has been noted to be prevalent in regions with higher tree ring density. The mineralogical nature of the remanence carrier was not directly detected but maghemite is suggested due to low coercivity and absence of Verwey transition. Tree ring density, along with the wood's magnetic remanence efficiency, records the Little Ice Age (LIA) well documented in Europe. Such a record suggests that the European LIA was a global phenomenon. Magnetic analysis of the thermal stability reveals the blocking temperatures near 200 degree C. This phenomenon suggests that the remanent component in this tree may be thermal in origin and was controlled by local thermal condition.     

The detection of common cycles in magnetic susceptibility observed in distant magnetostratigraphic sections

The data obtained by former magnetostartigraphic studies of sections of Jurassic/Cretaceous age located at Brodno, W. Slovakia, and Puert Esca?o, S. Spain, about 2200 km apart, are herein reprocessed in order to detect environmental cycles recorded by magnetic susceptibility. The dating of the samples with respect to the geomagnetic polarity time scale enabled to estimate the power spectrum up to the frequency of 11 Myr^?1 as well as the phases corresponding to the spectral maxima. Using these frequencies and phases, we linked together the cycles detected with different sections. The hypothesis that their similarity results only from random coincidence had to be rejected for seven pairs of these cycles. The frequencies of these cycles are related to those of the recent modes of orbital eccentricity.     

Magnetic properties of high-Ti basaltic rocks from the Krušné hory/Erzgebirge MTS. (Bohemia/Saxony), and their relation to mineral chemistry

This study provides new thermomagnetic and petrographic data on specific basaltic rock association from the broader vicinity of the Lou?ná-Oberwiesenthal volcanic centre, western Bohemia/Saxony. Two types of volcanic rocks were recognized there: (i) high-Ti types (3.5–5.2 wt% TiO₂) represented by (mela)nephelinite s.s., and sporadically present (ii) medium-Ti types (2.5–3.5 wt% TiO₂) of olivine nephelinite, nepheline basanite and phonotephrite compositions. In order to examine the rock-magnetic behaviour, they were studied for their variations in the Curie temperature (T_C) and field-dependent susceptibility, spinel group minerals, chemistry and petrology. Magnetic susceptibility of ulvöspinel-rich titanomagnetite, as a dominant magnetic carrier, depends on the amplitude of measured magnetic field, whereas pure magnetite is field-independent. Field dependence parameter ^kHD of the studied basaltic rocks ranges from 0.8 to 18.7%, TiO₂ contents in titanomagnetite range from 12.7 to 20.1 wt.%. TiO₂ content in titanomagnetite does not correlate with whole-rock TiO₂ content (2.8 to 5.6 wt.%). The content of substituted titanium in the sublattice of magnetite is also sensitively reflected in the Curie temperature, ranging from 200 to 580°C. The spinel group minerals are designated as titanomagnetite with the dominance of ulvöspinel, magnetite and magnesioferrite components, or titanomagnetite with the magnetite, ulvöspinel and magnesioferrite components. Only two samples are characterized by a significant presence of Cr-spinel and magnesiochromite components forming cores of titanomagnetites. The titanomagnetite-bearing rocks in the studied area, likewise the low- to medium-Ti basaltic rocks from the ?eské st?edoho?í Mts., provide similar thermomagnetic curves.     

High-resolution magnetostratigraphy and micropalaeontology across the J/K boundary strata at Brodno near ilina, western Slovakia: summary of results

This study summarizes the final results of magnetostratigraphic and micropalaeontological investigations of the Tithonian/Berriasian boundary (J/K) limestones at the locality of Brodno near ilina, Western Carpathians, West Slovakia. The aim is to prepare the background for correlation of a Late Tithonian and Early Berriasian biostratigraphic zonation with global magnetoevents (manifested in detailed magnetostratigraphic profiles) between the Tethyan realm and other regions, particularly the Boreal and Pacific realms. Suitable physical properties of the limestones studied, a favourable geological setting and rich microfossil assemblages (calpionellids) at Brodno (magnetozones M21r to M18r) allowed a systematic collection of new data on the original synoptic section, which now has the character of a high-resolution profile across the J/K boundary. Two reverse subzones detected within magnetozones M20n and M19n are named ‘Kysuca Subzone’ and ‘Brodno Subzone’, respectively. Both can be correlated with analogous subzones in the M-sequence of marine anomalies. Their existence can also be confirmed in the Bosso Valley section in Umbria, central Italy. A detailed study of the interval between magnetozones M20n and M17r in the Bosso Valley profile is presently in its final stage. Both magnetostratigraphic profiles, from the Brodno and Bosso Valley localities, were thoroughly investigated in the intervals close to the J/K boundary and are still unique among continent-based profiles in the detection and precise definition of both reverse subzones within M20n and M19n. Samples collected from the boundary strata of the reverse Kysuca Subzone at Brodno indicated a transition from N (R) to R (N) polarity of the Earth's palaeomagnetic field within a time interval of c. ±5 ka. Limestone samples (total number N=368) were subjected to progressive thermal demagnetization in 10–12 thermal fields and to subsequent multi-component analysis of remanence. The C-component, as the carrier of palaeomagnetic directions, was determined in the temperature interval of 300° to 540°, or possibly 580°C. Magnetomineralogical analyses of pilot samples and unblocking temperatures determined for all samples showed that magnetite is the carrier of remanent magnetization. The positions of the individual events of calpionellid stratigraphy relative to the global magnetic polarity timescale are precisely defined. The base of the Calpionella Standard Zone, which is considered a provisional J/K boundary indicator in ammonite-free sections in the Tethyan realm, lies within magnetozone M19n at the level of 35% of its local thickness. None of the boundaries in the calpionellid zonation coincides precisely with any of those in the palaeomagnetic zonation, but the first appearance ofCalpionella grandalpina , indicating the base of the Intermedia Subzone, lies in close proximity to the base of magnetozone M19r.     

Palaeomagnetism and palaeogeography of Mongolia from the Carboniferous to the Cretaceous—final report

The present study summarizes the results of palaeomagnetic investigations of Carboniferous to Cretaceous rocks with respect to global-tectonic interpretations of Eurasia. Normal and reverse directions of stable remanence components were found for the Carboniferous to Cretaceous rocks within single outcrops, sometimes even within individual samples. Triassic, Permian and Carboniferous pole positions for Mongolia are strikingly different from those of the Siberian platform. The conclusion about the different palaeogeographical development of Mongolia with respect to the Siberian platform is well seen from differences in palaeolatitudes (up to 50°) and palaeorotations (up to 150°). The apparent polar wander paths for Mongolia and the north China block are almost identical since the Carboniferous. This way, palaeomagnetic and palaeogeographical data are contributing to the global-tectonics model of the regions under study. During the Carboniferous, Permian and Triassic, the regions of Mongolia investigated were not part of Eurasia. Together with the north China block, they show a palaeogeographical affinity with the Pacific Plate.     

A palaeomagnetic and petromagnetic study of Upper-Carboniferous,Permian and Triassic sediments,NW Bulgaria

Summary In order to obtain basic palaeomagnetic data on Upper Carboniferous, Permian and Triassic sediments collected from the NW Bulgaria, laboratory stability tests were extended from A.C. and thermal treatments to studies of mineral phase changes and to investigations of changes of magnetic anisotropy during laboratory procedures. Laboratory criteria were found which permitted to distinguish samples suitable for palaeomagnetic analyses from those representing rocks totally or almost totally chemically reworked during their history. Palaeomagnetic directions and pole positions derived from Stephanian, Lower Permian and Triassic rocks from the southern margin of the Moesian Platform are compatible with the values obtained for the tectonically stable North-European Platform.     

Magnetostratigraphy of Cave Sediments: Application and Limits

The application of the magnetostratigraphy for dating of clastic and chemogenic cave sediments has been limited by the complex conditions underground and the lack of age constraints on these deposits for correlation with geomagnetic polarity timescale (GPTS). Without age constraints any correlation of obtained results cannot be explicit. Additionally, the dynamic character of cave infilling, exhumation and fossilisation expressed by unconformities within preserved sedimentary profiles can hide a substantial part of the geological time. The detailed internal division of deposits (breaks in deposition and related processes) and scarcity of fossils make the correlation of obtained magnetostratigraphic log with geomagnetic polarity timescales sometimes problematic. The analytical results confirmed that the complete step/field procedure offered by demagnetisation methods must be applied. The application of complete analysis only to pilot samples and shortened, selected field/step approach, to other samples did not offer sufficient data set for reliable interpretation.     

Palaeomagnetism and palaeogeography of Variscan formations of the Bohemian massif: A comparison with other regions in Europe

Summary Statistical evaluation of palaeomagnetic data from the Early Carboniferous to the Middle Triassic rocks in Europe, north of the Alpine tectonic belt, confirmed previously defined palaeotectonic stability of the whole European Plate since the Early Permian. The Trans-European Suture Zone represents a plate boundary, SW of which the Early Variscan and pre-Variscan formations show different degrees of palaeotectonic rotations, predominantly rotations of clockwise sense. A theoretical model simulating the translation and rotation movements was proposed showing that the West European Variscides underwent Hercynian palaeotectonic rotations comparable with the rotations derived for the Alpine tectonic belt.