The role of closed ecological systems in carbon cycle modelling

Acquiring a mechanistic understanding of the role of biotic feedbacks for the links between atmospheric CO₂ concentrations and temperature is essential for trustworthy climate predictions. Currently, computer-based simulations are the only available tool to estimate the global impact of biotic feedbacks on future atmospheric CO₂ and temperatures. Here we propose an alternative and complementary approach by using materially closed, energetically open analogue/physical models of the carbon cycle. We argue that there is unexplored potential in using a materially closed approach to improve our understanding of the magnitude and direction of many biotic carbon feedbacks and that recent technological advances make this feasible. We also suggest how such systems could be designed and discuss the advantages and limitations of establishing physical models of the global carbon cycle.     

A multi‐proxy record of changing environments from ca. 30 000 to 9000 cal. a BP: Onepoto maar palaeolake,Auckland, New Zealand

We present a high‐resolution record of lacustrine sedimentation spanning ca. 30 000 to 9000 cal. a BP from Onepoto maar, northern North Island, New Zealand. The multi‐proxy record of environmental change is constrained by tephrochronology and accelerator mass spectrometric ¹⁴C ages and provides evidence for episodes of rapid environmental change during the Last Glacial Coldest Period (LGCP) and Last Glacial–Interglacial Transition (LGIT) from northern New Zealand. The multi‐proxy palaeoenvironmental record from Onepoto indicates that the LGCP was cold, dry and windy in the Auckland region, with vegetation dominated by herb and grass in a beech forest mosaic between ca. 28 500 and 18 000 cal. a BP. The LGCP was accompanied by more frequent fires and influx of clastic sediment indicating increased erosion during the LGCP, with a mid‐LGCP interstadial identified between ca. 25 000 and 23 000 cal. a BP. Rapid climate amelioration at ca. 18 000 cal. a BP was accompanied by increased terrestrial biomass exemplified by the expansion of lowland podocarp forest, especially Dacrydium cupressinum. Increasing biomass production is reversed briefly by LGIT perturbations which are apparent in many of the proxies that span ca. 14 000–10 500 cal. a BP, suggesting generally increased wetness and higher in situ aquatic plant productivity with reduced terrestrial organic matter and terrigenous detrital influx. Furthermore, conditions at that time were probably warmer and frosts rare based on the increasing importance of Ascarina. The subsequent early Holocene is characterised by podocarp conifer forest and moist mild conditions. Postglacial sea‐level rise breached the crater rim and deposited 36 m of estuarine mud after ca. 9000 cal. a BP. Copyright © 2011 John Wiley & Sons, Ltd.     

LA‐ICP‐MS Pb isotope test of meteorite provenance: A terrestrial origin for Lovina

Lovina, classified as an ungrouped ataxite, is controversial and its identity as a meteorite has been questioned. In this work, we use Pb isotopes on targeted troilite nodules in Lovina as a test of its antiquity and provenance. Although precise ages cannot be obtained, LA‐ICP‐MS offers a rapid, straightforward procedure to establish the source of lead, whether ancient (meteoritic) or modern (terrestrial). For nine pristine, unweathered nodules in Lovina, we find a lead isotopic composition of: ²⁰⁶Pb/²⁰⁸Pb = 0.492 ± 0.003 (2σ, MSWD 0.79; 95%) and ²⁰⁷Pb/²⁰⁶Pb = 0.852 ± 0.003 (2σ, MSWD 1.09; 95%) with no detectable uranium. All lead compositions of the troilite fall in the range expected for modern environmental and mantle lead and are distinctly different from the primordial Canyon Diablo Troilite (CDT) composition of ancient meteoritic troilite. Although the origin of Lovina remains unknown, we conclude that lead in the Lovina troilite is unsupported by U decay and originated from a terrestrial source.     

A Simple Index of Trophic Status in Estuaries and Coastal Bays Based on Measurements of pH and Dissolved Oxygen

Measurements of pH and dissolved oxygen saturation in summer from 90 Irish estuaries and coastal bays were used to develop a simple index of trophic state. The index is based on the assumption that large fluctuations in both these variables are likely to be a characteristic feature of eutrophication. In this paper, we use a simple index to capture the relative variation in both pH and dissolved oxygen saturation in each water body during a period of 3 years. We show that the index is in good agreement with other trophic status schemes and strongly correlated with parameters indicative of trophic state such as chlorophyll a and biochemical oxygen demand. We conclude that the index could be used as a simple screening tool to group individual water bodies into broad categories that reflect their trophic state.     

Study of mango biomass (Mangifera indica L) as a cationic biosorbent

Unfertilizable fruiting buds of mango plant Mangifera Indica L, an agrowaste, is used as a biomass in this study. The efficacy of the biosorbent was tested for the removal of lead, copper, zinc and nickel metal ions using batch experiments in single and binary metal solution under controlled experimental conditions. It is found that metal sorption increases when the equilibrium metal concentration rises. At highest experimental solution concentration used (150 mg/L), the removal of metal ions were 82.76 % for lead, 76.60 % for copper, 63.35 % for zinc and 59.35 % for nickel while at lowest experimental solution concentration (25 mg/L), the removal of metal ions were 92.00% for lead, 86.84 % for copper, 83.96 % for zinc and 82.29 % for nickel. Biosorption equilibrium isotherms were plotted for metal uptake capacity (q) against residual metal concentrations (C_f) in solution. The q versus C_f sorption isotherm relationship was mathematically expressed by Langmuir and Freundlich models. The values of separation factor were between zero and one indicating favourable sorption for four tested metals on the biosorbent. The surface coverage values were approaching unity with increasing solution concentration indicating effectiveness of biosorbent under investigation. The non-living biomass of Mangifera indica L present comparable biosorption capacity for lead, copper, zinc and nickel metal ions with other types of biosorbent materials found in literature and is effective to remove metal ions from single metal solutions as well as in the presence of other co-ions with the main metal of solution.     

Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

Galaxy magnitudes

In this, the first of a short series of papers on the magnitudes of galaxies, the dependence of magnitude on the aperture used in photoelectric measures is discussed. mean results from an empirical study are presented.