Interplay between erosion and tectonics in the Western Alps

Bedrock fission‐track analysis, high‐resolution petrography and heavy mineral analyses of sediments are used to investigate the relationships between erosion and tectonics in the Western Alps. Along the Aosta Valley cross‐section, exhumation rates based on fission‐track data are higher in the fault‐bounded western block than in the eastern block (0.4–1.5 vs. 0.1–0.3 mm yr⁻¹). Erosion rates based on the analysis of bed‐load in the Dora Baltea drainage display the same pattern and have similar magnitudes in the relative sub‐basins (0.4–0.7 vs. 0.04–0.08 mm yr⁻¹). Results highlight that climate, relief and lithology are not the controlling factors of erosion in the Western Alps. The main driving force behind erosion is instead tectonics that causes the differential upward motion of crustal blocks.     

QUEST on DASI: a South Pole CMB polarization experiment

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.     

Abundances of [WC] central stars and their planetary nebulaee

We review elemental abundances derived for planetary nebula (PN) WCcentral stars and for their nebulae. Uncertainties in the abundances of[WC] stars are still too large to enable an abundance sequenceto be constructed. In particular it is not clear why the hotter [WCE]stars have C and O abundances which are systematically lower than those oftheir supposed precursors, the [WCL] stars. This abundance differencecould be real or it may be due to unaccounted-for systematic effects inthe analyses. Hydrogen might not be present in [WC] star winds asoriginallysuggested, since broad pedestals observed at the base of nebular lines canplausibly be attributed to high velocity nebular components. It isrecommended that stellar abundance analyses should be carried out withnon-LTE model codes, although recombination line analyses can provideuseful insights. In particular, C II dielectronic recombinationlines provide a unique means to determine electron temperatures in cool[WC] star winds. We then compare the abundances found for PNe which have [WC] central starswith those that do not. Numerous abundance analyses of PNe have beenpublished, but comparisons based on non-uniform samples and methods arelikely to lack reliability. Nebular C/H ratios, which might be expected todistinguish between PNe around H-poor and H-rich stars, are rather similarfor the two groups, with only a small tendency towards larger values fornebulae around H-deficient stars. Nebular abundances should be obtainedwith photoionization models using the best-fitting non-LTE modelatmosphere for the central star as the input. Heavy-metal line blanketingstill needs to be taken into consideration when modeling the central star,as its omission can significantly affect the ionizing fluxes as well asthe abundance determinations. We discuss the discrepancies between nebularabundances derived from collisionally excited lines and thosederived from optical recombination lines, a phenomenon that may havelinks with the presence of H-deficient central stars.     

Keck observations of near-Earth asteroids in the thermal infrared

We present the results of thermal-infrared observations of 20 near-Earth asteroids (NEAs) obtained in the period March 2000-February 2002 with the 10-m Keck-I telescope on Mauna Kea, Hawaii. The measured fluxes have been fitted with thermal-model emission continua to determine sizes and albedos. This work increases the number of NEAs having measured albedos by 35%. The spread of albedos derived is very large (p_v=0.02−0.55); the mean value is 0.25, which is much higher than that of observed main-belt asteroids. In most cases the albedos are in the ranges expected for the spectral types, although some exceptions are evident. Our results are consistent with a trend of increasing albedo with decreasing size for S-type asteroids with diameters below 20 km. A number of objects are found to have unexpectedly low apparent color temperatures, which may reflect unusual thermal properties. However, the results from our limited sample suggest that high thermal-inertia, regolith-free objects may be uncommon, even amongst NEAs with diameters of less than 1 km. We discuss the significance of our results in the light of information on these NEAs taken from the literature and the uncertainties inherent in applying thermal models to near-Earth asteroids.     

Carbon biogeochemistry of the Betsiboka estuary (north-western Madagascar)

Madagascar’s largest estuary (Betsiboka) was sampled along the salinity gradient during the dry season to document the distribution and sources of particulate and dissolved organic carbon (POC, DOC) as well as dissolved inorganic carbon (DIC). The Betsiboka was characterized by a relatively high suspended matter load, and in line with this, low DOC/POC ratios (0.4–2.5). The partial pressure of CO₂ (pCO₂) was generally above atmospheric equilibrium (270–1530 ppm), but relatively low in comparison to other tropical and subtropical estuaries, resulting in low average CO₂ emission to the atmosphere (9.1 ± 14.2 mmol m⁻² d⁻¹). Despite the fact that C4 vegetation is reported to cover >80% of the catchment area, stable isotope data on DOC and POC suggest that C4 derived material comprises only 30% of both pools in the freshwater zone, increasing to 60–70% and 50–60%, respectively, in the oligohaline zone due to additional lateral inputs. Sediments from intertidal mangroves in the estuary showed low organic carbon concentrations (<1%) and δ¹³C values (average −19.8‰) consistent with important inputs of riverine imported C4 material. This contribution was reflected in δ¹³C signatures of bacterial phospholipid derived fatty acids (i + a15:0), suggesting the potential importance of terrestrial organic matter sources for mineralization and secondary production in coastal ecosystems.     

Sulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS

We have developed a technique for the accurate and precise determination of ³⁴S/³²S isotope ratios (δ³⁴S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O₂⁺. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical.     

Assessment of sandstone deterioration at Ta Keo temple (Angkor): first results and future prospects

A first application of geomorphological methods to the assessment of sandstone deterioration at Angkor is presented. Damage diagnosis was carried out on the first eastern tier of the central pyramid of the 1,000 year-old Ta Keo temple. Methods combine field observations and measurements at 230 sampling points, high-resolution lasergrammetry and stereophotogrammetry on a 2-m² test zone, and SEM observations. The first results indicate that decay operates through a synergistic combination of weathering phenomena dominated by scaling and solution, and exhibits a high spatial variability. Percentages of deteriorated surfaces vary from 17.6 to 93.8%, and average stone recession values from 0.00 to 2.71 cm (minimum) and 0.34 to 5.49 cm (maximum). On the test-zone, stereophotogrammetry and 3D-mapping of the present and reconstructed initial states using lasergrammetry indicate that erosion scars up to 6 cm deep have formed since 1963. On the whole, the amount of deteriorated surfaces more than tripled between 1963 and 2008. The degree of implication of salts in stone decay remains unclear for most efflorescences are composed of calcite (CaCO3), with secondary importance of barite (BaSO4) and gypsum (CaSO₄·2H₂O). Future prospects aim to evaluate the impact on stone decay of the clearing out of the temple from the forest in the 1920s.     

Risk assessment strategies for the reactivation of earth flows in the Northern Apennines (Italy)

The aim of this paper is to analyze the reactivation mechanism of ancient earth flows, with a view to gleaning information that can subsequently be utilized to formulate a risk-reduction strategy. All considerations made herein are the result of direct experience and observation of actual events which have occurred over the past few decades in the Northern Apennines. Particular attention has been paid to the analysis of the evolution of landslides during actual reactivation, acknowledging a typical, recurring succession of events that precede the failure of the slope. The hazard assessment of these large landslide bodies, which are of slope scale, constitutes a thorny problem, especially in view of the inapplicability of traditional deterministic models such as limit equilibrium stability analysis. Nevertheless, a site-specific assessment of probability of reactivation of these large and ancient earth flows is fundamental to effective land-use planning.