Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.     

Regional rating curve models of suspended sediment transport for Turkey

Estimations of annual suspended sediment loads are required for various types of water resources studies. Often estimation of the sediment load is needed for ungauged watersheds. Regionalization methods provide a practical solution to solve such problems. The purpose of this study is to classify suspended sediment yields in watersheds into homogeneous regions in order to identify their regional sediment rating curves. This study has been carried out for suspended sediment stations on 26 main basins of Turkey. Long term-scale suspended sediment rating curves of 115 gauging stations in Turkey were classified using cluster analysis on the basis of hydrological homogeneity. An agglomerative hierarchical clustering algorithm is used so that stations from different geographical locations are considered in the same cluster independently of their geographical location. 115 gauging stations were clustered into 4 different homogenous regions and the regional suspended sediment rating curve was developed for each region. The performance efficiencies of the developed regional rating curves were evaluated for 8 test stations and compared to the performances of rating curves in test sites. A regionalization model is developed for estimating suspended sediment rating curves for ungauged sites in Turkey. The developed regional rating curve models result in very close performances to those of their corresponding site rating curves.     

Photochemistry of methane-water ices

We report a study on the broadband ultraviolet photolysis of methane-water ice mixtures, at low methane concentrations and temperatures relevant to the icy satellites of the outer Solar System. The photochemistry of these mixtures is dominated by the action of hydroxyl radicals on methane and the resulting products. This implies that, given sufficient exposure time, the methane will eventually be completely oxidized to carbon dioxide. The presence of methane inhibits the formation of hydrogen peroxide by serving as a trap for hydroxyl radicals. The distribution of photochemical products is broadly similar to that previously conducted using ion and electron sources, with some differences possibly attributable to the difference in radiation source. The results are applicable to a variety of icy bodies in the Solar System. On Enceladus, where methane mixed with water is measured in the plumes, methane in the surface ices is subject to oxidation and will eventually be converted to CO₂. The CH stretch feature detected in the VIMS spectra of the Enceladus surface ice suggests that methane is currently being supplied to the surface ice, likely from re-condensation of the plume gas.     

Probability distributions for carbon emissions and atmospheric response

Probability distributions for carbon burning, atmospheric CO₂, and global average temperature are produced by time series calibration of models of utility optimization and carbon and heat balance using log-linear production functions. Population growth is used to calibrate a logistically evolving index of development that influences production efficiency. Energy production efficiency also includes a coefficient that decreases linearly with decreasing carbon intensity of energy production. This carbon intensity is a piecewise linear function of fossil carbon depletion. That function is calibrated against historical data and extrapolated by sampling a set of hypotheses about the impact on the carbon intensity of energy production of depleting fluid fossil fuel resources and increasing cumulative carbon emissions. Atmospheric carbon balance is determined by a first order differential equation with carbon use rates and cumulative carbon use as drivers. Atmospheric CO₂ is a driver in a similar heat balance. Periodic corrections are included where required to make residuals between data and model results indistinguishable from independently and identically distributed normal distributions according to statistical tests on finite Fourier power spectrum amplitudes and nearest neighbor correlations. Asymptotic approach to a sustainable non-fossil energy production is followed for a global disaggregation into a tropical/developing and temperate/more-developed region. The increase in the uncertainty of global average temperature increases nearly quadratically with the increase in the temperature from the present through the next two centuries.     

Assessment of the collapse mechanisms of tufa deposits

This research assesses the collapse mechanisms of tufa deposits. The city of Antalya, located on the Mediterranean coast of Turkey, has been settled on tufa deposits. By the end of 1980s, the area behind the tufa cliffs became the site of high-rise residential buildings. Some of these buildings have suffered from foundation instabilities, which have given rise to cracking and fissuring of the walls, and overall tilting. The collapsible behaviour upon loading and/or wetting of some tufa deposits has caused foundation settlement.

Voids, bonding of grains and grain properties of the collapsible tufa were investigated using optical and scanning electron microscopes. Our studies indicate that the collapse behaviour of tufa is affected mainly by depositional environment and microfabric. Laboratory tests have been performed in order to determine the index properties and the collapse potential of tufa samples. Young tufa deposits near the surface are weakly bonded with thin films of carbonate cement, giving rise to high void ratios. Analysis of geotechnical parameters has shown that the collapse potential of tufa is closely related to the natural void ratio and the amount of cement binding the grains.     

Probabilistic seismic hazard assessment for the two layer fault system of Antalya (SW Turkey) area

Southwest Turkey, along Mediterranean coast, is prone to large earthquakes resulting from subduction of the African plate under the Eurasian plate and shallow crustal faults. Maximum observed magnitude of subduction earthquakes is Mw = 6.5 whereas that of crustal earthquakes is Mw = 6.6. Crustal earthquakes are sourced from faults which are related with Isparta Angle and Cyprus Arc tectonic structures. The primary goal of this study is to assess seismic hazard for Antalya area (SW Turkey) using a probabilistic approach. A new earthquake catalog for Antalya area, with unified moment magnitude scale, was prepared in the scope of the study. Seismicity of the area has been evaluated by the Gutenberg-Richter recurrence relationship. For hazard computation, CRISIS2007 software was used following the standard Cornell-McGuire methodology. Attenuation model developed by Youngs et al. Seismol Res Lett 68(1):58–73, (1997) was used for deep subduction earthquakes and Chiou and Youngs Earthq Spectra 24(1):173–215, (2008) model was used for shallow crustal earthquakes. A seismic hazard map was developed for peak ground acceleration and for rock ground with a hazard level of a 10% probability of exceedance in 50 years. Results of the study show that peak ground acceleration values on bedrock change between 0.215 and 0.23 g in the center of Antalya.     

Relevance of building site categories implementation into the land use plan in underground mining area in the region of Petrvald (Czech Republic)

Deep mining of mineral resources causes extensive changes in rock environment and ground morphology and must be considered in the land use planning. Subsidence as a result of underground mining activities in terrains is one of the serious geological hazards because they can effect slopes and damage engineering structures, settlement areas, natural lakes and allow infiltration of contaminant into the groundwater. The main aim of this article was implementation of the building site categories of underground mining regions into the land use plans. This case study area was selected from the region of Orlova town within the Ostrava-Karvina Coal district, and this region is one of the most affected areas by underground mining of black coal in the Czech Republic. Certain risk categories of land, where the individual categories express generalized influence of deep mining of coal in current and planned constructions were also represented in this article. Extensive variations caused by underground mining were identified within a wide variability of risk categories. An important finding was also the extensive variability over time, manifested by spatial variations in the stated categories in the studied time periods. Moreover, technical documentation of environmental impacts related to underground mining activities was provided; importance of existing and proposed underground mining projects that may significantly impact the land use was discussed and pointed out in this article, especially.