Adsorption of fluoride on goethite surfaces-implications on dental epidemiology

Fluoride ion interaction with synthetically prepared goethite has been investigated over a range of pH values (4–9) and F^– concentrations (10^–3–10^–5 M). The amount of F^– retained by goethite suspensions was found to be a function of pH, media ionic strength, F^– concentration, and goethite concentration. The lowest ionic strength (0.001 M KNO₃) gave the highest adsorption medium. Uptake was minimal at pH >7 and increased with decreasing pH. Thermodynamic properties for fluoride adsorption at 298 K and 323 K were investigated. The isosteric heat of adsorption (H _r) was calculated and the heterogeneity and homogeneity of the surface examined for goethite. In view of the importance of fluoride in dental health, the interaction of fluoride on goethite in the physical environment has important implications on dental epidemiology.     

Effects of climate change on coastal fresh groundwater resources

This study evaluates the impacts of climate change on fresh groundwater resources specifically salinity intrusion in water resources stressed coastal aquifers. Our assessment used the Hadley Centre climate model, HadCM3 with high and low emission scenarios (SRES A2 and B2) for years 2000–2099. In both scenarios, the annual fresh groundwater resources losses indicate an increasing long-term trend in all stressed areas, except in the northern Africa/Sahara region. We also found that precipitation and temperature individually did not show good correlations with fresh groundwater loss. However, the relationship between the aridity index and fresh groundwater loss exhibited a strong negative correlation. We also discuss the impacts of loss of fresh groundwater resources on socio-economic activities, mainly population growth and per capita fresh groundwater resources.     

Impacts of climate variability on water quality with best management practices in sub‐tropical climate of USA

Efficiency of non‐point source pollution control methods may be altered in future climate. This study investigated climate change impacts on sediment and nutrient transport, and efficiency of best management practices (BMPs), in the Upper Pearl River Watershed (UPRW) in Mississippi. The Soil and Water Assessment Tool was applied to the UPRW using observed flow, sediment and nutrient data. Water quality samples were collected at three US geological survey gauging stations. The model was successfully calibrated and validated for daily time steps (Nash Sutcliffe efficiency and coefficient of determination – R² up to 0.7) using manual and automatic (sequential uncertainty fitting version 2) methods from February 2010 to May 2011. Future weather scenarios were simulated using the LARS‐WG model, a stochastic weather generator, with Community Climate System Model, global climate model, which was developed by the National Center for Atmospheric Research in the USA. On the basis of the Special Report on Emissions Scenarios A1B, A2 and B1 of the Intergovernmental Panel on Climate Change, climate change scenarios were simulated for the mid (2046–2065) and late (2080–2099) century. Effectiveness of four BMPs (Riparian buffer, stream fencing, sub‐surface manure applications and vegetative filter strips) on reducing sediment and nutrient were evaluated in current and future climate conditions. Results show that sediment, nitrogen and phosphorus loadings will be increased up to a maximum of 26.3%, 7.3% and 14.3%, respectively, in future climate conditions. Furthermore, the effectiveness of BMPs on sediment removal will be reduced in future climate conditions, and the efficiency of nitrogen removal will be increased, whereas phosphorus removal efficiency will remain unchanged. Copyright © 2013 John Wiley & Sons, Ltd.     

Monsoonal impact on circulation pathways in the Indian Ocean

Monsoon driven water mass exchange between the Bay of Bengal(Bo B) and Arabian Sea(AS) is the common experience. However, it is not yet firmly confirmed that the exchange pathway is either passing through southern tip of Sri Lanka or Palk Strait. Local circulation patterns impact the pathways followed by the East Indian Coastal Currents(EICC) that drive exchange, thereby modulating mixing and water mass transformation in the Bay of Bengal around Sri Lanka. In this study, observations from surface drifters were incorporated with the satellite derived data to understand the monsoonal impact on circulation patterns in the Indian Ocean. This was the first multi-national scientific effort which was conducted in the Bo B and AS during 2013 to 2015 to understand the monsoonal impact on circulation patterns in the complex region. The results indicated that seasonally reversing monsoonal currents of southern Sri Lanka, traced by the wintertime freshwater export pathways of the EICC. The deflection of monsoon currents running along the east coast of Sri Lanka by forming cyclonic and anti-cyclonic eddies, which influence the mixing and stirring associated with these flows. Results further indicate the low salinity cold water flows from the Bo B to AS along the western boundary of the Bo B during northeast monsoon. In the same way, reverses the phenomena during southwest monsoon, transporting high salinity warm water from AS to the Bo B. This maintain the bay status which occurred due to freshwater influx from large rivers and high saline water from AS. However, no evidences were observed for the exchange through Palk Strait during the study.Also, there are some mis-matches in in-situ and remotely sensed measurements which imply the necessity of systematic observation system for the complex region as an alternative approach.     

Field Survey of Tsunami Effects in Sri Lanka due to the Sumatra-Andaman Earthquake of December 26, 2004

The December 26, 2004 Sumatra-Andaman earthquake that registered a moment magnitude (M_w) of 9.1 was one of the largest earthquakes in the world since 1900. The devastating tsunami that resulted from this earthquake caused more casualties than any previously reported tsunami. The number of fatalities and missing persons in the most seriously affected countries were Indonesia - 167,736, Sri Lanka - 35,322, India - 18,045 and Thailand - 8,212. This paper describes two field visits to assess tsunami effects in Sri Lanka by a combined team of Japanese and Sri Lankan researchers. The first field visit from December 30, 2004 – January 04, 2005 covered the western and southern coasts of Sri Lanka including the cities of Moratuwa, Beruwala, Bentota, Pereliya, Hikkaduwa, Galle, Talpe, Matara, Tangalla and Hambantota. The objectives of the first field visit were to investigate the damage caused by the tsunami and to obtain eyewitness information about wave arrival times. The second field visit from March 10–18, 2005 covered the eastern and southern coasts of Sri Lanka and included Trincomalee, Batticaloa, Arugam Bay, Yala National Park and Kirinda. The objectives of the second visit were mainly to obtain eyewitness information about wave arrival times and inundation data, and to take relevant measurements using GPS instruments.     

Hammer Efficiency and Correction Factors for the TxDOT Texas Cone Penetration Test

This study analyzes blowcount data from instrumented Texas Cone Penetration (TCP) tests. TCP hammer efficiency, rod length influence on the hammer efficiency, and overburden pressure correction factors for the TCP blowcounts (N_TCP) are explored. Results are compared to published correction factors for the standard penetration test (SPT). The final dataset analyzed for this study consisted of 293 TCP tests from which 135 tests were instrumented. TCP hammer efficiency values for automatic trip hammers ranged from 74 to 101% with an average of 89%. Analyses showed a statistically-significant relationship between the TCP hammer efficiency and the rod length below ground surface. Statistical models were developed for undifferentiated soils, and corresponding rod length correction factors for the TCP test (C_R-TCP) were obtained ranging from 0.90 to 1.00. In a second analysis, the relationship between the overburden pressure and N_TCP was explored and a mathematical expression for the overburden correction factor for the TCP blowcount value (C_N-TCP) was determined. This work represents the first study where corrections to N_TCP are explored, and the outcome of this research benefits the geotechnical engineering community using the TCP test and its associated foundation design method.     

Estimating snow distribution over a large area and its application for water resources

The spatial and temporal distribution of the snow water equivalent (SWE), snow density and snow depth were estimated by a method combining remote sensing technology and degree‐day techniques over a study area of 370 000 km². The advantages of this simulation model are its simplicity and the availability of degree‐day parameters, which can be successively evaluated by referring to snow area maps created from satellite images. This simulation worked very well for estimating SWE and helped to separate the areas of thin snow cover from heavier snowfall. However, shallow snow in warm regions led to some misjudgments in the snow area maps because of the time lag between when the satellite image was acquired and the simulation itself. Vulnerable areas, where a large variation in the amount of snow affects people's life, could be identified from the differences between heavy and light snow years. This vulnerability stems from a predicted lack of irrigation water for rice production caused by future climate change. The model developed in this study has the potential to contribute to water management activities and decision‐making processes when considering necessary adaptations to future climate change. Copyright © 2007 John Wiley & Sons, Ltd.     

A spatial temporal downscaling approach to development of IDF relations for Perth airport region in the context of climate change

ABSTRACT

Downscaling of climate projections is the most adapted method to assess the impacts of climate change at regional and local scales. This study utilized both spatial and temporal downscaling approaches to develop intensity–duration–frequency (IDF) relations for sub-daily rainfall extremes in the Perth airport area. A multiple regression-based statistical downscaling model tool was used for spatial downscaling of daily rainfall using general circulation models (GCMs) (Hadley Centre’s GCM and Canadian Global Climate Model) climate variables. A simple scaling regime was identified for 30 minutes to 24 hours duration of observed annual maximum (AM) rainfall. Then, statistical properties of sub-daily AM rainfall were estimated by scaling an invariant model based on the generalized extreme value distribution. RMSE, Nash-Sutcliffe efficiency coefficient and percentage bias values were estimated to check the accuracy of downscaled sub-daily rainfall. This proved the capability of the proposed approach in developing a linkage between large-scale GCM daily variables and extreme sub-daily rainfall events at a given location. Finally IDF curves were developed for future periods, which show similar extreme rainfall decreasing trends for the 2020s, 2050s and 2080s for both GCMs.

Editor M.C. Acreman; Associate editor S. Kanae