Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity

Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations.     

The Klippfisk Formation—a new lithostratigraphic unit of Lower Cretaceous platform carbonates on the Western Barents Shelf

A new Lower Cretceous lithostratigraphic unit of the Western Barents Shelf, named the Klippfisk Formation, is formally introduced. The formation represents a condensed carbonate succession deposited on platform areas and structural highs, where it consists of limestones and marls, often glauconitic. The limestones may have a nodular appearance, and fossil debris, which are dominated by Inoceramus prisms, may be abundant. The Klippfisk Formation is composed of two members: the Kutling Member defined herein from cores drilled on the Bjarmeland Platform, and the coeval Tordenskjoldberget Member described on Kong Karls Land. The base of the formation is defined by the abrupt decrease in gamma-ray intensity, where the dark shales of the underlying Hekkingen or Agardhfjellet formations are replaced by marls. It is often unconformable. The Klippfisk Formation is of Berriasian to Early Barremian age and appears to be time-transgressive over parts of the Western Barents Shelf (including Kong Karls Land). It passes laterally into the basinal Knurr Formation. On Kongsøya (Kong Karls Land) a thin shale unit, bounded by unconformities, earlier included in the Tordenskjoldberget Member, represents the northernmost extension of the overlying Kolje Formation in the Barents Shelf.     

Geology and palynology of the Triassic succession of Bjørnøya

The Triassic succession of Bjørnøya (200 m) comprises the Lower Triassic Urd Formation (65 m) of the Sassendalen Group, and the Middle and Upper Triassic Skuld Formation (135 m) of the Kapp Toscana Group. These units are separated by a condensed '.'Middle Triassic sequence represented by a phosphatic remainé conglomerate (0.2m).
The Urd Formation consists of grey to dark grey shales with yellow weathering dolomitic beds and nodules. Palynology indicates the oldest beds to be Diencrian; ammonoid faunas in the middle and upper part of the formation arc of Smithian age. The organic content (c. 1 %) includes kerogen of land and marine origin, reflecting a shallow marine depositional environment.
The Skuld Formation is dominated by grey shales with red weathering siderite nodules. There are minor coarsening upwards sequences; the highest bed exposed is a 20 m thick, very fine-grained sandstone. Palynomorphs indicate a late Ladinian age for the lower part of the formation, and macrofossils and palynomorphs indicate Ladinian to Carnian ages for the upper part. Sedimentary structures, a sparse marine fauna and microplankton indicate deposition in a shallow marine environment. The organic residues contain dominantly terrestrially derived kerogen.     

The type section of the Vikinghôgda Formation: a new Lower Triassic unit in central and eastern Svalbard

The Vikinghøgda Formation (250 m) is defined with a stratotype in Deltadalen-Vikinghøgda in central Spitsbergen. The Vikinghøgda Formation replaces the Vardebukta and Sticky Keep Formations of Buchan et al. (1965) and the lower part of the Barentsøya Formation of Lock et al. (1978) as extended geographically by Mørk, Knarud et al. (1982) in central Spitsbergen, Barentsøya and Edgeøya. The formation consists of three member: the Deltadalen Member (composed of mudstones with sandstones and siltstones), the Lusitaniadalen Member (dominated by mudstones with thin siltstone beds and some limestone concretions) and the Vendomdalen Member (composed of dark shales with dolomite interbeds and nodules). The Lusitaniadalen and Vendomdalen members replace the former Sticky Keep Formation/ Member in the siirne areu. The Vikinghøda Formation can be followed through central and eastern Spitsbergen to Barentøya and Edgeøya and includes all sediments between the chert-rich Kapp Starostin Formation (Permian) and the organic-rich shales of the Botneheia Formation (Middle Triassic). The subdivision into three members is also reflected in the organic carbon content and palynofacies. Upwards. each succeeding member becomes more distal, organic-rich and oil-prone than the one below.
The Vikinghøda Formation is well-dated by six ammonoid zones. although the transitional beds between the Deltadalen and Lusitaniadalen members lack age diagnostic macrofossils. Corresponding palynozonation and magnetustratigraphy have also been determined. The overall stratigraphical development correlates well with other key Triassic areas in the Arctic, although intervals in the late Dienerian and early Smithian may be condensed or missing.     

火山岩风化壳储层发育模式——以三塘湖盆地马朗凹陷石炭系火山岩为例

中国的火山岩油气勘探近年来进展非常快,并不断在许多盆地发现了优质火山岩储层,其中风化壳型储层作为非常重要的火山岩储集体类型而倍受重视。三塘湖盆地马朗凹陷石炭系风化壳型储层储集空间以溶蚀孔洞缝为主,储层物性非常好。通过火山岩油气勘探中的野外露头观察、钻井取心、镜下薄片鉴定,及主量元素、微量元素等分析化验资料,并结合火山岩岩石学特征和物性特点,初步建立了该区的风化壳储层的发育模式,将火山岩风化壳储层在垂向上自上而下划分为五个带: ①最终分解产物带; ②水解带; ③淋滤带; ④崩解带; ⑤未风化带(母岩)。淋滤带储集物性最好,该区风化淋滤是改善储层的关键。     

Tracing the source of 3,3'-dichlorobiphenyl found in samples collected in and around Halifax Harbour

3,3'-dichlorobiphenyl (IUPAC No. 11), a chlorobiphenyl (CB) that is not generally analysed in environmental studies of CBs, is found, sometimes at high concentrations, in water, suspended particulate material, biota and sediments from Halifax Harbour, NS, Canada. The results presented demonstrate the need for investigations of non-Aroclor CBs like CB 11. Not only can they have rather elevated environmental concentrations like those reported here for CB 11, but they also can be members of the more toxic non-ortho class of CBs and thus important from a toxicity standpoint. The focus of this paper was to investigate the possible sources of CB 11, a trace constituent of commercial mixtures, but dominant in various environmental compartments of Halifax Harbour.